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Aluminum Hydride

AlH3
CAS 7784-21-6


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(2N) 99% Aluminum Hydride AL-HID-02 Request Quote
(3N) 99.9% Aluminum Hydride AL-HID-03 Request Quote
(4N) 99.99% Aluminum Hydride AL-HID-04 Request Quote
(5N) 99.999% Aluminum Hydride AL-HID-05 Request Quote

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
AlH3 7784-21-6 5168777 14488 MFCD00000501 232-053-2 alumane N/A [AlH3] InChI=1S/Al.3H AZDRQVAHHNSJOQ-UHFFFAOYSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density Exact Mass Monoisotopic Mass Charge MSDS
H3Al 30.01 Colorless, white, or gray powder 150 °C N/A 1.486 g/cm3 30.005014 30.005014 0 Safety Data Sheet

Hydride IonAluminum Hydride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Hydride compounds are used often used as portable sources of hydrogen gas. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Aluminum (Al) atomic and molecular weight, atomic number and elemental symbolAluminum, also known as Aluminium, (atomic symbol: Al, atomic number: 13) is a Block P, Group 13, Period 3 element with an atomic weight of 26.9815386. It is the third most abundant element in the earth's crust and the most abundant metallic element.Aluminum Bohr ModelAluminum's name is derived from alumina, the mineral from which Sir Humphrey Davy attempted to refine it from in 1812. It wasn't until 1825 that Aluminum was first isolated by Hans Christian Oersted. Aluminum is a silvery gray metal that possesses many desirable characteristics. It is light, nonmagnetic and non-sparking. It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Elemental Aluminum Although it has only 60% of the electrical conductivity of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements it imparts a variety of useful properties. Aluminum was first predicted by Antoine Lavoisierin 1787 and first isolated by Friedrich Wöhler in 1827. For more information on aluminum, including properties, safety data, research, and American Elements' catalog of aluminum products, visit the Aluminum element page.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Precautions N/A
RTECS Number BD0930000
Transport Information UN 2463 4.3/PG I
WGK Germany N/A
Globally Harmonized System of
Classification and Labelling (GHS)
N/A        

ALUMINUM HYDRIDE SYNONYMS
Trihydridoaluminium; Alumane; aluminium trihydride; Aluminium(III) hydride; aluminum trihydride; alane

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Aluminum

  • Non-specific phospholipase C4 mediates response to aluminum toxicity in Arabidopsis thaliana. Pejchar P, Potocký M, Kr?ková Z, Brouzdová J, Dan?k M, Martinec J. Front Plant Sci. 2015 Feb 16
  • Homocatenation of Aluminum: Alkane-like Structures of Li2 Al2 H6 and Li3 Al3 H8. Gish JT, Popov IA, Boldyrev AI. Chemistry. 2015 Mar 4.
  • Treatment of Melasma in Men With Low-Fluence Q-Switched Neodymium-Doped Yttrium-Aluminum-Garnet Laser Versus Combined Laser and Glycolic Acid Peeling. Vachiramon V, Sahawatwong S, Sirithanabadeekul P. Dermatol Surg. 2015 Mar 9.
  • Energetics of Order-Disorder in Layered Magnesium Aluminum Double Hydroxides with Interlayer Carbonate. Shivaramaiah R, Navrotsky A. Inorg Chem. 2015 Mar 9.
  • Real Time Monitoring of Layer-by-Layer Polyelectrolyte Deposition and Bacterial Enzyme Detection in Nanoporous Anodized Aluminum Oxide. Krismastuti FS, Bayat H, Voelcker NH, Schönherr H. Anal Chem. 2015 Mar 12.
  • Fabrication of SERS-Active Substrates using Silver Nanofilm-Coated Porous Anodic Aluminum Oxide for Detection of Antibiotics. Chen J, Feng S, Gao F, Grant E, Xu J, Wang S, Huang Q, Lu X. J Food Sci. 2015 Mar 3.
  • Cytotoxic and genotoxic characterization of aluminum and silicon oxide nanoparticles in macrophages. Hashimoto M, Imazato S. Dent Mater. 2015 Mar 5.
  • Hybrid Structures of Polycationic aluminum phthalocyanines and quantum dots. Maksimov EG, Gvozdev DA, Strakhovskaya MG, Paschenko VZ. Biochemistry (Mosc). 2015 Mar
  • The influence of gingerol treatment on aluminum toxicity in rats. Shrivastava S. J Environ Pathol Toxicol Oncol. 2015
  • Theoretical and experimental studies on the corrosion inhibition potentials of some purines for aluminum in 0.1 M HCl. Eddy NO, Momoh-Yahaya H, Oguzie EE. J Adv Res. 2015 Mar
  • A method of lyophilizing vaccines containing aluminum salts into a dry powder without causing particle aggregation or decreasing the immunogenicity following reconstitution. Li X, Thakkar SG, Ruwona TB, Williams RO 3rd, Cui Z. J Control Release. 2015 Feb 28
  • Chitosan-aluminum monostearate composite sponge dressing containing asiaticoside for wound healing and angiogenesis promotion in chronic wound. Phaechamud T, Yodkhum K, Charoenteeraboon J, Tabata Y. Mater Sci Eng C Mater Biol Appl. 2015 May
  • Magnesium uptake of Arabidopsis transporters, AtMRS2-10 and AtMRS2-11, expressed in Escherichia coli mutants: Complementation and growth inhibition by aluminum. Ishijima S, Uda M, Hirata T, Shibata M, Kitagawa N, Sagami I. Biochim Biophys Acta. 2015 Mar 12.
  • Phosphorylation and Interaction with the 14-3-3 Protein of the Plasma Membrane H+-ATPase Are Involved in the Regulation of Magnesium-Mediated Increases in Aluminum-Induced Citrate Exudation in Broad Bean (Vicia faba. L). Chen Q, Kan Q, Wang P, Yu W, Yu Y, Zhao Y, Yu XY, Li ZK, Chen ML. Plant Cell Physiol. 2015 Mar 5.
  • Mechanisms on Boron-Induced Alleviation of Aluminum-Toxicity in Citrus grandis Seedlings at a Transcriptional Level Revealed by cDNA-AFLP Analysis. Zhou XX, Yang LT, Qi YP, Guo P, Chen LS. PLoS One. 2015 Mar 6
  • Measurement of critical currents of superconducting aluminum nanowires in external magnetic fields: evidence for a weber blockade. Morgan-Wall T, Leith B, Hartman N, Rahman A, Markovi? N. Phys Rev Lett. 2015 Feb 20
  • The Metal-Organic Framework MIL-53(Al) Constructed from Multiple Metal Sources: Alumina, Aluminum Hydroxide, and Boehmite. Li Z, Wu YN, Li J, Zhang Y, Zou X, Li F. Chemistry. 2015 Mar 10.
  • Isobaric tags for relative and absolute quantitation (iTRAQ)-based proteomic analysis of Cryptococcus humicola response to aluminum stress. Zhang J, Zhang L, Qiu J, Nian H. J Biosci Bioeng. 2015 Mar 3.
  • ZnO-based thin film transistors employing aluminum titanate gate dielectrics deposited by spray pyrolysis at ambient air. Afouxenidis D, Mazzocco R, Vourlias G, Livesley PJ, Krier A, Milne WI, Kolosov OV, Adamopoulos G. ACS Appl Mater Interfaces. 2015 Mar 16.
  • Triple-layer Fabry-Perot/SPP aluminum absorber in the visible and near-infrared region. Shu S, Li YY. Opt Lett. 2015 Mar 15

Recent Research & Development for Hydrides

  • Subporphyrins: Hydride enters the ring. Pichon A. Nat Chem. 2015 Feb 20
  • Insights into the origin of the separation selectivity with silica hydride adsorbents. Kulsing C, Nolvachai Y, Marriott PJ, Boysen RI, Matyska MT, Pesek JJ, Hearn MT. J Phys Chem B. 2015 Feb 19
  • Ruthenium-Catalyzed C?C Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination. Sam B, Luong T, Krische MJ. Angew Chem Int Ed Engl. 2015 Mar 10.
  • Exploring σ-hole bonding in XH3Si···HMY (X=H, F, CN
  • The free-energy barrier to hydride transfer across a dipalladium complex. Vanston CR, Kearley GJ, Edwards AJ, Darwish TA, de Souza NR, Ramirez-Cuesta AJ, Gardiner MG. Faraday Discuss. 2015 Feb 5.
  • True Boundary for the Formation of Homoleptic Transition-Metal Hydride Complexes. Takagi S, Iijima Y, Sato T, Saitoh H, Ikeda K, Otomo T, Miwa K, Ikeshoji T, Aoki K, Orimo SI. Angew Chem Int Ed Engl. 2015 Mar 13.
  • Reactions of phenylacetylene with nickel POCOP-pincer hydride complexes resulting in different outcomes from their palladium analogues. Wilson GL, Abraha M, Krause JA, Guan H. Dalton Trans. 2015 Mar 16.
  • Mechanisms of Reactions of Sulfur Hydride Hydroxide: Tautomerism, Condensations, and C-Sulfenylation and O-Sulfenylation of 2,4-Pentanedione. Freeman F. J Phys Chem A. 2015 Mar 12.
  • Improvement in thallium hydride generation using iodide and Rhodamine B. Picón D, Carrero P, Valero M, de Peña YP, Gutiérrez L. Talanta. 2015 May
  • A pyrazolate-stabilized sodium hydride complex. Stasch A. Chem Commun (Camb). 2015 Mar 10
  • The Unexpected Mechanism Underlying the High-Valent Mono-Oxo-Rhenium(V) Hydride Catalyzed Hydrosilylation of C?N Functionalities: Insights from a DFT Study. Wang J, Wang W, Huang L, Yang X, Wei H. Chemphyschem. 2015 Feb 20.
  • Transition-Metal-Free Coupling Reaction of Vinylcyclopropanes with Aldehydes Catalyzed by Tin Hydride. Ieki R, Kani Y, Tsunoi S, Shibata I. Chemistry. 2015 Mar 5.
  • Predicting the reactivity of hydride donors in water: thermodynamic constants for hydrogen. Connelly SJ, Wiedner ES, Appel AM. Dalton Trans. 2015 Feb 20.
  • Discrete Magnesium Hydride Aggregates: A Cationic Mg13 H18 Cluster Stabilized by NNNN-Type Macrocycles. Martin D, Beckerle K, Schnitzler S, Spaniol TP, Maron L, Okuda J. Angew Chem Int Ed Engl. 2015 Feb 4.
  • On the coupling of hydride generation with atmospheric pressure glow discharge in contact with the flowing liquid cathode for the determination of arsenic, antimony and selenium with optical emission spectrometry. Greda K, Jamroz P, Jedryczko D, Pohl P. Talanta. 2015 May
  • Hydride-Induced Anionic Cyclization: An Efficient Method for the Synthesis of 6-H-Phenanthridines via a Transition-Metal-Free Process. Chen WL, Chen CY, Chen YF, Hsieh JC. Org Lett. 2015 Mar 12.
  • Hylleraas hydride binding energy: diatomic electron affinities. Chen ES, Keith H, Lim T, Pham D, Rosenthal R, Herder C, Pai S, Flores RA, Chen EC. J Mol Model. 2015 Apr
  • Reversible metal-hydride phase transformation in epitaxial films. Roytburd AL, Boyerinas BM, Bruck HA. J Phys Condens Matter. 2015 Mar 11
  • Thermodynamically neutral Kubas-type hydrogen storage using amorphous Cr(iii) alkyl hydride gels. Morris L, Trudeau ML, Reed D, Book D, Antonelli DM. Phys Chem Chem Phys. 2015 Mar 13.
  • Synthesis and Characterization of a Cu14 Hydride Cluster Supported by Neutral Donor Ligands. Nguyen TA, Goldsmith BR, Zaman HT, Wu G, Peters B, Hayton TW. Chemistry. 2015 Feb 20.