Iridium Potassium Cyanide is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. Iridium Potassium Cyanide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.
Iridium is a Block D, Group 9, Period 6 element. The number of electrons in each of Iridium's shells is 2, 8, 18, 32, 15, 2 and its electronic configuration is [Xe] 4f14 5d7 6s2. In its elemental form iridium's CAS number is 7439-88-5. The iridium atom has a radius of 135.7.pm and it's Van der Waals radius is 200.pm. Iridium is only slightly toxic. Iridium is a member of the platinum group of metals. It is the most corrosion resistant metal known. It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. It is alloyed with platinum to produce highly corrosive resistant electrical contacts for spark plugs. Iridium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Iridium information, including Technical Data, Safety Data and its high purityproperties, research, applications and other useful facts are discussed here. Iridium was first discovered by Smithson Tennant in 1804. See Iridium research below.
Potassium is a Block S, Group 1, Period 4 element. The number of electrons in each of Potassium's shells is 2, 8, 8, 1 and its electronic configuration is [Ar] 4s1. In its elemental form potassium's CAS number is 7440-09-7. The potassium atom has a radius of 227.2 .pm and it's Van der Waals radius is 275.pm. Potassium is not toxic. Potassium is the seventh most abundant element on earth. In its metallic form it is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other metals of the alkali group, the metal decomposes in water with the evolution of hydrogen. It catches fire spontaneously in water. In high purity, potassium compounds have numerous pharmacological, medical, and electronics applications. Important compounds include the hydroxide, nitrate, carbonate, chloride, bromide, iodide, and sulfate. Lower purity compounds are used in pyrotechnics for its violet color on ignition and in glass and ceramic glazes to produce this color. Potassium also used as a nutrient in plant growth. Potassium was first discovered by Sir Humphrey Davy in 1807. The origin of the element name comes from the English word 'potash' meaning pot ashes and the Arabic word 'qali' which means alkali. The symbol K originates from the Latin word 'kalium'. See Potassium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Determination of the relative ligand-binding strengths in heteroleptic Ir(III) complexes by ESI-Q-TOF tandem mass spectrometry.
Altuntas E, Winter A, Baumgaertel A, Paulus RM, Ulbricht C, Crecelius AC, Risch N, Schubert US.
J Mass Spectrom. 2012 Jan;47(1):34-40. doi: 10.1002/jms.2023.
PMID:
22282087
[PubMed - in process]
Ir(3)Co(6) and Co(3)Fe(3) Dithiolene Cluster Complexes: Multiple Metal-Metal Bond Formation and Correlation between Structure and Internuclear Electronic Communication.
Tsukada S, Shibata Y, Sakamoto R, Kambe T, Ozeki T, Nishihara H.
Inorg Chem. 2012 Jan 26. [Epub ahead of print]
PMID:
22280498
[PubMed - as supplied by publisher]
Bright Blue Phosphorescence from Cationic Bis-Cyclometalated Iridium(III) Isocyanide Complexes.
Shavaleev NM, Monti F, Costa RD, Scopelliti R, Bolink HJ, Ortí E, Accorsi G, Armaroli N, Baranoff E, Grätzel M, Nazeeruddin MK.
Inorg Chem. 2012 Jan 26. [Epub ahead of print]
PMID:
22280407
[PubMed - as supplied by publisher]
IrO2-Based Disperse-Phase Electrocatalysts: A Complementary Study by Means of the Cavity-Microelectrode and the ex-Situ X-ray Absorption Spectroscopy.
Minguzzi A, Locatelli C, Cappelletti G, Scavini M, Vertova A, Ghigna PF, Rondinini S.
J Phys Chem A. 2012 Jan 27. [Epub ahead of print]
PMID:
22280059
[PubMed - as supplied by publisher]
Synthesis and optoelectronic properties of a heterobimetallic Pt(ii)-Ir(iii) complex used as a single-component emitter in white PLEDs.
Li X, Liu Y, Luo J, Zhang Z, Shi D, Chen Q, Wang Y, He J, Li J, Lei G, Zhu W.
Dalton Trans. 2012 Jan 25. [Epub ahead of print]
PMID:
22278126
[PubMed - as supplied by publisher]
Stepwise Formation of Iridium(III) Complexes with Monocyclometalating and Dicyclometalating Phosphorus Chelates.
Lin CH, Lin CY, Hung JY, Chang YY, Chi Y, Chung MW, Chang YC, Liu C, Pan HA, Lee GH, Chou PT.
Inorg Chem. 2012 Jan 24. [Epub ahead of print]
PMID:
22272818
[PubMed - as supplied by publisher]
General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes.
Kuznetsov A, Gevorgyan V.
Org Lett. 2012 Jan 24. [Epub ahead of print]
PMID:
22272663
[PubMed - as supplied by publisher]
Patterns of Radiotherapy Practice for Patients with Cervical Cancer in Japan, 2003-2005: Changing Trends in the Pattern of Care Process.
Tomita N, Toita T, Kodaira T, Shinoda A, Uno T, Numasaki H, Teshima T, Mitsumori M.
Int J Radiat Oncol Biol Phys. 2012 Jan 21. [Epub ahead of print]
PMID:
22270160
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Bright electrochemiluminescence of iridium(iii) complexes.
Swanick KN, Ladouceur S, Zysman-Colman E, Ding Z.
Chem Commun (Camb). 2012 Jan 19. [Epub ahead of print]
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22262342
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Turning on Red and Near-Infrared Phosphorescence in Octahedral Complexes with Metalated Quinones.
Damas A, Ventura B, Moussa J, Esposti AD, Chamoreau LM, Barbieri A, Amouri H.
Inorg Chem. 2012 Jan 19. [Epub ahead of print]
PMID:
22260200
[PubMed - as supplied by publisher]
Reactions of Hydridoirida-ß-diketones with Amines or with 2-Aminopyridines: Formation of Hydridoirida-ß-ketoimines, PCN Terdentate Ligands, and Acyl Decarbonylation.
Ciganda R, Garralda MA, Ibarlucea L, Mendicute-Fierro C, Torralba MC, Torres MR.
Inorg Chem. 2012 Jan 18. [Epub ahead of print]
PMID:
22257029
[PubMed - as supplied by publisher]
Overview of the boston retinal prosthesis: Challenges and opportunities to restore useful vision to the blind.
Rizzo JF, Shire DB, Kelly SK, Troyk P, Gingerich M, McKee B, Priplata A, Chen J, Drohan W, Doyle P, Mendoza O, Theogarajan L, Cogan S, Wyatt JL.
Conf Proc IEEE Eng Med Biol Soc. 2011 Aug;2011:7492-5.
PMID:
22256071
[PubMed - in process]
A dual-shank neural probe integrated with double waveguides on each shank for optogenetic applications.
Im M, Cho IJ, Wu F, Wise KD, Yoon E.
Conf Proc IEEE Eng Med Biol Soc. 2011 Aug;2011:5480-3.
PMID:
22255578
[PubMed - in process]
Electrical performance of penetrating microelectrodes chronically implanted in cat cortex.
Kane SR, Cogan SF, Ehrlich J, Plante TD, McCreery DB.
Conf Proc IEEE Eng Med Biol Soc. 2011 Aug;2011:5416-9.
PMID:
22255562
[PubMed - in process]
Development of the boston retinal prosthesis.
Rizzo JF, Shire DB, Kelly SK, Troyk P, Gingerich M, McKee B, Priplata A, Chen J, Drohan W, Doyle P, Mendoza O, Theogarajan L, Cogan S, Wyatt JL.
Conf Proc IEEE Eng Med Biol Soc. 2011 Aug;2011:3135-8.
PMID:
22255004
[PubMed - in process]
Surface modification of neural stimulating/recording electrodes with high surface area platinum-iridium alloy coatings.
Petrossians A, Whalen JJ, Weiland JD, Mansfeld F.
Conf Proc IEEE Eng Med Biol Soc. 2011 Aug;2011:3001-4.
PMID:
22254972
[PubMed - in process]
The first neural probe integrated with light source (blue laser diode) for optical stimulation and electrical recording.
Park H, Shin HJ, Cho IJ, Yoon ES, Suh JK, Im M, Yoon E, Kim YJ, Kim J.
Conf Proc IEEE Eng Med Biol Soc. 2011 Aug;2011:2961-4.
PMID:
22254962
[PubMed - in process]
Development of an implantable microstimulation system for chronic DBS in rodents.
Paulat R, Meissner W, Morgenstern R, Kupsch A, Harnack D.
Conf Proc IEEE Eng Med Biol Soc. 2011 Aug;2011:660-2.
PMID:
22254395
[PubMed - in process]
Photonics of a Conjugated Organometallic Pt-Ir Polymer and Its Model Compounds Exhibiting Hybrid CT Excited States.
Soliman AM, Fortin D, Zysman-Colman E, Harvey PD.
Macromol Rapid Commun. 2012 Jan 17. doi: 10.1002/marc.201100721. [Epub ahead of print]
PMID:
22253217
[PubMed - as supplied by publisher]
Detection of intracochlear damage during cochlear implant electrode insertion using extracochlear measurements in the gerbil.
Ahmad FI, Choudhury B, De Mason CE, Adunka OF, Finley CC, Fitzpatrick DC.
Laryngoscope. 2011 Nov 26. doi: 10.1002/lary.22488. [Epub ahead of print]
PMID:
22252968
[PubMed - as supplied by publisher]
[Choice of urinary tract drainage in different age groups of patients with urolithiasis].
[No authors listed]
Urologiia. 2011 Mar-Apr;(2):3-7. Russian.
PMID:
21818867
[PubMed - in process]
Correlation between Serum Electrolytes and Fasting Glucose and Hb1Ac in Saudi Diabetic Patients.
Al-Rubeaan K, Siddiqui K, Abu Risheh K, Hamsirani R, Alzekri A, Alaseem A, Saleh SM, Al-Yami Z, Al-Ghamdi A, Alayed K.
Biol Trace Elem Res. 2011 Aug 5. [Epub ahead of print]
PMID:
21818670
[PubMed - as supplied by publisher]
Safety and efficacy of administering the maximal dose of candesartan in renal transplant recipients.
Okumi M, Kawada N, Ichimaru N, Kitamura H, Abe T, Imamura R, Kojima Y, Kokado Y, Isaka Y, Rakugi H, Nonomura N, Moriyama T, Takahara S.
Clin Exp Nephrol. 2011 Aug 5. [Epub ahead of print]
PMID:
21818547
[PubMed - as supplied by publisher]
Multi-ion detection by one-shot optical sensors using a colour digital photographic camera.
Lapresta-Fernández A, Capitán-Vallvey LF.
Analyst. 2011 Aug 5. [Epub ahead of print]
PMID:
21818486
[PubMed - as supplied by publisher]
Conformational Control of Polysilanes: Use of CH(2) Spacers in the Silicon Backbone.
Wallner A, Hlina J, Wagner H, Baumgartner J, Marschner C.
Organometallics. 2011 Aug 8;30(15):3930-3938. Epub 2011 Jul 11.
PMID:
21818170
[PubMed]
Pancreatic ß-cell prosurvival effects of the incretin hormones involve post-translational modification of Kv2.1 delayed rectifier channels.
Kim SJ, Widenmaier SB, Choi WS, Nian C, Ao Z, Warnock G, McIntosh CH.
Cell Death Differ. 2011 Aug 5. doi: 10.1038/cdd.2011.102. [Epub ahead of print]
PMID:
21818121
[PubMed - as supplied by publisher]
Sodium MRI in a rat migraine model and a NEURON simulation study support a role for sodium in migraine.
Harrington MG, Chekmenev EY, Schepkin V, Fonteh AN, Arakaki X.
Cephalalgia. 2011 Aug 4. [Epub ahead of print]
PMID:
21816771
[PubMed - as supplied by publisher]
Molecular organization of antibiotic amphotericin B in dipalmitoylphosphatidylcholine monolayers induced by K(+) and Na(+) ions: The Langmuir technique study.
Arczewska M, Gagos M.
Biochim Biophys Acta. 2011 Jul 26. [Epub ahead of print]
PMID:
21816134
[PubMed - as supplied by publisher]
Intravenous Administration of Magnesium and Potassium Solution Lowers Energy Levels and Increases Success Rates Electrically Cardioverting Atrial Fibrillation.
Sultan A, Steven D, Rostock T, Hoffmann B, Müllerleile K, Servatius H, Drewitz I, Lüker J, Meyer P, Salukhe T, Willems S.
J Cardiovasc Electrophysiol. 2011 Aug 4. doi: 10.1111/j.1540-8167.2011.02146.x. [Epub ahead of print]
PMID:
21815963
[PubMed - as supplied by publisher]
Splenda(®) Improves Tolerance of Oral Potassium Citrate Supplementation for Prevention of Stone Formation: Results of a Randomized Double-Blind Trial.
Mechlin C, Kalorin C, Asplin J, White M.
J Endourol. 2011 Aug 4. [Epub ahead of print]
PMID:
21815827
[PubMed - as supplied by publisher]
Effects of Nicotine Administration on Striatal Dopamine Signaling after Traumatic Brain Injury in Rats.
Shin SS, Bray ER, Dixon CE.
J Neurotrauma. 2011 Aug 4. [Epub ahead of print]
PMID:
21815786
[PubMed - as supplied by publisher]
Cassia obtusifolia MetE as a Cytosolic Target for Potassium Isolespedezate, a Leaf-Opening Factor of Cassia plants: Target Exploration by a Compact Molecular-Probe Strategy.
Ueda M, Manabe Y, Otsuka Y, Kanzawa N.
Chem Asian J. 2011 Aug 3. doi: 10.1002/asia.201100392. [Epub ahead of print]
PMID:
21815269
[PubMed - as supplied by publisher]
Forming the lunar farside highlands by accretion of a companion moon.
Jutzi M, Asphaug E.
Nature. 2011 Aug 3;476(7358):69-72. doi: 10.1038/nature10289.
PMID:
21814278
[PubMed - in process]
Serotonin nerve terminals in the dorsomedial medulla facilitate sympathetic and ventilatory responses to hemorrhage and peripheral chemoreflex activation.
Kung LH, Scrogin KE.
Am J Physiol Regul Integr Comp Physiol. 2011 Aug 3. [Epub ahead of print]
PMID:
21813868
[PubMed - as supplied by publisher]
Following Federal Guidelines To Increase Nutrient Consumption May Lead To Higher Food Costs For Consumers.
Monsivais P, Aggarwal A, Drewnowski A.
Health Aff (Millwood). 2011 Aug 3. [Epub ahead of print]
PMID:
21813865
[PubMed - as supplied by publisher]
With-No-Lysine Kinase 3 (WNK3) Stimulates Glioma Invasion By Regulating Cell Volume.
Haas BR, Cuddapah VA, Watkins S, Rohn KJ, Dy TE, Sontheimer H.
Am J Physiol Cell Physiol. 2011 Aug 3. [Epub ahead of print]
PMID:
21813709
[PubMed - as supplied by publisher]
Suppression of a Neocortical Potassium Channel Activity by Intracellular Amyloid-{beta} and Its Rescue with Homer1a.
Yamamoto K, Ueta Y, Wang L, Yamamoto R, Inoue N, Inokuchi K, Aiba A, Yonekura H, Kato N.
J Neurosci. 2011 Aug 3;31(31):11100-9.
PMID:
21813671
[PubMed - in process]
Idiopathic Recurrent Calcium Urolithiasis (IRCU): Pathophysiology Evaluated in Light of Oxidative Metabolism, without and with Variation of Several Biomarkers in Fasting Urine and Plasma - A Comparison of Stone-free and -Bearing Male Patients, Emphasizing Mineral, Acid-Base, Blood Pressure and Protein Status.
Schwille PO, Schmiedl A, Manoharan M, Wipplinger J.
Eur J Med Res. 2011 Aug 8;16(8):349-66.
PMID:
21813378
[PubMed - in process]
Washing of irradiated red blood cells in paediatric cardiopulmonary bypass: is it clinically useful? A retrospective audit.
Boks RH, Golab HD, Takkenberg JJ, Bogers AJ.
Eur J Cardiothorac Surg. 2011 Aug 1. [Epub ahead of print]
PMID:
21813284
[PubMed - as supplied by publisher]
Unexpected Alkyl Group Migration in Palladium(II) Benzocarbaporphyrins (?).
Lash TD.
Org Lett. 2011 Aug 3. [Epub ahead of print]
PMID:
21812402
[PubMed - as supplied by publisher]
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