Real-time detection of oxalyl chloride based on a long-lived iridium(iii) probe.

Title Real-time detection of oxalyl chloride based on a long-lived iridium(iii) probe.
Authors C. Wu; G. Li; Q. Bin Han; R.J. Pei; J.B. Liu; D.L. Ma; C.H. Leung
Journal Dalton Trans
DOI 10.1039/c7dt04054g
Abstract

A series of luminescent iridium(iii) complexes were designed and evaluated for their ability to detect oxalyl chloride ((COCl)2) at ambient temperature. In the presence of (COCl)2, a double amidation reaction takes place at the diamino functionality of complex 1, leading to the switching-on of a long-lived red luminescence with a 9-fold enhanced emission. Complex 1 exhibited high sensitivity and selectivity, with a detection limit for (COCl)2 at 32 nM. Additionally, complex 1 can be used to detect (COCl)2 using a simple smartphone, allowing for the portable and real-time monitoring of (COCl)2.

Citation C. Wu; G. Li; Q. Bin Han; R.J. Pei; J.B. Liu; D.L. Ma; C.H. Leung.Real-time detection of oxalyl chloride based on a long-lived iridium(iii) probe.. Dalton Trans. 2017;46(48):1707417079. doi:10.1039/c7dt04054g

Related Elements

Iridium

See more Iridium products. Iridium (atomic symbol: Ir, atomic number: 77) is a Block D, Group 9, Period 6 element with an atomic weight of 192.217. The number of electrons in each of iridium's shells is [2, 8, 18, 32, 15, 2] and its electron configuration is [Xe] 4f14 5d7 6s2. Iridium Bohr ModelThe iridium atom has a radius of 136 pm and a Van der Waals radius of 202 pm. Iridium was discovered and first isolated by Smithson Tennant in 1803. In its elemental form, Iridium has a silvery white appearance. Iridium is a member of the platinum group of metals.Elemental Iridium It is the most corrosion resistant metal known and is the second-densest element (after osmium). It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. Iridium is found as an uncombined element and in iridium-osmium alloys. Iridium's name is derived from the Greek goddess Iris, personification of the rainbow, on account of the striking and diverse colors of its salts.

Chlorine

Chlorine is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s23p5. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. Chlorine ModelIn its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. It has the third highest electronegativity and the highest electron affinity of all elements, making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.

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