Embonic Acid Functionalized Niobium Complexes with Selective Dye Sorption Properties.

Title Embonic Acid Functionalized Niobium Complexes with Selective Dye Sorption Properties.
Authors L.B. Yuan; Y.P. He; L. Zhang; J. Zhang
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.7b03265
Abstract

Presented here are binuclear Nb, tetranuclear TiNb, and dodecanuclear Nb complexes decorated by embonic acid ligands. These structures feature a unique Ti-O-Nb or Nb-O-Nb subunit. Besides, the unprecedented dodecanuclear Nb cluster further displays a porous three-dimensional packing framework and stability in water, affording an interesting selective uptake for methylene blue molecules over rhodamine B.

Citation L.B. Yuan; Y.P. He; L. Zhang; J. Zhang.Embonic Acid Functionalized Niobium Complexes with Selective Dye Sorption Properties.. Inorg Chem. 2018;57(8):42264229. doi:10.1021/acs.inorgchem.7b03265

Related Elements

Niobium

See more Niobium products. Niobium (atomic symbol: Nb, atomic number: 41) is a Block D, Group 5, Period 5 element with an atomic weight of 92.90638. Niobium Bohr ModelThe number of electrons in each of niobium's shells is 2, 8, 18, 12, 1 and its electron configuration is [Kr] 4d4 5s1. The niobium atom has a radius of 146 pm and a Van der Waals radius of 207 pm. Niobium was discovered by Charles Hatchett in 1801 and first isolated by Christian Wilhelm Blomstrand in 1864. In its elemental form, niobium has a gray metallic appearance. Niobium has the largest magnetic penetration depth of any element and is one of three elemental type-II superconductors (Elemental Niobiumalong with vanadium and technetium). Niobium is found in the minerals pyrochlore, its main commercial source, and columbite. The word Niobium originates from Niobe, daughter of mythical Greek king Tantalus.

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