Precisely controlled synthesis of ?-/?-MnO2 materials by adding Zn(acac)2 as a phase transformation-inducing agent.

Title Precisely controlled synthesis of ?-/?-MnO2 materials by adding Zn(acac)2 as a phase transformation-inducing agent.
Authors N. Zhang; L. Li; J. Zhao; T. Yang; G. Zhang; H. He; S. Sun
Journal Chem Commun (Camb)
DOI 10.1039/c7cc08253c
Abstract

In this paper, we present an approach for the precisely controlled phase transformation of MnOin order to synthesise different compositions of ?-/?-MnOmaterials, by adding a trace amount of Zn(acac)as the phase transformation-inducing agent in a hydrothermal reaction. The single-atomic dispersion of Zn might reduce the barrier of phase transformation of ?-MnOto ?-MnO. The ratio of the Zn species present in the single-atomic dispersions and nanoclusters might dominate the generation of ?-MnOand ?-MnO. The results of the oxygen reduction reactions indicate that the MnOmaterials have potential applications as promising catalysts in electrochemical catalysis.

Citation N. Zhang; L. Li; J. Zhao; T. Yang; G. Zhang; H. He; S. Sun.Precisely controlled synthesis of ?-/?-MnO2 materials by adding Zn(acac)2 as a phase transformation-inducing agent.. Chem Commun (Camb). 2018;54(12):14771480. doi:10.1039/c7cc08253c

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Manganese

See more Manganese products. Manganese (atomic symbol: Mn, atomic number: 25) is a Block D, Group 7, Period 4 element with an atomic weight of 54.938045. Manganese Bohr ModelThe number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d5 4s2. The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. Elemental ManganeseIt is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."

Zinc

See more Zinc products. Zinc (atomic symbol: Zn, atomic number: 30) is a Block D, Group 12, Period 4 element with an atomic weight of 65.38. The number of electrons in each of zinc's shells is 2, 8, 18, 2, and its electron configuration is [Ar] 3d10 4s2. Zinc Bohr ModelThe zinc atom has a radius of 134 pm and a Van der Waals radius of 210 pm. Zinc was discovered by Indian metallurgists prior to 1000 BC and first recognized as a unique element by Rasaratna Samuccaya in 800. Zinc was first isolated by Andreas Marggraf in 1746. In its elemental form, zinc has a silver-gray appearance. It is brittle at ordinary temperatures but malleable at 100 °C to 150 °C.Elemental Zinc It is a fair conductor of electricity, and burns in air at high red producing white clouds of the oxide. Zinc is mined from sulfidic ore deposits. It is the 24th most abundant element in the earth's crust and the fourth most common metal in use (after iron, aluminum, and copper). The name zinc originates from the German word "zin," meaning tin.

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