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Disulfur Dichloride

CAS #:

Linear Formula:

S2Cl2

MDL Number:

MFCD00011446

EC No.:

233-036-2

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PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
98% Disulfur Dichloride
S2-CL2-018-LIQ
Pricing > SDS > Data Sheet >

Disulfur Dichloride Properties (Theoretical)

Compound Formula Cl2S2
Molecular Weight 135.04
Appearance Clear liquid
Melting Point -80 °C
Boiling Point 138 °C
Density 1.688 g/mL (25 °C)
Solubility in H2O N/A
Exact Mass 133.881847 g/mol
Monoisotopic Mass 133.881847 g/mol

Disulfur Dichloride Health & Safety Information

Signal Word Danger
Hazard Statements H301-H332-H314-H335-H400-EUH014-EUH029
Hazard Codes T, C, N
Precautionary Statements P273-P280-P301 + P330 + P331-P304 + P340-P305 + P351 + P338-P308 + P310
Flash Point >130 °C
Risk Codes N/A
Safety Statements N/A
RTECS Number N/A
Transport Information UN 1828 , 8, I
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 12/07/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Disulfur Dichloride

Product Number: All applicable American Elements product codes, e.g. S2-CL2-018-LIQ 02

CAS #: 10025-67-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 3), H331
Skin corrosion (Category 1A), H314
Serious eye damage (Category 1), H318
Acute aquatic toxicity (Category 1), H400

2.2 GHS Label elements, including precautionary statements

Skull and Crossbones - GHS06 Corrosion - GHS05Environment - GHS09

Pictogram
Signal word Danger
Hazard statement(s)
H301 + H331 Toxic if swallowed or if inhaled
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ Vapors/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately
call a POISON CENTER or doctor/ physician.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
Reacts violently with water., Contact with water liberates toxic gas.
Lachrymator.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Synonyms : Sulfur chloride
Formula : Cl2S2
Molecular weight : 135.04 g/mol
CAS-No. : 10025-67-9
EC-No. : 233-036-2
Index-No. : 016-012-00-4
Hazardous components
Component Classification Concentration
Sulfur chloride
Acute Tox. 3; Skin Corr. 1A;
Eye Dam. 1; Aquatic Acute 1;
H301 + H331, H314, H318,
H400
<= 100 %


SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim
immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Continue rinsing eyes during
transport to hospital.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a
physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable extinguishing media
Dry powder
5.2 Special hazards arising from the substance or mixture
Sulphur oxides, Hydrogen chloride gas
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid breathing Vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel
to safe areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment
must be avoided.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Do not flush with water. Keep in suitable,
closed containers for disposal.
6.4 Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of Vapor or mist.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage.
Never allow product to get in contact with water during storage.
Store under inert gas.
Storage class (TRGS 510): Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
Components with workplace control parameters
Component CAS-No. Value Control
parameters
Basis
Sulfur chloride 10025-67-9 TWA 1.000000 ppm
6.000000
mg/m3
USA. Occupational Exposure Limits
(OSHA) - Table Z-1 Limits for Air
Contaminants
Remarks The value in mg/m3 is approximate.
C 1.000000 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Upper Respiratory Tract irritation
Eye irritation
Skin irritation
C 1 ppm
USA. ACGIH Threshold Limit Values
(TLV)
Upper Respiratory Tract irritation
Eye irritation
Skin irritation
C 1.000000 ppm
6.000000
mg/m3
USA. NIOSH Recommended
Exposure Limits
C 1 ppm
6 mg/m3
USA. NIOSH Recommended
Exposure Limits
TWA 1 ppm
6 mg/m3
USA. Occupational Exposure Limits
(OSHA) - Table Z-1 Limits for Air
Contaminants
The value in mg/m3 is approximate.
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Full contact
Material: Fluorinated rubber
Minimum layer thickness: 0.7 mm
Break through time: 480 min
Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.4 mm
Break through time: 120 min
Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method:
EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It
should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, Flame retardant protective clothing, The type of protective
equipment must be selected according to the concentration and amount of the dangerous substance at the
specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose
combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
a) Appearance Form: clear, liquid
b) Odor No data available
c) Odor Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: -80 °C (-112 °F) - lit.
f) Initial boiling point and
boiling range
138 °C (280 °F) - lit.
g) Flash point > 130 °C (> 266 °F) - closed cup
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapor pressure 9.1 hPa (6.8 mmHg) at 20 °C (68 °F)
59 hPa (44 mmHg) at 55 °C (131 °F)
l) Vapor density 4.66 - (Air = 1.0)
m) Relative density 1.688 g/cm3 at 25 °C (77 °F)
n) Water solubility No data available
o) Partition coefficient: noctanol/
water
No data available
p) Auto-ignition
temperature
390 °C (734 °F)
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
Relative Vapor density 4.66 - (Air = 1.0)


SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Reacts violently with water.
10.4 Conditions to avoid
Exposure to moisture
10.5 Incompatible materials
Strong oxidizing agentsReacts violently with water., Alcohols, Metals, Peroxides, Amines
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male and female - 132 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation - Rat - male and female - 4 h - 2.5 mg/l
(OECD Test Guideline 403)
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
Ames test
Salmonella typhimurium
Result: negative
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: WS4300000
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin.,
spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary
edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea


SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Very toxic to aquatic life.


SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a
chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number: 3390 Class: 6.1 (8) Packing group: I
Proper shipping name: Toxic by inhalation liquid, corrosive, n.o.s. (Sulfur chloride)
Reportable Quantity (RQ):
Marine pollutant:yes
Poison Inhalation Hazard: Hazard zone B
IMDG
UN number: 3390 Class: 6.1 (8) Packing group: I EMS-No: F-A, S-B
Proper shipping name: TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. (Sulfur chloride)
Marine pollutant:yes
IATA
UN number: 3390 Class: 6.1 (8)
Proper shipping name: Toxic by inhalation liquid, corrosive, n.o.s. (Sulfur chloride)
IATA Passenger: Not permitted for transport
IATA Cargo: Not permitted for transport


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De
Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard
Massachusetts Right To Know Components
Sulfur chloride 10025-67-9 1993-04-24
Pennsylvania Right To Know Components
Sulfur chloride
CAS-No.
10025-67-9
Revision Date
1993-04-24
New Jersey Right To Know Components
Sulfur chloride
CAS-No.
10025-67-9
Revision Date
1993-04-24
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Disulfur Dichloride

Disulfur Dichloride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Disulfur Dichloride Synonyms

Disulfur dichloride, Sulfur monochloride, Chlorosulfane, Sulfur subchloride; Sulfur chloride (S2Cl2); Thiosulfurous dichloride, 10545-99-0, sulfur dichloride

Chemical Identifiers

Linear Formula S2Cl2
MDL Number MFCD00011446
EC No. 233-036-2
Pubchem CID 24807
IUPAC Name chlorosulfanyl thiohypochlorite
SMILES S(SCl)Cl
InchI Identifier InChI=1S/Cl2S2/c1-3-4-2
InchI Key PXJJSXABGXMUSU-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Chlorine is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s23p5. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. In its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. it has the third highest electronegativity and the highest electron affinity of all the elements making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

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