A novel silicon-oxygen aurone derivative assisted by graphene oxide as fluorescence chemosensor for fluoride anions.

Title A novel silicon-oxygen aurone derivative assisted by graphene oxide as fluorescence chemosensor for fluoride anions.
Authors Y. Xu; Q. Yang; D. Cao; Z. Liu; S. Zhao; R. Guan; Y. Wang; Q. Wu; X. Yu
Journal Spectrochim Acta A Mol Biomol Spectrosc
DOI 10.1016/j.saa.2017.03.073
Abstract

A novel silicon-oxygen aurone derivative TBDPSA was synthesized and used for the detection of fluoride anions in aqueous solution based on a specifically F(-)-triggered silicon-oxygen cleavage. Even though the compound has shown high selectivity, obvious absorption and fluorescence response for fluoride anions in aqueous solution, but it also is suffered from many limits, such as low detection sensitivity and long response time. Here the compound was successfully assembled on the graphene oxide (GO) surface by ?-? stacking. GO improves recognition sensitivity and shortens response time of TBDPSA for fluoride anions by taking advantage of the nanocarrier GO. Compared with TBDPSA, the response time of GO/TBDPSA is shortened greatly from 1h to <5s and the detection limit is lowered about four times with fluorescence as detected signal. Generally speaking, GO is an excellent promoter for accelerate recognition.

Citation Y. Xu; Q. Yang; D. Cao; Z. Liu; S. Zhao; R. Guan; Y. Wang; Q. Wu; X. Yu.A novel silicon-oxygen aurone derivative assisted by graphene oxide as fluorescence chemosensor for fluoride anions.. Spectrochim Acta A Mol Biomol Spectrosc. 2017;182:3741. doi:10.1016/j.saa.2017.03.073

Related Elements

Silicon

See more Silicon products. Silicon (atomic symbol: Si, atomic number: 14) is a Block P, Group 14, Period 3 element with an atomic weight of 28.085. Silicon Bohr MoleculeThe number of electrons in each of Silicon's shells is 2, 8, 4 and its electron configuration is [Ne] 3s2 3p2. The silicon atom has a radius of 111 pm and a Van der Waals radius of 210 pm. Silicon was discovered and first isolated by Jöns Jacob Berzelius in 1823. Silicon makes up 25.7% of the earth's crust, by weight, and is the second most abundant element, exceeded only by oxygen. The metalloid is rarely found in pure crystal form and is usually produced from the iron-silicon alloy ferrosilicon. Elemental SiliconSilica (or silicon dioxide), as sand, is a principal ingredient of glass, one of the most inexpensive of materials with excellent mechanical, optical, thermal, and electrical properties. Ultra high purity silicon can be doped with boron, gallium, phosphorus, or arsenic to produce silicon for use in transistors, solar cells, rectifiers, and other solid-state devices which are used extensively in the electronics industry.The name Silicon originates from the Latin word silex which means flint or hard stone.

Carbon

See more Carbon products. Carbon (atomic symbol: C, atomic number: 6) is a Block P, Group 14, Period 2 element. Carbon Bohr ModelThe number of electrons in each of Carbon's shells is 2, 4 and its electron configuration is [He]2s2 2p2. In its elemental form, carbon can take various physical forms (known as allotropes) based on the type of bonds between carbon atoms; the most well known allotropes are diamond, graphite, amorphous carbon, glassy carbon, and nanostructured forms such as carbon nanotubes, fullerenes, and nanofibers . Carbon is at the same time one of the softest (as graphite) and hardest (as diamond) materials found in nature. It is the 15th most abundant element in the Earth's crust, and the fourth most abundant element (by mass) in the universe after hydrogen, helium, and oxygen. Carbon was discovered by the Egyptians and Sumerians circa 3750 BC. It was first recognized as an element by Antoine Lavoisier in 1789.

Fluorine

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.

Related Forms & Applications