Light-driven hydrogen production from aqueous solutions based on a new Dubois-type nickel catalyst.

Title Light-driven hydrogen production from aqueous solutions based on a new Dubois-type nickel catalyst.
Authors Y. Zhou; S. Yang; J. Huang
Journal Phys Chem Chem Phys
DOI 10.1039/c7cp00247e
Abstract

In this work, we report a new photocatalytic system that links multifunctional semiconductor nanocrystals with emerging water-soluble molecular catalysts made of earth-abundant elements for H2 generation [Ni(P2(R)N2(R'))2(BF4)2](4-), R = Ph, R' = [PhSO3](-) (NiS). This noble metal free hybrid exhibits remarkable catalytic activity with a turnover number of 511 for H2 production and a photon-to-H2 conversion efficiency of 12.5%. The mechanistic insight into such high efficiency in this photocatalytic system was examined using a combination of steady-state emission and time-resolved absorption spectroscopy.

Citation Y. Zhou; S. Yang; J. Huang.Light-driven hydrogen production from aqueous solutions based on a new Dubois-type nickel catalyst.. Phys Chem Chem Phys. 2017;19(11):74717475. doi:10.1039/c7cp00247e

Related Elements

Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

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