Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III)

Yb(TMHD)3

CAS #:

Linear Formula:

C33H57O6Yb

MDL Number:

MFCD00000034

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III)
YB-TMHD3-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III)
YB-TMHD3-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III)
YB-TMHD3-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III)
YB-TMHD3-05
Pricing > SDS > Data Sheet >

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III) Properties (Theoretical)

Compound Formula C33H57O6Yb
Molecular Weight 722.86
Appearance Crystalline
Melting Point 167-169 °C
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass 723.354377
Monoisotopic Mass 723.354377

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III) Health & Safety Information

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Precautionary Statements P262-P280-P305+P351+P338-P304+P340-P403+P233-P501
Risk Codes 36/37/38
Safety Statements 26-37
RTECS Number N/A
Transport Information NONH for all modes of transport
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 04/19/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III)

Product Number: All applicable American Elements product codes, e.g. YB-TMHD3-02 , YB-TMHD3-03 , YB-TMHD3-04 , YB-TMHD3-05

CAS #: 15492-52-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
The substance is not classified according to the Globally Harmonized System (GHS).
Label elements
GHS label elements not applicable
Hazard pictograms not applicable
Signal word not applicable
Hazard statements not applicable
Precautionary statements
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Classification system:
NFPA ratings (scale 0 - 4)
Health = 0
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 - 4)
Health = 0
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS No. Description
15492-52-1 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III),
99% (99.9%-Yb) (REO) [Yb(TMHD)3]


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information: No special measures required.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately rinse with water.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing: If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture No further relevant information available.
Advice for firefighters
Protective equipment: No special measures required.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Not required.
Environmental precautions: No special measures required.
Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling:
Precautions for safe handling No special measures required.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.
Specific end use(s) No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems: No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Breathing equipment: Not required.
Protection of hands:
SProtective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection: Safety glasses


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Crystalline
Color: Whitish
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 167-169 °C (333-336 °F)
Boiling point/Boiling range: dec. 3 °C (dec. 37 °F)
Flash point: Not applicable.
Flammability (solid, gaseous): Product is not flammable
Ignition temperature:
Decomposition temperature: Not determined.
Auto igniting: Not determined.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapor pressure: no data hPa
Density: Not determined.
Relative density Not determined.
Vapor density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
Water: Insoluble.
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
Solvent content:
Organic solvents: 0.0 %
VOC content: 0.0 g/l / 0.00 lb/gl
Solids content: 100.0 %
Other information No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity No further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No further relevant information available.
Incompatible materials: No further relevant information available.
Hazardous decomposition products: No dangerous decomposition products known.


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin: No irritant effect.
on the eye: No irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us.
The substance is not subject to classification.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
Substance is not listed.
NTP (National Toxicology Program)
Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Behavior in environmental systems:
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes: Not known to be hazardous to water.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation: Disposal must be made according to official regulations.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, ADN, IMDG, IATA not regulated
UN proper shipping name
DOT, ADN, IMDG, IATA not regulated
Transport hazard class(es)
DOT, ADN, IMDG, IATA
Class not regulated
Packing group
DOT, IMDG, IATA not regulated
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
UN "Model Regulation": not regulated


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
Substance is not listed.
Section 313 (Specific toxic chemical listings):
Substance is not listed.
TSCA (Toxic Substances Control Act):
Substance is listed.
Proposition 65
Chemicals known to cause cancer:
Substance is not listed.
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
Chemicals known to cause developmental toxicity:
Substance is not listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
Substance is not listed.
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
GHS label elements not applicable
Hazard pictograms not applicable
Signal word not applicable
Hazard statements not applicable
Precautionary statements
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III)

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III) is one of numerous organo-metallic compounds sold by American Elements under the trade name AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III) is generally immediately available in most volumes, including bulk quantities. American Elements can produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available, as is additional technical and safety (MSDS) data. Please contact us for information on lead time and pricing above.

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium(III) Synonyms

Ytterbium(III)-DPM; Yb(TMHD)3; 2,2,6,6-tetramethylheptane-3,5-dione, ytterbium(3+)

Chemical Identifiers

Linear Formula C33H57O6Yb
MDL Number MFCD00000034
EC No. N/A
Beilstein/Reaxys No. N/A
Pubchem CID 44473428
IUPAC Name (Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-olate; ytterbium(3+)
SMILES CC(/C(=C/C(=O)C(C)(C)C)/[O-])(C)C.CC(/C(=C/C(=O)C(C)(C)C)/[O-])(C)C.CC(/C(=C/C(=O)C(C)(C)C)/[O-])(C)C.[Yb+3]
InchI Identifier InChI=1S/3C11H20O2.Yb/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
InchI Key KACMHCBXMZUMQV-LWTKGLMZSA-K

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Ytterbium

See more Ytterbium products. Ytterbium (atomic symbol: Yb, atomic number: 70) is a Block F, Group 3, Period 6 element with an atomic weight of 173.054. Ytterbium Bohr ModelThe number of electrons in each of Ytterbium's shells is [2, 8, 18, 32, 8, 2] and its electron configuration is [Xe]4f14 6s2. The Ytterbium atom has a radius of 176 pm and a Van der Waals radius of 242 pm. Ytterbium was discovered by Jean Charles Galissard de Marignac in 1878 and first isolated by Georges Urbain in 1907.Elemental Ytterbium In its elemental form, ytterbium has a silvery-white color. Ytterbium is found in monazite sand as well as the ores euxenite and xenotime. Ytterbium is named after Ytterby, a village in Sweden. Ytterbium can be used as a source for gamma rays, for the doping of stainless steel, or other active metals. Its electrical resistivity rises under stress, making it very useful for stress gauges that measure the deformation of the ground in the even of an earthquake.

TODAY'S TOP DISCOVERY!

April 19, 2024
Los Angeles, CA
Each business day American Elements' scientists & engineers post their choice for the most exciting materials science news of the day
Researchers develop enzymatic cocktail that can kill tuberculosis-causing mycobacteria

Researchers develop enzymatic cocktail that can kill tuberculosis-causing mycobacteria