Cysteamine-capped copper nanoclusters as a highly selective turn-on fluorescent assay for the detection of aluminum ions.

Title Cysteamine-capped copper nanoclusters as a highly selective turn-on fluorescent assay for the detection of aluminum ions.
Authors C. Boonmee; V. Promarak; T. Tuntulani; W. Ngeontae
Journal Talanta
DOI 10.1016/j.talanta.2017.10.006
Abstract

A new type of copper nanoclusters was synthesized by a one-pot reaction using cysteamine as a capping agent and reducing agent (Cys-CuNCs). The synthesized CuNCs exhibited a spherical shape and a monodisperse and strong fluorescent emission characteristic peak at 430nm when exciting at 330nm. The Cys-CuNCs were demonstrated as a fluorescent chemodosimeter for the selective detection of Al3+. In the presence of Al3+, the fluorescent emission of the Cys-CuNCs was considerably enhanced, while other studied metal ions did not show this phenomenon. The fluorescent intensity near 380nm linearly increased with an increasing Al3+ concentration. The proposed method provided a working range of 1-7µM with a low detection limit of 26.7nM and was applied to determine Al3+ in drinking water samples with satisfactory results.

Citation C. Boonmee; V. Promarak; T. Tuntulani; W. Ngeontae.Cysteamine-capped copper nanoclusters as a highly selective turn-on fluorescent assay for the detection of aluminum ions.. Talanta. 2018;178:796804. doi:10.1016/j.talanta.2017.10.006

Related Elements

Aluminum

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Copper

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