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Thorium Hydride
ThH2
16689-88-6
Product Product Code Order or Specifications
(2N) 99% Thorium Hydride TH-HID-02 Contact American Elements
(3N) 99.9% Thorium Hydride TH-HID-03 Contact American Elements
(4N) 99.99% Thorium Hydride TH-HID-04 Contact American Elements
(5N) 99.999% Thorium Hydride TH-HID-05 Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
ThH2 16689-88-6 46237069 162404 N/A 254-746-9 molecular hydrogen; thorium N/A [Th].[HH].[HH].[HH] InChI=1S/Th.3H2/h;3*1H OZOODZWRASVGKN-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
H2Th 234.1 N/A 9.5 g/cm3 238.085001 238.085001 0 Safety Data Sheet


Thorium Hydride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Hydride compounds are used often used as portable sources of hydrogen gas.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Thorium(Th) atomic and molecular weight, atomic number and elemental symbol Thorium is a Block F, Group 3, Period 7 element. The number of electrons in each of Thorium's shells is 2, 8, 18, 32, 18, 10, 2 and its electronic configuration is [Rn] 6d2 7s2. In its elemental form thorium's CAS number is 7440-29-1. The thorium atom has a radius of 179.8.pm and it's Van der Waals radius is 200.pm. Thorium is radioactive and can collect in bones which may cause bone cancer several years after exposure. Breathing in substantial amounts of thorium may be lethal. Thorium is a lanthanide (rare earth) material with potential nuclear power applications. Thorium Elemental Thorium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is Thorium Bohr Modelpresently used as a tungsten coating in electronic parts due to its high emission factor. Thorium in the form of its fluoride and oxide is used in advanced optic applications for its high refractive index. It is also used in several other high temperature glass applications, such as in the mantle of lamps and to produce crystal growth crucibles and ampules. Thorium was first discovered by Jons Berzelius in 1828. The name Thorium originates from the Scandinavian god, Thor, the Norse god of war and thunder. See Thorium research below.

Hydrogen is a Block S, Group 1, Period 1 element. The electronic configuration is 1s1. In its elemental form hydrogen's CAS number is 1333-74-0. The hydrogen atom has a radius of 37.3.pm and it's Van der Waals radius is 120.pm. Hydrogen is highly flammable. Hydrogen was discovered by Sir Henry Cavendish in 1766.
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Toxicity
Safety & Handling
             
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
N/A N/A N/A N/A N/A N/A N/A N/A

 

Synonyms for Thorium Hydride Include:


molecular hydrogen; thorium

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 

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Recent Research & Development for Thorium

  • The Th[double bond, length as m-dash]C double bond: an experimental and computational study of thorium poly-carbene complexes. Ren W, Deng X, Zi G, Fang DC. Dalton Trans. 2011 Aug 4. [Epub ahead of print] PMID: 21814698 [PubMed - as supplied by publisher]

  • Synthesis and Characterization of Thorium(IV) Sulfates. Knope KE, Wilson RE, Skanthakumar S, Soderholm L. Inorg Chem. 2011 Aug 3. [Epub ahead of print] PMID: 21812466 [PubMed - as supplied by publisher]

  • Thorium Oxo and Sulfido Metallocenes: Synthesis, Structure, Reactivity, and Computational Studies. Ren W, Zi G, Fang DC, Walter MD. J Am Chem Soc. 2011 Jul 27. [Epub ahead of print] PMID: 21793520 [PubMed - as supplied by publisher]

  • The discoveries of uranium 237 and symmetric fission - From the archival papers of Nishina and Kimura. Ikeda N. Proc Jpn Acad Ser B Phys Biol Sci. 2011;87(7):371-6. PMID: 21785255 [PubMed - in process]

  • Matrix infrared spectroscopic and density functional theoretical investigations on thorium and uranium atom reactions with dimethyl ether. Gong Y, Andrews L. Dalton Trans. 2011 Jul 18. [Epub ahead of print] PMID: 21769368 [PubMed - as supplied by publisher]

  • Tris(tetra-butyl-ammonium) tris-(nitrato-?O,O')tetra-kis-(thio-cyanato-?N)thorium(IV). Lozano-Rodriguez MJ, Thuéry P, Petit S, Copping R, Mustre de Leon J, Den Auwer C. Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m487. Epub 2011 Mar 26. PMID: 21753998 [PubMed]

  • Interaction of thorium(iv) with nitrate in aqueous solution: medium effect or weak complexation? Di Bernardo P, Zanonato P, Rao L, Bismondo A, Endrizzi F. Dalton Trans. 2011 Jul 8. [Epub ahead of print] PMID: 21738949 [PubMed - as supplied by publisher]

  • Should we consider using liquid fluoride thorium reactors for power generation? Cooper N, Minakata D, Begovic M, Crittenden J. Environ Sci Technol. 2011 Aug 1;45(15):6237-8. Epub 2011 Jul 6. No abstract available. PMID: 21732635 [PubMed - in process]

  • Electron correlation and relativistic effects in atomic structure calculations of the thorium atom. Roy SK, Prasad R, Chandra P. J Chem Phys. 2011 Jun 21;134(23):234302. PMID: 21702551 [PubMed - in process]

  • [Dust concentration analysis in non-coal mining. Exposure evaluation based on measurements performed by occupational hygiene laboratories in the years 2001-2005 in Poland]. Bujak-Pietrek S, Mikolajczyk U, Szadkowska-Stanczyk I. Med Pr. 2011;62(2):113-25. Polish. PMID: 21698871 [PubMed - indexed for MEDLINE]

  • A cryogenic beam of refractory, chemically reactive molecules with expansion cooling. Hutzler NR, Parsons MF, Gurevich YV, Hess PW, Petrik E, Spaun B, Vutha AC, Demille D, Gabrielse G, Doyle JM. Phys Chem Chem Phys. 2011 Jun 22. [Epub ahead of print] PMID: 21698321 [PubMed - as supplied by publisher]

  • Proposal for a nuclear gamma-ray laser of optical range. Tkalya EV. Phys Rev Lett. 2011 Apr 22;106(16):162501. Epub 2011 Apr 21. PMID: 21599361 [PubMed - in process]

  • Accumulation and soil-to-plant transfer of radionuclides in the Nile Delta coastal black sand habitats. Hegazy AK, Emam MH. Int J Phytoremediation. 2011 Feb;13(2):140-55. PMID: 21598782 [PubMed - in process]

  • Smart thorium and uranium determination exploiting renewable solid-phase extraction applied to environmental samples in a wide concentration range. Avivar J, Ferrer L, Casas M, Cerdà V. Anal Bioanal Chem. 2011 Jul;400(10):3585-94. Epub 2011 May 14. PMID: 21573729 [PubMed - in process]

  • Gamma-spectrometric analysis of high salinity fluids - how to analyze radionuclides of the thorium decay chain far from radioactive equilibrium? Degering D, Köhler M. Appl Radiat Isot. 2011 Apr 22. [Epub ahead of print] PMID: 21570856 [PubMed - as supplied by publisher]

  • Assessment of radionuclide and metal contamination in a thorium rich area in Norway. Popic JM, Salbu B, Strand T, Skipperud L. J Environ Monit. 2011 Jun;13(6):1730-8. Epub 2011 May 10. PMID: 21556423 [PubMed - in process]

  • Retraction notice to "Immobilization of 5-amino-1,3,4-thiadiazole-thiolonto kanemite for thorium (IV) removal: thermodynamic and equilibrium study" [J. Colloid Interface Sci. 338 (2009) 30-39]. [No authors listed] J Colloid Interface Sci. 2011 May 15;357(2):558. No abstract available. PMID: 21553729 [PubMed - indexed for MEDLINE]

  • EPR evidence for the restricted mobility of NO2 in gamma irradiated thorium nitrate pentahydrate Th(NO3)4·5H2O. Rajeswari B, Kadam RM, Dhawale BA, Babu Y, Natarajan V, Godbole SV. Spectrochim Acta A Mol Biomol Spectrosc. 2011 Aug;79(3):405-11. Epub 2011 Mar 24. PMID: 21524936 [PubMed - in process]

  • Screening of plant species for phytoremediation of uranium, thorium, barium, nickel, strontium and lead contaminated soils from a uranium mill tailings repository in South China. Li GY, Hu N, Ding DX, Zheng JF, Liu YL, Wang YD, Nie XQ. Bull Environ Contam Toxicol. 2011 Jun;86(6):646-52. Epub 2011 Apr 27. PMID: 21523506 [PubMed - indexed for MEDLINE]

  • Background radiation and individual dosimetry in the costal area of Tamil Nadu, India. Matsuda N, Brahmanandhan GM, Yoshida M, Takamura N, Suyama A, Koguchi Y, Juto N, Raj YL, Winsley G, Selvasekarapandian S. Radiat Prot Dosimetry. 2011;146(1-3):314-7. Epub 2011 Apr 18. PMID: 21502300 [PubMed - in process]

 

Recent Research & Development for Hydride

  • Diazaphospholenes: N-Heterocyclic Phosphines between Molecules and Lewis Pairs. Gudat D. Acc Chem Res. 2010 Jun 24. [Epub ahead of print] PubMed PMID: 20572668.

  • Thymidylate Synthase Catalyzed H-Transfers: Two Chapters in One Tale. Wang Z, Kohen A. J Am Chem Soc. 2010 Jun 24. [Epub ahead of print] PubMed PMID: 20575541.

  • Cobalt-Mediated Linear 2:1 Co-oligomerization of Alkynes with Enol Ethers to Give 1-Alkoxy-1,3,5-Trienes: A Missing Mode of Reactivity. Lebœuf D, Iannazzo L, Geny A, Malacria M, Vollhardt KP, Aubert C, Gandon V. Chemistry. 2010 Jun 23. [Epub ahead of print] PubMed PMID: 20575116.

  • Synthesis and evaluation of silica hydride-based fluorinated stationary phases. Pesek JJ, Matyska MT, Prajapati KV. J Sep Sci. 2010 Jun 22. [Epub ahead of print] PubMed PMID: 20572267.

  • Kinetics of substituted silylene addition and elimination in silicon nanocluster growth captured by group additivity. Adamczyk AJ, Reyniers MF, Marin GB, Broadbelt LJ. Chemphyschem. 2010 Jun 21;11(9):1978-94. PubMed PMID: 20549662.

  • Synthesis of 2-Boryl- and Silylindoles by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl Isocyanides. Tobisu M, Fujihara H, Koh K, Chatani N. J Org Chem. 2010 Jun 17. [Epub ahead of print] PubMed PMID: 20557065.

  • Thermal Decomposition of Mono- and Bimetallic Magnesium Amidoborane Complexes. Spielmann J, Piesik DF, Harder S. Chemistry. 2010 Jun 16. [Epub ahead of print] PubMed PMID: 20564288.

  • Versatile New C(3)-Symmetric Tripodal Tetraphosphine Ligands; Structural Flexibility to Stabilize Cu(I) and Rh(I) Species and Tune Their Reactivity. Wassenaar J, Siegler MA, Spek AL, de Bruin B, Reek JN, van der Vlugt JI. Inorg Chem. 2010 Jun 16. [Epub ahead of print] PubMed PMID: 20552965.

  • Iron-Catalyzed Hydrogen Production from Formic Acid. Boddien A, Loges B, Ga¨rtner F, Torborg C, Fumino K, Junge H, Ludwig R, Beller M. J Am Chem Soc. 2010 Jun 15. [Epub ahead of print] PubMed PMID: 20550131.

  • Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C-H Bond Activation. Yi CS, Lee DW. Organometallics. 2010 Mar 19;29(8):1883-1885. PubMed PMID: 20567607; PubMed Central PMCID: PMC2887707.

     

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