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Lanthanum 2-Ethylhexanoate

CAS #:

Linear Formula:

C24H45LaO6

MDL Number:

N/A

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Lanthanum 2-Ethylhexanoate
LA-2EH-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Lanthanum 2-Ethylhexanoate
LA-2EH-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Lanthanum 2-Ethylhexanoate
LA-2EH-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Lanthanum 2-Ethylhexanoate
LA-2EH-05
Pricing > SDS > Data Sheet >

Lanthanum 2-Ethylhexanoate Properties (Theoretical)

Compound Formula C24H45LaO6
Molecular Weight 568.52
Appearance solid
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass N/A
Monoisotopic Mass 568.227966 Da
Charge N/A

Lanthanum 2-Ethylhexanoate Health & Safety Information

Signal Word Danger
Hazard Statements H225-H315-H361-H336-H373-H304
Hazard Codes F, Xi, T
Risk Codes N/A
Safety Statements N/A
Transport Information N/A
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 08/17/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Lanthanum 2-Ethylhexanoate

Product Number: All applicable American Elements product codes, e.g. LA-2EH-02 02 , LA-2EH-03 03 , LA-2EH-04 04 , LA-2EH-05 05

CAS #: 67816-09-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS08 Health hazard
Repr. 2
H361 Suspected of damaging fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Hazards not otherwise classified
No data available
GHS label elements
GHS label elements, including precautionary statements
Hazard pictograms

Flame - GHS02 Exclamation Mark - GHS07 Health Hazard - GHS08

GHS02 GHS07 GHS08
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H361 Suspected of damaging fertility or the unborn child.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
H304 May be fatal if swallowed and enters airways.
Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280
Wear protective gloves / protective clothing.
P273
Avoid release to the environment.
P243
Take precautionary measures against static discharge.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P315
Get immediate medical advice/attention.
WHMIS classification
B2 - Flammable liquid
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 2
Flammability = 3
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
67816-09-5 Lanthanum(III) 2-ethylhexanoate, 10% w/v in hexane


SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
CO2, sand, extinguishing powder. Do not use water.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Carbon monoxide and carbon dioxide
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Methods and materials for containment and cleanup:
Keep away from ignition sources.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
Keep ignition sources away.
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
n-Hexane
ppm
ACGIH TLV 50 (skin)
Austria MAK 50
Belgium TWA 50
Denmark TWA 25
Finland TWA 50; 150-STEL
France VME 50
Germany MAK 50
Hungary TWA 100; 200-STEL
Japan OEL 40 (skin)
Korea TLV 50 (skin)
Netherlands MAC-TGG 25
Norway TWA 25
Poland TWA 100; 400-STEL
Russia TWA 40; 300-STEL
Sweden NGV 25; 50-KTV
Switzerland MAK-W 50; 100-KZG-W
United Kingdom TWA 20
USA PEL 500
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance:
Form: Liquid
Odor: Petrol-like
Odor threshold: No data available.
pH: No data available.
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flash point: -22 °C (-8 °F) (n-hexane)
Flammability (solid, gas)
No data available.
Ignition temperature: 225 °C (437 °F) (n-hexane)
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures is possible.
Explosion limits:
Lower: 1.2 Vol % (n-hexane)
Upper: 7.5 Vol % (n-hexane)
Vapor pressure: No data available
Density: No data available
Relative density
No data available.
Vapor density
No data available.
Evaporation rate
No data available.
Solubility in Water (H2O): Not miscible or difficult to mix
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Other information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No data available
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Metal oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
No effects known.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
Causes skin irritation.
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
Suspected of damaging fertility or the unborn child.
Specific target organ system toxicity - repeated exposure:
May cause damage to organs through prolonged or repeated exposure.
Specific target organ system toxicity - single exposure:
May cause drowsiness or dizziness.
May cause respiratory irritation.
Aspiration hazard:
May be fatal if swallowed and enters airways.
Subacute to chronic toxicity: n-Hexane causes skin irritation, CNS effects, lung irritation, headache, dizziness, drowsiness, Repeated or prolonged exposure to the vapor can cause peripheral
polyneuropathy. Symptoms include incoordination, slowed reaction time, blurred vision, slurred speech, facial numbness, loss of senstaiion. Gradual recovery is normally found after removal from exposure. Also causes reproductive effects in laboratory animals.
Lanthanons can cause delayed blood clotting leading to hemorrhages.
Exposure may also lead to sensitivity to heat, itching, increased awareness of odor and taste,
and liver damage.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Ecotoxical effects:
Remark:
Toxic for aquatic organisms
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Toxic for aquatic organisms
Do not allow product to reach groundwater, water courses, or sewage systems, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic to aquatic life.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN1208
UN proper shipping name
DOT
Hexanes
IMDG
HEXANES, MARINE POLLUTANT
IATA
HEXANES
Transport hazard class(es)
DOT
Class
3 Flammable liquids.
Label
3
Class
3 (F1) Flammable liquids
Label
3
IMDG
Class
3 Flammable liquids.
Label
3
IATA
Class
3 Flammable liquids.
Label
3
Packing group
DOT, IMDG, IATA
II
Environmental hazards:
Environmentally hazardous substance, liquid; Marine Pollutant
Marine pollutant (IMDG):
Symbol (fish and tree)
Special precautions for user
Warning: Flammable liquids
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
Remarks:
Special marking with the symbol (fish and tree).
UN "Model Regulation":
UN1208, Hexanes, 3, II


SECTION 15. REGULATORY INFORMATION

National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Lanthanum 2-Ethylhexanoate

Ethylhexanoate Formula Diagram (CH3(CH2)3CH(C2H5)CO2H)Lanthanum 2-Ethylhexanoate is an Lanthanum source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic Organo-Metallic Packaging, Lab Quantity compounds) as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic compounds). Ethylhexanoates are carboxylates with many commercial applications. They are commonly used in various catalysts for oxidation, hydrogenation and polymerization and as an adhesion promoter. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Lanthanum 2-Ethylhexanoate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the trade name AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. Additional technical, research and safety information is available as is a Reference Calculator for converting relevant units of measurement.

Lanthanum 2-Ethylhexanoate Synonyms

Lanthanum(III) 2-Ethylhexanoate; Lanthanum(III) 2-ethylhexanoate, 10% w/v in hexane; 2-Ethylhexanoic acid lanthanum(III) salt; hexanoic acid, 2-ethyl-, lanthanum salt (3:1); Lanthanum(3+) 2-ethylhexanoate; Lanthanum tris(2-ethylhexanoate)

Chemical Identifiers

Linear Formula C24H45LaO6
MDL Number N/A
EC No. N/A
Beilstein Registry No. N/A
Pubchem CID N/A
IUPAC Name Lanthanum tris(2-ethylhexanoate)
SMILES [La+3].[O-]C(=O)C(CC)CCCC.[O-]C(=O)C(CC)CCCC.[O-]C(=O)C(CC)CCCC
InchI Identifier InChI=1S/3C8H16O2.La/c3*1-3-5-6-7(4-2)8(9)10;/h3*7H,3-6H2,1-2H3,(H,9,10);/q;;;+3/p-3
InchI Key PPNFILUQDVDXDA-UHFFFAOYSA-K

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Lanthanum products. Lanthanum (atomic symbol: La, atomic number: 57) is a Block F, Group 3, Period 6 element with an atomic weight of 138.90547. Lanthanum Bohr ModelThe number of electrons in each of lanthanum's shells is [2, 8, 18, 18, 9, 2] and its electron configuration is [Xe] 5d1 6s2. The lanthanum atom has a radius of 187 pm and a Van der Waals radius of 240 pm. Lanthanum was first discovered by Carl Mosander in 1838. In its elemental form, lanthanum has a silvery white appearance.Elemental Lanthanum It is a soft, malleable, and ductile metal that oxidizes easily in air. Lanthanum is the first element in the rare earth or lanthanide series. It is the model for all the other trivalent rare earths and it is the second most abundant of the rare earths after cerium. Lanthanum is found in minerals such as monazite and bastnasite. The name lanthanum originates from the Greek word Lanthaneia, which means 'to lie hidden'.

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