Oxidation-reductive coupling of alcohols catalyzed by oxo-vanadium complexes.

Title Oxidation-reductive coupling of alcohols catalyzed by oxo-vanadium complexes.
Authors E. Steffensmeier; K.M. Nicholas
Journal Chem Commun (Camb)
DOI 10.1039/c7cc08387d
Abstract

Oxo-vanadium complexes are found to catalyze the redox disproportionation of benzylic and allylic alcohols, which results in co-production of carbonyl products and reductively coupled hydrocarbon dimers. Preliminary experimental and computational findings suggest the intervention of reduced V-alkoxide species, which undergo facile C-O bond homolysis to produce carbon free radicals, precursors to the hydrocarbon dimers.

Citation E. Steffensmeier; K.M. Nicholas.Oxidation-reductive coupling of alcohols catalyzed by oxo-vanadium complexes.. Chem Commun (Camb). 2018. doi:10.1039/c7cc08387d

Related Elements

Vanadium

See more Vanadium products. Vanadium (atomic symbol: V, atomic number: 23) is a Block D, Group 5, Period 4 element with an atomic weight of 50.9415. Vanadium Bohr ModelThe number of electrons in each of Vanadium's shells is 2, 8, 11, 2 and its electron configuration is [Ar] 3d3 4s2. The vanadium atom has a radius of 134 pm and a Van der Waals radius of 179 pm. Vanadium was discovered by Andres Manuel del Rio in 1801 and first isolated by Nils Gabriel Sefström in 1830. In its elemental form, vanadium has a bluish-silver appearance. Elemental VanadiumIt is a hard, ductile transition metal that is primarily used as a steel additive and in alloys such as Titanium-6AL-4V, which is composed of titanium, aluminum, and vanadium and is the most common titanium alloy commercially produced. Vanadium is found in fossil fuel deposits and 65 different minerals. Vanadium is not found free in nature; however, once isolated it forms an oxide layer that stabilizes the free metal against further oxidation. Vanadium was named after the word "Vanadis" meaning goddess of beauty in Scandinavian mythology.

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