Lutetium Acetate is a moderately water soluble crystalline Lutetium source that decomposes to Thorium oxide on heating. It is generally immediately available in most volumes. Acetates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic acetates are inorganic salts of a metal cation and the acetate anion. The acetate anion is a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. Lutetium is used for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG). We also produce Lutetium Acetate Solution.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Lutetium is a Block F, Group 3, Period 6 element. The number of electrons in each of Lutetium's shells is 2, 8, 18, 32, 9, 2 and its electronic configuration is [Xe] 4f15 5d1 6s2. In its elemental form lutetium's CAS number is 7439-94-3. The lutetium atom has a radius of 171.8.pm and it's Van der Waals radius is unknown. Lutetium is not toxic. Lutetium is the last member of the rare earth series. Lutetium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic moment. It also has the smallest metallic radius of any rare earth. It also has the smallest metallic radius of any rare earth. It is perhaps the least naturally abundant of the lanthanides. It is the ideal host for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG) crystals due its lack of a magnetic moment.Lutetium is the last member of the rare earth series. Lutetium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic moment. It also has the smallest metallic radius of any rare earth. Lutetium was first discovered by George Urbain in 1907. The name Lutetium originates from the Latin word Lutetia meaning Paris. See Lutetium research below.
Acetate is an anion used as a ligand in metal complexes. The formula is CH3CO2-, C2H3O2-, or CH3COO-. Metal acetates are used in biology, printing, vinyl acetate in plastic production, volatile organic esters as solvents and cellulose acetate in photographic films and textiles. Cellulose acetate, one of the first synthetic fibers, is often called acetate.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Use of internal scintillator radioactivity to calibrate DOI function of a PET detector with a dual-ended-scintillator readout.
Bircher C, Shao Y.
Med Phys. 2012 Feb;39(2):777.
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Phthalocyanine with a giant dielectric constant.
Yazici A, Unüs N, Altindal A, Salih B, Bekaroglu O.
Dalton Trans. 2012 Feb 7. [Epub ahead of print]
PMID:
22310939
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Towards the Real Octupolar Cube: ABAB Bis(phthalocyaninato)lutetium(III) Complex exhibiting Out-standing Quadratic Hyperpolarizability.
Ayhan MM, Singh A, Hirel C, Gürek AG, Ahsen V, Jeanneau E, Ledoux-Rak I, Zyss J, Andraud C, Bretonničre Y.
J Am Chem Soc. 2012 Feb 6. [Epub ahead of print]
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Rare-Earth-Metal-Hydrocarbyl Complexes Bearing Linked Cyclopentadienyl or Fluorenyl Ligands: Synthesis, Catalyzed Styrene Polymerization, and Structure-Reactivity Relationship.
Jian Z, Cui D, Hou Z.
Chemistry. 2012 Jan 26. doi: 10.1002/chem.201102682. [Epub ahead of print]
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Outpatient therapeutic nuclear oncology.
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Ann Nucl Med. 2012 Jan 7. [Epub ahead of print]
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Poly[tetra-aquadi-?(4)-oxalato-lutetium(III)potassium].
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Acta Crystallogr Sect E Struct Rep Online. 2011 Nov 1;67(Pt 11):m1591. Epub 2011 Oct 22.
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22219822
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Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution.
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Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print]
PMID:
22193863
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Nuclear chemical transformations of ytterbium and lutetium radionuclides following (n,?) and beta decay reactions in Tris(2,2,6,6-tetramethyle-3,5-heptanedionato)Yb(III).
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Appl Radiat Isot. 2011 Dec 6. [Epub ahead of print]
PMID:
22189373
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Influence of cations on the complexation yield of DOTATATE with yttrium and lutetium: a perspective study for enhancing the (90)Y and (177)Lu labeling conditions.
Asti M, Tegoni M, Farioli D, Iori M, Guidotti C, Cutler CS, Mayer P, Versari A, Salvo D.
Nucl Med Biol. 2011 Dec 13. [Epub ahead of print]
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22172388
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A novel compensation method for the anode gain non-uniformity of multi-anode photomultiplier tubes.
Lee CM, Il Kwon S, Ko GB, Ito M, Yoon HS, Lee DS, Hong SJ, Lee JS.
Phys Med Biol. 2012 Jan 7;57(1):191-207.
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Automated Module Radiolabeling of Peptides and Antibodies with Gallium-68, Lutetium-177 and Iodine-131.
De Decker M, Turner JH.
Cancer Biother Radiopharm. 2011 Dec 7. [Epub ahead of print]
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An unusual organoyttrium alkyl complex containing a [C5HMe3(?(3)-CH2)-C5H4N-?]- ligand and an elusive cyclopentadienide-based scandium tuck-over zwitterion obtained by C-H bond activation.
Jian Z, Cui D.
Chemistry. 2011 Dec 16;17(51):14578-85. doi: 10.1002/chem.201102378. Epub 2011 Nov 14.
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Evaluation of 177Lu-DOTA-sst2 antagonist versus 177Lu-DOTA-sst2 agonist binding in human cancers in vitro.
Cescato R, Waser B, Fani M, Reubi JC.
J Nucl Med. 2011 Dec;52(12):1886-90. Epub 2011 Nov 8.
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Reactions of late lanthanide metal atoms and methanol in solid argon: a matrix isolation infrared spectroscopic and theoretical study.
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J Phys Chem A. 2011 Dec 29;115(51):14581-92. Epub 2011 Dec 5.
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Nuclear medicine techniques for the imaging and treatment of neuroendocrine tumours.
Teunissen JJ, Kwekkeboom DJ, Valkema R, Krenning EP.
Endocr Relat Cancer. 2011 Oct 17;18 Suppl 1:S27-51. Print 2011 Oct. Review.
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A Positron Emission Tomograph Based on LSO-APD Modules with a Sampling ADC Read-out System for a Students' Advanced Laboratory Course.
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Material Safety Data Sheet
1 Identification of substance
Product details
Trade name Lutetium acetate
2 Composition/Data on components:
Chemical characterization: Designation: (CAS#)
Lutetium acetate (CAS# 18779-08-3); 100%
Identification number(s):
EINECS Number: 233-241-7
3 Hazards identification
Hazard designation:
Xi Irritant
O Oxidising
Information pertaining to particular dangers for man and environment
R 8 Contact with combustible material may cause fire.
R 36/37/38 Irritating to eyes, respiratory system and skin.
4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing Seek immediate medical advice.
5 Fire fighting measures
Suitable extinguishing agents
Use fire fighting measures that suit the environment.
Special hazards caused by the material, its products of combustion or flue gases:
This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting: Ensure adequate ventilation.
Additional information:
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and storage
Handling
Information for safe handling:
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
Substance/product can reduce the ignition temperature of flammable substances.
This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Storage
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Store away from flammable substances.
Store away from reducing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Components with critical values that require monitoring at the workplace:
Not required.
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Breathing equipment: Use breathing protection with high concentrations.
Protection of hands: Impervious gloves
Eye protection:
Safety glasses
Face protection
Body protection: Protective work clothing.
9 Physical and chemical properties:
General Information
Form: Crystalline aggregates
Colour: White
Smell: Odourless
Value/Range Unit Method
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: Not applicable
Inflammability (solid, gaseous)
Contact with combustible material may cause fire.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Critical values for explosion:
Lower: Not determined
Upper: Not determined
Steam pressure: Not determined
Density Not determined
Solubility in / Miscibility with
Water: Soluble
Fully miscible
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Materials to be avoided: Reducing agents, easily oxidized materials
Dangerous reactions:
Reacts with reducing agents
Reacts with flammable substances
Dangerous products of decomposition: Nitrous vitriol gases
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Irritant for skin and mucous membranes.
on the eye: Irritant effect.
Sensitization: No sensitizing effect known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations for proper disposal.
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
Recommended cleaning agent: Water, if necessary with cleaning agent.
14 Transport information
Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
Code letter and hazard designation of product:
Xi Irritant O Oxidising
Risk phrases:
8 Contact with combustible material may cause fire.
36/37/38 Irritating to eyes, respiratory system and skin.
Safety phrases:
17 Keep away from combustible material.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
National regulations
Information about limitation of use:
For use only by technically qualified individuals.
Employment restrictions concerning young persons must be observed.
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
Lutetium Acetate is a moderately water soluble crystalline Lutetium source that decomposes to Thorium oxide on heating. It is generally immediately available in most volumes. Acetates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic acetates are inorganic salts of a metal cation and the acetate anion. The acetate anion is a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. Lutetium is used for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG). We also produce Lutetium Acetate Solution.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Lutetium is a Block F, Group 3, Period 6 element. The number of electrons in each of Lutetium's shells is 2, 8, 18, 32, 9, 2 and its electronic configuration is [Xe] 4f15 5d1 6s2. In its elemental form lutetium's CAS number is 7439-94-3. The lutetium atom has a radius of 171.8.pm and it's Van der Waals radius is unknown. Lutetium is not toxic. Lutetium is the last member of the rare earth series. Lutetium is available as metal and 
compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic 
moment. It also has the smallest metallic radius of any rare earth. It also has the smallest metallic radius of any rare earth. It is perhaps the least naturally abundant of the lanthanides. It is the ideal host for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG) crystals due its lack of a magnetic moment.Lutetium is the last member of the rare earth series. Lutetium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic moment. It also has the smallest metallic radius of any rare earth. Lutetium was first discovered by George Urbain in 1907. The name Lutetium originates from the Latin word Lutetia meaning Paris. See Lutetium research below. 
