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Potassium Hexabromoiridate(IV)

K2IrBr6

MDL Number:

MFCD00054221

EC No.:

242-827-1

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Potassium Hexabromoiridate(IV)
K-BRI6-02
Pricing > SDS > Data Sheet >
(2N5) 99.5% Potassium Hexabromoiridate(IV)
K-BRI6-025
Pricing > SDS > Data Sheet >
(3N) 99.9% Potassium Hexabromoiridate(IV)
K-BRI6-03
Pricing > SDS > Data Sheet >
(3N5) 99.95% Potassium Hexabromoiridate(IV)
K-BRI6-035
Pricing > SDS > Data Sheet >
(4N) 99.99% Potassium Hexabromoiridate(IV)
K-BRI6-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Potassium Hexabromoiridate(IV)
K-BRI6-05
Pricing > SDS > Data Sheet >

Potassium Hexabromoiridate(IV) Properties

Compound Formula

Br6K2Ir

Molecular Weight

749.86

Appearance

Black crystalline solid

Melting Point

N/A

Boiling Point

N/A

Density

N/A

Exact Mass

750.394223

Monoisotopic Mass

744.400362

Potassium Hexabromoiridate(IV) Health & Safety Information

Signal Word Danger
Hazard Statements H318-H290-H302
Hazard Codes Xn, Xi
Risk Codes 22-36
Safety Statements 26-36-60
RTECS Number N/A
Transport Information N/A
WGK Germany N/A
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 09/23/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Potassium Hexabromoiridate(IV)

Product Number: All applicable American Elements product codes, e.g. K-BRI6-02 , K-BRI6-025 , K-BRI6-03 , K-BRI6-035 , K-BRI6-04 , K-BRI6-05

CAS #: 19121-78-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS05 Corrosion
Met. Corr.1 H290 May be corrosive to metals.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Hazards not otherwise classified No information known.
Label elements
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)

Corrosion - GHS05Exclamation Mark - GHS07

Hazard pictograms
GHS05 GHS07
Signal word Danger
Hazard statements
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/…
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell.
P406 Store in corrosive resistant container with a resistant inner liner.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2B - Toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
2
1
1
Health (acute effects) = 2
Flammability = 1
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
19121-78-9 Potassium hexabromoiridate(IV)
Identification number(s):
EC number: 242-827-1


SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Hydrogen bromide (HBr)
Metal oxide fume
Potassium oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up: Dispose of contaminated material as waste according to section 13.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires: No information known.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility:
Store away from water/moisture.
Do not store together with acids.
Store away from strong bases.
Store away from oxidizing agents.
Store away from metals.
Further information about storage conditions:
Store under dry inert gas.
This product is hygroscopic.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Protect from humidity and water.
Specific end use(s) No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes) Not determined
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Crystalline
Color: Black
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous) Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density: Not determined
Relative density Not determined.
Vapor density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
Water: Not determined
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity No information known.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions Reacts with strong oxidizing agents
Conditions to avoid No further relevant information available.
Incompatible materials:
Acids
Water/moisture
Bases
Oxidizing agents
Metals
Hazardous decomposition products:
Hydrogen bromide
Metal oxide fume
Potassium oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: Harmful if swallowed.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: Causes serious eye damage.
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: No effects known.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, ADN, IMDG, IATA Not applicable
UN proper shipping name
DOT, ADN, IMDG, IATA Not applicable
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class Not applicable
Packing group
DOT, IMDG, IATA Not applicable
Environmental hazards: Not applicable.
Special precautions for user Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": -


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS05 GHS07
Signal word Danger
Hazard statements
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/…
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell.
P406 Store in corrosive resistant container with a resistant inner liner.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
This product is not listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical Substance Inventory. Use of this product is restricted
to research and development only. This product must be used by or directly under the supervision of a technically qualified individual as defined by TSCA. This
product must not be used for commercial purposes or in formulations for commercial purposes.
This product is not listed on the Canadian Domestic Substances List (DSL) or the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings) Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer Substance is not listed.
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Potassium Hexabromoiridate(IV)

Bromide IonPotassium Hexabromoiridate(IV) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Potassium Hexabromoiridate(IV) Synonyms

Dipotassium hexabromoiridate(2-); Dipotassium hexabromoiridate; dipotassium hexabromoiridium; iridate(2-), hexabromo-, potassium (1:2)

Potassium Hexabromoiridate(IV) Chemical Identifiers

Linear Formula

K2IrBr6

Pubchem CID

22555925

MDL Number

MFCD00054221

EC No.

242-827-1

Beilstein Registry No.

N/A

IUPAC Name

dipotassium; hexabromoiridium(2-)

SMILES

[K+].[K+].Br[Ir-2](Br)(Br)(Br)(Br)Br

InchI Identifier

InChI=1S/6BrH.Ir.2K/h6*1H;;;/q;;;;;;+4;2*+1/p-6

InchI Key

RSDYABYRTHADQA-UHFFFAOYSA-H

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Iridium products. Iridium (atomic symbol: Ir, atomic number: 77) is a Block D, Group 9, Period 6 element with an atomic weight of 192.217. The number of electrons in each of iridium's shells is [2, 8, 18, 32, 15, 2] and its electron configuration is [Xe] 4f14 5d7 6s2. Iridium Bohr ModelThe iridium atom has a radius of 136 pm and a Van der Waals radius of 202 pm. Iridium was discovered and first isolated by Smithson Tennant in 1803. In its elemental form, Iridium has a silvery white appearance. Iridium is a member of the platinum group of metals.Elemental Iridium It is the most corrosion resistant metal known and is the second-densest element (after osmium). It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. Iridium is found as an uncombined element and in iridium-osmium alloys. Iridium's name is derived from the Greek goddess Iris, personification of the rainbow, on account of the striking and diverse colors of its salts.

Elemental PotassiumSee more Potassium products. Potassium (atomic symbol: K, atomic number: 19) is a Block S, Group 1, Period 4 element with an atomic weight of 39.0983. The number of electrons in each of Potassium's shells is [2, 8, 8, 1] and its electron configuration is [Ar] 4s1. The potassium atom has a radius of 227.2 pm and a Van der Waals radius of 275 pm. Potassium was discovered and first isolated by Sir Humphrey Davy in 1807. Potassium is the seventh most abundant element on earth. It is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other alkali metals, potassium decomposes in water with the evolution of hydrogen because of its reacts violently with water, it only occurs in nature in ionic salts.Potassium Bohr Model In its elemental form, potassium has a silvery gray metallic appearance, but its compounds (such as potassium hydroxide) are more frequently used in industrial and chemical applications. The origin of the element's name comes from the English word 'potash,' meaning pot ashes, and the Arabic word qali, which means alkali. The symbol K originates from the Latin word kalium.

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