Copper(II) Carbonate Basic

CAS #:

Linear Formula:

CuCO3 · Cu(OH)2

MDL Number:

MFCD00010976

EC No.:

235-113-6

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PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Copper(II) Carbonate Basic
CU2-CBB-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Copper(II) Carbonate Basic
CU2-CBB-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Copper(II) Carbonate Basic
CU2-CBB-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Copper(II) Carbonate Basic
CU2-CBB-05
Pricing > SDS > Data Sheet >

Copper(II) Carbonate Basic Properties (Theoretical)

Compound Formula CH2Cu2O5
Molecular Weight 221.12
Appearance Dark Green Powder
Melting Point N/A
Boiling Point N/A
Density 4.00 g/cm3
Solubility in H2O N/A
Exact Mass 219.849418
Monoisotopic Mass 219.849418

Copper(II) Carbonate Basic Health & Safety Information

Signal Word Warning
Hazard Statements H302-H315-H319-H335
Hazard Codes Xn
Risk Codes 22-36/37/38
Safety Statements N/A
RTECS Number GL6910000
Transport Information N/A
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 12/12/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Copper(II) Carbonate Basic

Product Number: All applicable American Elements product codes, e.g. CU2-CBB-02 , CU2-CBB-03 , CU2-CBB-04 , CU2-CBB-05

CAS #: 12069-69-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
Hazards not otherwise classified
No information known
GHS label elements
The product is classified and labeled in
accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

Exclamation Mark - GHS07

GHS07
Signal word
Warning
Hazard statements
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious
eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D1B - Toxic material causing immediate and serious toxic effects
D2B - Toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH-2
FIRE-1
REACTIVITY-1
Health (acute effects) = 2
Flammability = 1
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
12069-69-1 Copper(II) carbonate dihydroxide
Identification number(s):
EC number:
235-113-6


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply fresh air or oxygen; call for doctor.
n case of unconsciousness place patient
stably in side position for transportation.
Supply patient with fresh air. If required, provide arti
ficial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under
running water. Consult a physician.
If swallowed:
Drink lots of water.
Induce vomiting if patient is conscious.
Call a doctor immediately.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Carbon monoxide and carbon dioxide
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Avoid formation of dust.
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow to enter sewers/ surface or groundwater.
Methods and materials for containment and cleanup:
Prevent formation of dust.
Dispose of contaminated material
as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information
on personal protection equipment.
See Section 13 for disposal information


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Thoroughly remove all dust particles.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions
in well-sealed containers.
Specific end use(s)
No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood desi
gned for hazardous chemicals and
having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
None.
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Penetration time of glove material (in minutes)
No data available
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Powder
Color: Green
Odor: No data available
Odor threshold: No data available.
pH: N/A
Melting point/Melting range:200 °C (392 °F) (dec)
Boiling point/Boiling range:None
Sublimation temperature / start:No data available
Flash point:N/A
Flammability (solid, gas) Product is not flammable.
Ignition temperature:No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density at 20 °C (68 °F): 4 g/cm3 (33.38 lbs/gal)
Relative density No data available.
Vapor density N/A
Evaporation rate N/A
Solubility in Water (H2O): No data available
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
To avoid thermal decomposition do not overheat.
Decomposes before melting.
Possibility of hazardous reactions
Reacts with acids
Reacts with various metals
Conditions to avoid
No data available
Incompatible materials:
No data available
Hazardous decomposition products:
Poisonous gases/vapors
Carbon monoxide and carbon dioxide
Metal oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: Harmful if swallowed.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for components in this product.
LD/LC50 values that are relevant for classification: Oral LD50 1350 mg/kg (rat)
Skin irritation or corrosion: Causes skin irritation.
Eye irritation or corrosion: Causes serious eye irritation.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity: EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal evidence of carcinogenicity or no data are available.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: May cause respiratory irritation.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: The Registry of Toxic Effects of Chemic
al Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information: Do not allow material to be released to the environment without official permits.
Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation: Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

Not a hazardous material for transportation.
UN-Number
DOT, IMDG, IATA: None
UN proper shipping name
DOT, IMDG, IATA: None
Transport hazard class(es)
DOT, ADR, IMDG, IATA Class: None
Packing group
DOT, IMDG, IATA: None
Environmental hazards: N/A
Special precautions for user: N/A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: N/A
Transport/Additional information:
Not dangerous according to the above specifications.
DOT
Marine Pollutant (DOT): No


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS07
Signal word: Warning
Hazard statements
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
12069-69-1 Copper(II) carbonate dihydroxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
Employment restrictions concerning pregnant and lactating women must be observed.
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) accord
ing to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Copper(II) Carbonate Basic

High purity Copper(II) Carbonate BasicCopper(II) Carbonate Basic is generally immediately available in most volumes, including bulk orders. American Elements can produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form, as well as numerous other machined shapes and in the form of solutions and organometallic compounds. Ultra high purity and high purity forms also include metal powder, submicron powder and nanomaterials, targets for thin film deposition, and pellets for chemical vapor deposition (CVD) and physical vapor deposition (PVD) applications. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Copper(II) Carbonate Basic Synonyms

Copper(II) carbonate hydroxide; Cupric carbonate basic; Dicopper dihydroxycarbonate; (Carbonato)dihydroxydicopper; Carbonic acid, copper complex; Copper, (carbonato)dihydroxydi-; (Carbonato(2-))dihydroxydicopper; Copper hydroxy carbonate; Carbonic acid, copper(2+) salt (1:1), basic; dicopper carbonate dihydroxide; Copper(II) carbonate copper(II) hydroxide (1:1); Copper, (mu-(carbonato(2-)-kappaO:kappaO'))dihydroxydi-; Blue Verditer, Azurite natural; CAS 100742-53-8 (Copper(II) carbonate dihydroxy monohydrate)

Chemical Identifiers

Linear Formula CuCO3 · Cu(OH)2
MDL Number MFCD00010976
EC No. 235-113-6
Beilstein/Reaxys No. N/A
Pubchem CID 25503
IUPAC Name dicopper; carbonate; dihydroxide
SMILES C(=O)([O-])[O-].[OH-].[OH-].[Cu+2].[Cu+2]
InchI Identifier InChI=1S/CH2O3.2Cu.2H2O/c2-1(3)4;;;;/h(H2,2,3,4);;;2*1H2/q;2*+2;;/p-4
InchI Key ZMMDPCMYTCRWFF-UHFFFAOYSA-J

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Copper

See more Copper products. Copper Bohr Model Copper (atomic symbol: Cu, atomic number: 29) is a Block D, Group 11, Period 4 element with an atomic weight of 63.546. The number of electrons in each of copper's shells is 2, 8, 18, 1 and its electron configuration is [Ar]3d10 4s1. The copper atom has a radius of 128 pm and a Van der Waals radius of 186 pm. Copper was first discovered by Early Man prior to 9000 BC. In its elemental form, copper has a reddish-orange metallic and lustrous appearance. Of all pure metals, only silver Elemental Copperhas a higher electrical conductivity. The origin of the word copper comes from the Latin word 'cuprium' which translates as "metal of Cyprus," as the Mediterranean island of Cyprus was known as an ancient source of mined copper..

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