Barium Acetylacetonate

Ba(CH3COCHCOCH3)2 • xH2O

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BA-ACAC-02 (2N) 99% Barium Acetylacetonate Request
BA-ACAC-03 (3N) 99.9% Barium Acetylacetonate Request
BA-ACAC-04 (4N) 99.99% Barium Acetylacetonate Request
BA-ACAC-05 (5N) 99.999% Barium Acetylacetonate Request

About

Acetylaceton Formula Diagram (C5H8O2)Barium Acetylacetonate is a Barium source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic Acetylacetonate Packaging, Lab Quantitycompounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures (as demonstrated by a 2013 experiment by researchers at the Leibniz Institute for Solid State and Materials Research Dresden) via the use of chemical vapor deposition (CVD) and laser evaporation techniques. Barium Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Barium 2, 4-pentanedionate, Barium bis[(2Z)-4-oxopent-2-en-2-olate], Ba(acac)2, 3-penten-2-one, 4-hydroxy-, barium salt, (3Z)- (2:1), Bis(pentane-2, 4-dionato-O, O')barium

Chemical Identifiers

Formula Ba(CH3COCHCOCH3)2 • xH2O
CAS 12084-29-6
Pubchem CID 5486157
MDL MFCD00150161
EC No. 235-151-3
IUPAC Name barium(2+); (Z)-4-oxopent-2-en-2-olate
SMILES [Ba+2].O=C(/C=C(\[O-])C)C.[O-]\C(=C/C(=O)C)C
InchI Identifier InChI=1S/2C5H8O2.Ba/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InchI Key HYRVTHFPMWHAEG-SUKNRPLKSA-L

Properties

Compound Formula C10H14BaO4
Molecular Weight 335.53
Appearance White to off-white powder
Melting Point N/A
Boiling Point N/A
Density N/A
Exact Mass 335.994456
Monoisotopic Mass 335.994456

Health & Safety Info  |  MSDS / SDS

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Statements N/A
Transport Information N/A
Globally Harmonized System of Classification and Labelling (GHS) N/A
MSDS / SDS

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

Related Products

BaSee more Barium products. Barium (atomic symbol: Ba, atomic number: 56) is a Block S, Group 2, Period 6 element with an atomic weight of 137.27. The number of electrons in each of barium's shells is [2, 8, 18, 18, 8, 2] and its electron configuration is [Xe] 6s2. Barium Bohr ModelBarium is a member of the alkaline-earth metals. The barium atom has a radius of 222 pm and a Van der Waals radius of 268 pm. Barium was discovered by Carl Wilhelm Scheele in 1772 and first isolated by Humphry Davy in 1808. Elemental BariumIn its elemental form, barium is a soft, silvery-gray metal. Industrial applications for barium include acting as a "getterer," or unwanted gas remover, for vacuum tubes, and as an additive to steel and cast iron. Barium is also alloyed with silicon and aluminum as load-bearing alloys. The main commercial source of barium is the mineral barite (BaSO4) it does not occur naturally as a free element . The name barium is derived from the Greek word "barys," meaning heavy.

Research

Recent Research & Development for Barium

  • Correlation Between Timed Barium Esophagogram and Esophageal Transit Scintigraphy Results in Achalasia. Park YM, Jeon HH, Park JJ, Kim JH, Youn YH, Park H. Dig Dis Sci. 2015 Apr 30.
  • Oxygen diffusion in single crystal barium titanate. Kessel M, De Souza RA, Martin M. Phys Chem Chem Phys. 2015 May 6
  • Size-dependent ecotoxicity of barium titanate particles: the case of Chlorella vulgaris green algae. Polonini HC, Brandão HM, Raposo NR, Brandão MA, Mouton L, Couté A, Yéprémian C, Sivry Y, Brayner R. Ecotoxicology. 2015 May
  • Unfolding grain size effects in barium titanate ferroelectric ceramics. Tan Y, Zhang J, Wu Y, Wang C, Koval V, Shi B, Ye H, McKinnon R, Viola G, Yan H. Sci Rep. 2015 May 7
  • One-dimensional carbon nanotube@barium titanate@polyaniline multiheterostructures for microwave absorbing application. Ni QQ, Zhu YF, Yu LJ, Fu YQ. Nanoscale Res Lett. 2015 Apr 11
  • Biocompatibility and osteogenesis of the castor bean polymer doped with silica (SiO2) or barium titanate (BaTiO3) nanoparticles. Nacer RS, Silva BA, Poppi RR, Silva DK, Cardoso VS, Delben JR, Delben AA. Acta Cir Bras. 2015 Apr
  • Size-dependent ecotoxicity of barium titanate particles: the case of Chlorella vulgaris green algae. Polonini HC, Brandão HM, Raposo NR, Brandão MA, Mouton L, Couté A, Yéprémian C, Sivry Y, Brayner R. Ecotoxicology. 2015 May: Ecotoxicology
  • Anteroposterior radiograph of a barium examination of the oesophagus. Zheng MH, Pan KH. BMJ. 2015 Mar 5: BMJ
  • Enhanced photoreversible color switching of redox dyes catalyzed by barium-doped TiO2 nanocrystals. Wang W, Ye Y, Feng J, Chi M, Guo J, Yin Y. Angew Chem Int Ed Engl. 2015 Jan 19: Angew Chem Int Ed Engl
  • Composite nanoplatelets combining soft-magnetic iron oxide with hard-magnetic barium hexaferrite. Primc D, Makovec D. Nanoscale. 2015 Feb 14: Nanoscale

Recent Research & Development for Acetylacetonates

  • Binary Diffusion Coefficients of Platinum(II) Acetylacetonate in Supercritical Carbon Dioxide. Kong CY, Siratori T, Wang G, Sako T, Funazukuri T. J Chem Eng Data. 2013 Nov 14
  • Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x < 5)-oleylamine and platinum(ii) acetylacetonate. Bian B, Xia W, Du J, Zhang J, Liu JP, Guo Z, Yan A. Nanoscale. 2013 Mar 21
  • Antitumor efficacy and tolerability of systemically administered gallium acetylacetonate-loaded gelucire-stabilized nanoparticles. Wehrung D, Bi L, Geldenhuys WJ, Oyewumi MO. J Biomed Nanotechnol. 2013 Jun
  • High performance polymer solar cells with as-prepared zirconium acetylacetonate film as cathode buffer layer. Tan Z, Li S, Wang F, Qian D, Lin J, Hou J, Li Y. Sci Rep. 2014 Apr 15
  • Vanadyl acetylacetonate upregulates PPARγ and adiponectin expression in differentiated rat adipocytes. Wu Y, Huang M, Zhao P, Yang X. J Biol Inorg Chem. 2013 Aug
  • Effect of magnesium acetylacetonate on the signal of organic forms of vanadium in graphite furnace atomic absorption spectrometry. Kowalewska Z, Welz B, Castilho IN, Carasek E. Talanta. 2013 Jan 15
  • [Differentiated fluorescence centers in europium acetylacetonate hydrate doped poly methyl methacrylate]. Zhang YY, Zhong H, Chen BJ, Xia Y, Lin H. Guang Pu Xue Yu Guang Pu Fen Xi. 2014 Jun
  • Photophysical properties of an unusual bichromophoric species constructed from a cyclometalated Pt(II) chromophore and a blue Bodipy-acetylacetonate species. Nastasi F, Puntoriero F, Serroni S, Campagna S, Olivier JH, Ziessel R. Dalton Trans. 2014 Dec 21
  • Binary Diffusion Coefficients of Platinum(II) Acetylacetonate in Supercritical Carbon Dioxide. Kong CY, Siratori T, Wang G, Sako T, Funazukuri T. J Chem Eng Data. 2013 Nov 14
  • Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x < 5)-oleylamine and platinum(ii) acetylacetonate. Bian B, Xia W, Du J, Zhang J, Liu JP, Guo Z, Yan A. Nanoscale. 2013 Mar 21

Free Test Sample Program

We recognize many of our customers are purchasing small quantities directly online as trial samples in anticipation of placing a larger future order or multiple orders as a raw material for production. Since our primary business is the production of industrial quantities and/or highly consistent batches which can be used for commercial production and purchased repeatedly in smaller quantity, American Elements offers trial samples at no charge on the following basis. Within 6 months of purchasing materials directly online from us, you have the option to refer back to that order and advise that it is the intention of your company, institution or lab to either purchase a larger quantity, purchase the material in regular intervals or purchase more on some other basis.

We will then evaluate your future needs and assuming the quantity or number of future purchases qualify, we will fully credit your purchase price with the next order. Because of the many variables in the quantity and number of orders you may place, it is impossible to evaluate whether your future order(s) will qualify for this program prior to your placing your next order. Please know American Elements strongly desires to make this free sample program available to you and will make every effort to do so once your next order is placed.