Sandwich-Type NbS2@S@I-Doped Graphene for High-Sulfur-Loaded, Ultrahigh-Rate and Long-Life Lithium-Sulfur Batteries.

Title Sandwich-Type NbS2@S@I-Doped Graphene for High-Sulfur-Loaded, Ultrahigh-Rate and Long-Life Lithium-Sulfur Batteries.
Authors Z. Xiao; Z. Yang; L. Zhang; H. Pan; R. Wang
Journal ACS Nano
DOI 10.1021/acsnano.7b04442
Abstract

Lithium-sulfur batteries practically suffer from short cycling life, low sulfur utilization and safety concerns, particularly at ultrahigh rate and high sulfur loading. To address these problems, we have designed and synthesized a ternary NbS2@S@IG composite consisting of sandwich-type NbS2@S enveloped by iodine-doped graphene (IG). The sandwich-type structure provides an interconnected conductive network and plane-to-point intimate contact between layered NbS2 (or IG) and sulfur particles, enabling sulfur species to be efficiently entrapped and utilized at ultrahigh rates while the structural integrity is well maintained. NbS2@S@IG exhibits prominent high-power charge/discharge performances. Reversible capacities of 195, 107 and 74 mA h g-1 (1.05 mg cm-2) have been achieved after 2000 cycles at ultrahigh rates of 20, 30 and 40 C, respectively, the corresponding average decay rates per cycle are 0.022%, 0.031% and 0.033%, respectively. When the area sulfur loading is increased to 3.25 mg cm-2, the electrode still maintains a high discharge capacity of 405 mAh g-1 after 600 cycles at 1 C. Three half-cells in series assembled with NbS2@S@IG can drive 60 indicators of LED modules after only 18 s of charging. The instantaneous current and power of the device reach 196.9 A g-1 and 1369.7 W g-1, respectively.

Citation Z. Xiao; Z. Yang; L. Zhang; H. Pan; R. Wang.Sandwich-Type NbS2@S@I-Doped Graphene for High-Sulfur-Loaded, Ultrahigh-Rate and Long-Life Lithium-Sulfur Batteries.. ACS Nano. 2017. doi:10.1021/acsnano.7b04442

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Sulfur

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Carbon

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