Lanthanum Chunk

CAS 7439-91-0
Linear Formula: La
MDL Number: MFCD00011066
EC No.: 231-099-0

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PRODUCT Product Code REQUEST A QUOTE SAFETY DATA TECHNICAL DATA
(2N) 99% Lanthanum Chunk
LA-M-02-CK Pricing
(3N) 99.9% Lanthanum Chunk
LA-M-03-CK Pricing
(4N) 99.99% Lanthanum Chunk
LA-M-04-CK Pricing
(5N) 99.999% Lanthanum Chunk
LA-M-05-CK Pricing

Properties

Molecular Weight 138.91
Appearance Silvery
Melting Point 920 °C
Boiling Point 3470 °C
Density 6146 kg/m3
Thermal Expansion

(r.t.) (poly) 12.1 µm/(m·K)

Poisson Ratio (? form) 0.280
Vickers Hardness 491 MPa
Young's Modulus (? form) 36.6 GPa
Tensile Strength N/A
Thermal Conductivity 0.134 W/cm/K @ 298.2 K
Electronegativity 1.1 Paulings
Specific Heat 0.047 Cal/g/K @ 25 °C
Heat of Vaporization 96 K-Cal/gm atom at 3457 °C
Heat of Fusion 2.40 Cal/gm mole

Health & Safety Information

Signal Word Danger
Hazard Statements H228-H261
Hazard Codes N/A
Precautionary Statements P210-P231+P323-P280-P370+P378-P402+P404-P501
Risk Codes N/A
Safety Statements N/A
RTECS Number NONH
Transport Information UN 3208 4.3 / PGI
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 09/28/2016
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Lanthanum Chunk

Product Number: All applicable American Elements product codes, e.g. LA-M-02-CK , LA-M-03-CK , LA-M-04-CK , LA-M-05-CK

CAS #: 7439-91-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 Flame
Flam. Sol. 1 H228 Flammable solid.
Water-react. 2 H261 In contact with water releases flammable gas.
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms

Flame - GHS02

GHS02
Signal word
Danger
Hazard statements
H228 Flammable solid.
H261 In contact with water releases flammable gas.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378 In case of fire: Use for extinction: CO2, sand, extinguishing powder.
P402+P404 Store in a dry place. Store in a closed container.
P501 Dispose of contents/container in accordance with local/regional/
national/international regulations.
WHMIS classification
B6 - Reactive flammable material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
1
2
3
Health (acute effects) = 1
Flammability = 2
Physical Hazard = 3
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
7439-91-0 Lanthanum
Identification number(s):
EC number:
231-099-0


SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents
Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up:
Keep away from ignition sources.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Reacts violently with water
Information about protection against explosions and fires:
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Information about storage in one common storage facility:
Do not store together with oxidizing and acidic materials.
Store away from air.
Store away from water/moisture.
Further information about storage conditions:
Store under dry inert gas.
This product is air sensitive.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Protect from humidity and water.
Specific end use(s)
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and
having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes)
Not determined
Eye protection:
Safety glasses
Full face protection
Body protection:
Protective work clothing


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Solid in various forms
Color: Silvery-white
Odor: Not determined
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 920 °C (1688 °F)
Boiling point/Boiling range: 3464 °C (6267 °F)
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Highly flammable.
Contact with water liberates extremely flammable gases.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure at 3230 °C (5846 °F): 533 hPa (400 mm Hg)
Density at 20 °C (68 °F): 6.17 g/cm³ (51.489 lbs/gal)
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Contact with water releases flammable gases
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
In contact with water releases flammable gases which may ignite spontaneously.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Contact with water releases flammable gases
Conditions to avoid
No further relevant information available.
Incompatible materials:
Air
Oxidizing agents
Water/moisture
Hazardous decomposition products:
Metal oxide fume


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
No effects known.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
Powder: irritant effect
Eye irritation or corrosion:
Powder: irritant effect
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
Carcinogenic categories
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3208
UN proper shipping name
DOT
Metallic substance, water-reactive, n.o.s. (Lanthanum)
IMDG, IATA
METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. (Lanthanum)
Transport hazard class(es)
DOT
Class
4.3 Substances which, in contact with water, emit flammable gases.
Label
4.3
Class
4.3 (W2) Substances which, in contact with water, emit flammable gases
Label
4.3
IMDG, IATA
Class
4.3 Substances which, in contact with water, emit flammable gases.
Label
4.3
Packing group
DOT, IMDG, IATA
II
Environmental hazards:
Not applicable.
Special precautions for user
Warning: Substances which, in contact with water, emit flammable gases
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3208, Metallic substance, water-reactive, n.o.s. (Lanthanum), 4.3, ll


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

High purity lanthanum chunkAmerican Elements specializes in producing high purity Lanthanum Chunks using crystallization, solid state and other ultra high purification processes such as sublimation. Standard Chunk pieces are amorphous uniform pieces ranging in size from 5-15 mm. American Elements also casts any of the rare earth metals and most other advanced materials into granules, rod, bar or plate form We also produce Lanthanum as rod, pellets, powder, pieces, disc, ingot, wire, and in compound forms, such as oxide.

Synonyms

N/A

Chemical Identifiers

Linear Formula La
CAS 7439-91-0
Pubchem CID 23926
MDL Number MFCD00011066
EC No. 231-099-0
Beilstein Registry No. N/A
SMILES [La]
InchI Identifier InChI=1S/La
InchI Key FZLIPJUXYLNCLC-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Products & Element Information

SUCCESS

See more Lanthanum products. Lanthanum (atomic symbol: La, atomic number: 57) is a Block F, Group 3, Period 6 element with an atomic weight of 138.90547. Lanthanum Bohr ModelThe number of electrons in each of lanthanum's shells is [2, 8, 18, 18, 9, 2] and its electron configuration is [Xe] 5d1 6s2. The lanthanum atom has a radius of 187 pm and a Van der Waals radius of 240 pm. Lanthanum was first discovered by Carl Mosander in 1838. In its elemental form, lanthanum has a silvery white appearance.Elemental Lanthanum It is a soft, malleable, and ductile metal that oxidizes easily in air. Lanthanum is the first element in the rare earth or lanthanide series. It is the model for all the other trivalent rare earths and it is the second most abundant of the rare earths after cerium. Lanthanum is found in minerals such as monazite and bastnasite. The name lanthanum originates from the Greek word Lanthaneia, which means 'to lie hidden'.

Recent Research

Simultaneous removal of ammonium and phosphate by alkaline-activated and lanthanum-impregnated zeolite., He, Yinhai, Lin Hai, Dong Yingbo, Liu Quanli, and Wang Liang , Chemosphere, 2016 Sep 2, Volume 164, p.387-395, (2016)

Did Lanthanum Carbonate Improve Prognosis in Patients Requiring Chronic Hemodialysis in the Kawashima Study?, Oka, Yoshinari, Matsuda Hiroaki, and Miyazaki Masashi , Ther Apher Dial, 2016 Sep 16, (2016)

Dehydration of lactic acid to acrylic acid over lanthanum phosphate catalysts: the role of Lewis acid sites., Guo, Zhen, Theng De Sheng, Tang Karen Yuanting, Zhang Lili, Huang Lin, Borgna Armando, and Wang Chuan , Phys Chem Chem Phys, 2016 Sep 14, Volume 18, Issue 34, p.23746-54, (2016)

Insight into mechanism of lanthanum (III) induced damage to plant photosynthesis., Hu, Huiqing, Wang Lihong, Li Yueli, Sun Jingwen, Zhou Qing, and Huang Xiaohua , Ecotoxicol Environ Saf, 2016 May, Volume 127, p.43-50, (2016)

Combined effects of simulated acid rain and lanthanum chloride on chloroplast structure and functional elements in rice., Hu, Huiqing, Wang Lihong, Zhou Qing, and Huang Xiaohua , Environ Sci Pollut Res Int, 2016 May, Volume 23, Issue 9, p.8902-16, (2016)

Phosphate adsorption on lanthanum loaded biochar., Wang, Zhanghong, Shen Dekui, Shen Fei, and Li Tianyu , Chemosphere, 2016 May, Volume 150, p.1-7, (2016)

Lanthanum Nitrate As Electrolyte Additive To Stabilize the Surface Morphology of Lithium Anode for Lithium-Sulfur Battery., Liu, Sheng, Li Guo-Ran, and Gao Xue-Ping , ACS Appl Mater Interfaces, 2016 Mar 30, Volume 8, Issue 12, p.7783-9, (2016)

Refractive index and dispersion control of ultrafast laser inscribed waveguides in gallium lanthanum sulphide for near and mid-infrared applications., Demetriou, Giorgos, Bérubé Jean-Philippe, Vallée Réal, Messaddeq Younes, Petersen Christian R., Jain Deepak, Bang Ole, Craig Chris, Hewak Daniel W., and Kar Ajoy K. , Opt Express, 2016 Mar 21, Volume 24, Issue 6, p.6350-8, (2016)

Impact of Lanthanum Carbonate on Prognosis of Chronic Hemodialysis Patients: A Retrospective Cohort Study (Kawashima Study)., Tsuchida, Kenji, Nagai Kojiro, Yokota Narushi, Minakuchi Jun, and Kawashima Shu , Ther Apher Dial, 2016 Mar 1, (2016)

Adsorption of phosphate from water by easily separable Fe3O4@SiO2 core/shell magnetic nanoparticles functionalized with hydrous lanthanum oxide., Lai, Li, Xie Qiang, Chi Lina, Gu Wei, and Wu Deyi , J Colloid Interface Sci, 2016 Mar 1, Volume 465, p.76-82, (2016)

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