Organometallic rubidium and cesium compounds of the 5,6;11,12-di-o-phenylene-tetracene dianion.

Title Organometallic rubidium and cesium compounds of the 5,6;11,12-di-o-phenylene-tetracene dianion.
Authors T. Wombacher; R. Goddard; C.W. Lehmann; J.J. Schneider
Journal Chem Commun (Camb)
DOI 10.1039/c7cc02320k
Abstract

Twofold reduction of the title molecule 5,6;11,12-di-o-phenylenetetracene (DOPT) with an excess of metallic rubidium and cesium in the presence of strongly coordinating ethers like 18-crown-6-ether (18C6) and tetraglyme results in the formation of the first Rb(i) triple-decker complex and the first Cs(i) coordination polymer of the so far only sparsely studied polyaromatic planar hydrocarbon DOPT. Both compounds are extremely sensitive towards air and water in solution as well as in the solid state. Both compounds exhibit isomerism within their crystal lattices.

Citation T. Wombacher; R. Goddard; C.W. Lehmann; J.J. Schneider.Organometallic rubidium and cesium compounds of the 5,6;11,12-di-o-phenylene-tetracene dianion.. Chem Commun (Camb). 2017;53(52):70307033. doi:10.1039/c7cc02320k

Related Elements

Cesium

See more Cesium products. Cesium (or Caesium) (atomic symbol: Ce, atomic number: 55) is a Block S, Group 1, Period 6 element with an atomic weight of 132.9054519. The number of electrons in each of Cesium's shells is 2, 8, 18, 18, 8, 1 and its electron configuration is [Xe]6s1. Cesium Bohr ModelThe cesium atom has a radius of 265 pm and a Van der Waals radius of 343 pm. Cesium is a member of the alkali group of metals. It is one of three metals that occur as a liquid at room temperature, the others being mercury and gallium. Elemental CesiumCesium's main commercial source is pollucite ore; however, it is also found in beryl, avogadrite, pezzottaite, and londonite. Cesium was discovered by Robert Bunsen and Gustav Kirchhoff in 1860 and first isolated by Carl Setterberg in 1882. In its elemental form, cesium has a silvery gold appearance. The word Cesium originates from the Latin word "caesius," meaning "sky blue," which refers to the vibrant blue lines in its spectrum.

Rubidium

See more Rubidium products. Rubidium (atomic symbol: Rb, atomic number: 37) is a Block S, Group 1, Period 5 element with an atomic weight of 5.4678. The number of electrons in each of Rubidium's shells is [2, 8, 18, 8, 1] and its electron configuration is [Kr] 5s1. The rubidium atom has a radius of 248 pm and a Van der Waals radius of 303 pm. Rubidium Bohr ModelRubidium is highly reactive, with properties similar to other Group 1 alkali metals, e.g., rapid oxidation in air. In its elemental form, rubidium has a gray white appearance. Rubidium is found in the minerals lepidolite, leucite, pollucite, carnallite, and zinnwaldite as well as some potassium minerals. Rubidium was discovered by Robert Bunsen and Gustav Kirchhoff in 1861 and was first isolated by George de Hevesy. The name Rubidium, originates from the Latin word rubidus, meaning "dark or deepest red."

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