Cerium Hydride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Hydride compounds are used often used as portable sources of hydrogen gas.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Cerium is a Block F, Group 3, Period 6 element. The number of electrons in each of Cerium's shells is 2, 8, 18, 19, 9, 2 and its electronic configuration is [Xe]4f2 6s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is moderately toxic. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueoussolutions.It is, therefore, strongly acidic and moderately toxic. It is also a strong oxidizer.The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolor glass by keeping iron in its ferrous state. The ability of cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass.
Cerium was first discovered by W. von Hisinger in 1903. The element was named after the asteroid Ceres. See Cerium research below.
Hydrogen is a Block S, Group 1, Period 1 element. The electronic configuration is 1s1. In its elemental form hydrogen's CAS number is 1333-74-0. The hydrogen atom has a radius of 37.3.pm and it's Van der Waals radius is 120.pm. Hydrogen is highly flammable. Hydrogen was discovered by Sir Henry Cavendish in 1766.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Retraction notice to "Characterization and mechanistic analysis of the visible light response of cerium and nitrogen co-doped TiO2 nano-photocatalyst synthesized using a one-step technique" [Journal of Hazardous Materials 176 (2010) 829-835]. J Hazard Mater. 2010 Oct 15;182(1-3):945. PubMed PMID: 20737669.
High-throughput continuous hydrothermal flow synthesis of Zn-Ce oxides: unprecedented solubility of Zn in the nanoparticle fluorite lattice. Kellici S, Gong K, Lin T, Brown S, Clark RJ, Vickers M, Cockcroft JK, Middelkoop V, Barnes P, Perkins JM, Tighe CJ, Darr JA. Philos Transact A Math Phys Eng Sci. 2010 Sep 28;368(1927):4331-49. PubMed PMID: 20732890.
Can simple salts influence self-assembly in oil? Multivalent cations as efficient gelators of lecithin organosols. Lee HY, Diehn KK, Ko SW, Tung SH, Raghavan SR. Langmuir. 2010 Sep 7;26(17):13831-8. PubMed PMID: 20677736.
Cytogenetic and developmental toxicity of cerium and lanthanum to sea urchin embryos. Oral R, Bustamante P, Warnau M, D'Ambra A, Guida M, Pagano G. Chemosphere. 2010 Sep;81(2):194-198. Epub 2010 Aug 4. PubMed PMID: 20688349.
Development and validation of fixed-time method for the determination of isoxsuprine hydrochloride in commercial dosages forms. Rahman N, Afaq N. Drug Test Anal. 2010 Sep 1. [Epub ahead of print] PubMed PMID: 20812296.
Cerium Relieves the Inhibition of Chlorophyll Biosynthesis of Maize Caused by Magnesium Deficiency. Zhou M, Gong X, Ying W, Chao L, Hong M, Wang L, Fashui H. Biol Trace Elem Res. 2010 Aug 27. [Epub ahead of print] PubMed PMID: 20798996.
Determination of cerium ion by polymeric membrane and coated graphite electrode based on novel pendant armed macrocycle. Singh AK, Singh P. Anal Chim Acta. 2010 Aug 24;675(2):170-180. Epub 2010 Jul 21. PubMed PMID: 20800729.
Aggregation Control of Hydrophilic Maghemite (gamma-Fe(2)O(3)) Nanoparticles by Surface Doping Using Cerium Atoms. Haviv AH, Grene`che JM, Lellouche JP. J Am Chem Soc. 2010 Aug 24. [Epub ahead of print] PubMed PMID: 20735060.
Ceria maintains smaller metal catalyst particles by strong metal-support bonding. Farmer JA, Campbell CT. Science. 2010 Aug 20;329(5994):933-6. PubMed PMID: 20724631.
Effect of natural organic matter on cerium dioxide nanoparticles settling in model fresh water. Quik JT, Lynch I, Hoecke KV, Miermans CJ, Schamphelaere KA, Janssen CR, Dawson KA, Stuart MA, Meent DV. Chemosphere. 2010 Aug 19. [Epub ahead of print] PubMed PMID: 20728203.
Redox-active radical scavenging nanomaterials. Karakoti A, Singh S, Dowding JM, Seal S, Self WT. Chem Soc Rev. 2010 Aug 17. [Epub ahead of print] PubMed PMID: 20717560.
Methanol adsorption and decomposition on Pt/CeO2(111)/Cu(111) thin film model catalyst. Matolín V, Johánek V, Skoda M, Tsud N, Prince KC, Skála T, Matolínová I. Langmuir. 2010 Aug 17;26(16):13333-41. PubMed PMID: 20695575.
Covalency in Ce(IV) and U(IV) Halide and N-Heterocyclic Carbene Bonds. Arnold PL, Turner ZR, Kaltsoyannis N, Pelekanaki P, Bellabarba RM, Tooze RP. Chemistry. 2010 Aug 16;16(31):9623-9. PubMed PMID: 20658507.
Virus removal by biogenic cerium. De Gusseme B, Du Laing G, Hennebel T, Renard P, Chidambaram D, Fitts JP, Bruneel E, Van Driessche I, Verbeken K, Boon N, Verstraete W. Environ Sci Technol. 2010 Aug 15;44(16):6350-6. PubMed PMID: 20704235.
Unveiling the mechanism of uptake and sub-cellular distribution of cerium oxide nanoparticles. Singh S, Kumar A, Karakoti A, Seal S, Self WT. Mol Biosyst. 2010 Aug 9. [Epub ahead of print] PubMed PMID: 20697616.
Surface-Charge-Dependent Cell Localization and Cytotoxicity of Cerium Oxide Nanoparticles. Asati A, Santra S, Kaittanis C, Perez JM. ACS Nano. 2010 Aug 6. [Epub ahead of print] PubMed PMID: 20690607.
Multicolored redox active upconverter cerium oxide nanoparticle for bio-imaging and therapeutics. Babu S, Cho JH, Dowding JM, Heckert E, Komanski C, Das S, Colon J, Baker CH, Bass M, Self WT, Seal S. Chem Commun (Camb). 2010 Aug 4. [Epub ahead of print] PubMed PMID: 20683524.
Effect of Cerium on Photosynthetic Pigments and Photochemical Reaction Activity in Soybean Seedling Under Ultraviolet-B Radiation Stress. Liang C, Zhang G, Zhou Q. Biol Trace Elem Res. 2010 Aug 3. [Epub ahead of print] PubMed PMID: 20680511.
[Antiviral effect of cerium dioxide nanoparticles stabilized by low-molecular polyacrylic acid]. Mikrobiol Z. 2010 May-Jun;72(3):42-7. Russian. PubMed PMID: 20695228.
Non-FokI-based zinc finger nucleases. Imanishi M, Negi S, Sugiura Y. Methods Mol Biol. 2010;649:337-49. PubMed PMID: 20680845.
Recent Research & Development for Hydride
Diazaphospholenes: N-Heterocyclic Phosphines between Molecules and
Lewis Pairs. Gudat D. Acc Chem Res. 2010 Jun 24. [Epub ahead of print] PubMed PMID:
20572668.
Thymidylate Synthase Catalyzed H-Transfers: Two Chapters in
One Tale. Wang Z, Kohen A. J Am Chem Soc. 2010 Jun 24. [Epub ahead of print] PubMed PMID:
20575541.
Cobalt-Mediated Linear 2:1 Co-oligomerization of Alkynes with Enol Ethers to Give
1-Alkoxy-1,3,5-Trienes: A Missing Mode of Reactivity. Lebœuf D, Iannazzo L, Geny A, Malacria M, Vollhardt KP, Aubert C, Gandon V. Chemistry. 2010 Jun 23.
[Epub ahead of print] PubMed PMID: 20575116.
Synthesis and evaluation of silica
hydride-based fluorinated stationary phases. Pesek JJ, Matyska MT, Prajapati KV. J Sep Sci. 2010 Jun 22. [Epub ahead
of print] PubMed PMID: 20572267.
Kinetics of substituted
silylene addition and elimination in silicon nanocluster growth captured by group
additivity. Adamczyk AJ, Reyniers MF, Marin GB, Broadbelt LJ. Chemphyschem. 2010 Jun 21;11(9):1978-94. PubMed PMID: 20549662.
Synthesis of 2-Boryl- and Silylindoles
by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl
Isocyanides. Tobisu M, Fujihara H, Koh K, Chatani N. J Org Chem. 2010 Jun 17. [Epub ahead of print] PubMed PMID:
20557065.
Thermal Decomposition of Mono- and
Bimetallic Magnesium Amidoborane Complexes. Spielmann J, Piesik DF, Harder S. Chemistry. 2010 Jun 16. [Epub ahead
of print] PubMed PMID: 20564288.
Versatile New C(3)-Symmetric Tripodal Tetraphosphine Ligands; Structural
Flexibility to Stabilize Cu(I) and Rh(I) Species and Tune Their Reactivity. Wassenaar J, Siegler MA, Spek AL, de Bruin B, Reek JN, van der Vlugt JI. Inorg
Chem. 2010 Jun 16. [Epub ahead of print] PubMed PMID: 20552965.
Iron-Catalyzed Hydrogen Production from Formic Acid. Boddien A, Loges B, Ga¨rtner F, Torborg C, Fumino K, Junge H, Ludwig R, Beller
M. J Am Chem Soc. 2010 Jun
15. [Epub ahead of print] PubMed PMID: 20550131.
Intermolecular Dehydrative Coupling Reaction of Arylketones
with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride
Complex: A Novel Ketone Olefination Method via Vinyl C-H Bond Activation.
Yi CS, Lee DW. Organometallics. 2010 Mar 19;29(8):1883-1885. PubMed PMID: 20567607; PubMed
Central PMCID: PMC2887707.
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