Synthesis of Nickel Phosphide Electrocatalysts from Hybrid Metal Phosphonates.

Title Synthesis of Nickel Phosphide Electrocatalysts from Hybrid Metal Phosphonates.
Authors R. Zhang; P.A. Russo; M. Feist; P. Amsalem; N. Koch; N. Pinna
Journal ACS Appl Mater Interfaces
DOI 10.1021/acsami.7b01178
Abstract

Transition-metal phosphides (TMPs) have recently emerged as efficient and inexpensive electrocatalysts for electrochemical water splitting. The synthesis of nanostructured phosphides often involves highly reactive and hazardous phosphorous-containing compounds. Herein, we report the synthesis of nickel phosphides through thermal treatment under H2(5%)/Ar of layered nickel phenylphosphonate (NiPh) or methylphosphonate (NiMe) that act as single-source precursors. Ni12P5, Ni12P5-Ni2P, and Ni2P nanoparticles (NPs) with sizes of ca. 15-45 nm coated with a thin shell of carbonaceous material were produced. Thermogravimetric analysis coupled with mass spectrometry (TG-MS) showed that H2, H2O, P2, and -C6H5 are the main compounds formed during the transformation of the precursor under argon and no hazard phosphorous-containing compounds are created, making this a simple and relatively safe route for fabricating nanostructured TMPs. The H2 most likely reacts with the -PO3 groups of the precursor to form H2O and P2, and the latter subsequently reacts with the metal to produce the phosphide. The Ni12P5-Ni2P and Ni2P NPs efficiently catalyze the hydrogen evolution reaction (HER), with Ni2P showing the best performance and generating a current density of 10 mA cm(-2) at an overpotential of 87 mV and exhibiting long-term stability. Co2P and CoP NPs were also synthesized following this method. This approach may be utilized to explore the rich metal phosphonate chemistry for fabricating phosphide-based materials for electrochemical energy conversion and storage applications.

Citation R. Zhang; P.A. Russo; M. Feist; P. Amsalem; N. Koch; N. Pinna.Synthesis of Nickel Phosphide Electrocatalysts from Hybrid Metal Phosphonates.. ACS Appl Mater Interfaces. 2017;9(16):1401314022. doi:10.1021/acsami.7b01178

Related Elements

Nickel

28 Ni 58.693400000 Nickel

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Phosphorus

15 P 30.973762000 Phosphorus

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Related Forms & Applications

Phosphides
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