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Boron Oxide

B2O3

MDL Number:

MFCD00191837

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Boron Oxide
BO-OX-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Boron Oxide
BO-OX-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Boron Oxide
BO-OX-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Boron Oxide
BO-OX-05
Pricing > SDS > Data Sheet >

Boron Oxide Properties

Compound Formula

B2O3

Molecular Weight

69.62

Appearance

White Crystalline Solid

Melting Point

510 °C (950 °F)

Boiling Point

1860 °C (3380 °F)

Density

2.46 g/cm3

Exact Mass

N/A

Monoisotopic Mass

70.003356 Da

Boron Oxide Health & Safety Information

Signal Word Danger
Hazard Statements N/A
Hazard Codes H360FD
Precautionary Statements P201-P202-P280-P308+P313-P405
Risk Codes 36/37/38
Safety Statements 26-36
RTECS Number NONH
Transport Information NONH
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 08/19/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Boron Oxide

Product Number: All applicable American Elements product codes, e.g. BO-OX-02 , BO-OX-03 , BO-OX-04 , BO-OX-05

CAS #: 1303-86-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS06 Skull and crossbones
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
Carc. 1B H350 May cause cancer.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms

Skull and Crossbones - GHS06 Health Hazard - GHS08

GHS06 GHS08
Signal word: Danger
Hazard statements
H330 Fatal if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P284 Wear respiratory protection.
P281 Use personal protective equipment as required.
P320 Specific treatment is urgent (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D1A - Very toxic material causing immediate and serious toxic effects
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
3

1
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
1306-19-0 Cadmium oxide
Identification number(s):
EC number: 215-146-2
Index number: 048-002-00-0


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
Remove breathing apparatus only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Cadmium oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from magnesium/magnesium alloys
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
1306-19-0 Cadmium oxide (100.0%)
PEL (USA) Long-term value: 0.005 mg/m³ as Cd; see 29 CFR 1910.1027
REL (USA) See Pocket Guide App. A
TLV (USA) Long-term value: 0.01 0.002* mg/m³ as Cd; *respirable fraction; BEI
EL (Canada) Long-term value: 0.01 mg/m³ as Cd; ACIGH A1, IARC 1
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use self-contained respiratory protective device in emergency situations.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands: Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes): Not determined
Eye protection: Safety glasses
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder or solid in various forms
Color: Red-brown
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 1430 °C (2606 °F)
Boiling point/Boiling range: Not determined
Sublimation temperature / start: 1559 °C (2838 °F)
Flammability (solid, gaseous): Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): 8.15 g/cm³ (68.012 lbs/gal)
Relative density: Not determined.
Vapor density: Not applicable.
Evaporation rate: Not applicable.
Solubility in / Miscibility with Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No further relevant information available.
Incompatible materials:
Magnesium/magnesium alloys
Hazardous decomposition products:
Cadmium oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: Fatal if inhaled.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification:
Oral LD50 72 mg/kg (rat)
Inhalative LC50/1H 45 mg/m3/1H (rat)
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: Suspected of causing genetic defects.
Carcinogenicity: May cause cancer.
IARC-1: Carcinogenic to humans: sufficient evidence of carcinogenicity.
EPA-B1: Probable human carcinogen, limited evidence of carcinogenicity from epidemiologic studies.
Carcinogen as defined by OSHA.
ACGIH A2: Suspected human carcinogen: Agent is carcinogenic in experimental animals at dose levels, by route(s) of administration, at site(s), of histologic type(s), or by mechanism(s) considered relevant to worker exposure. Available epidemiologic studies are conflicting or insufficient to confirm an increased risk of cancer in exposed humans.
NTP-K: Known to be carcinogenic: sufficient evidence from human studies.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or carcinogenic and/or neoplastic data for this substance.
Reproductive toxicity:
Suspected of damaging fertility or the unborn child.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure:
Causes damage to organs through prolonged or repeated exposure.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
Carcinogenic categories
OSHA-Ca (Occupational Safety & Health Administration)
Substance is listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Ecotoxical effects:
Remark:
Very toxic for aquatic organisms
Additional ecological information:
General notes:
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Very toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number: 2570
Class: 6.1
Packing group: I
Proper shipping name: Cadmium compounds (Cadmium oxide non-pyrophoric)
Reportable Quantity (RQ):
Poison Inhalation Hazard: No
IMDG
UN number: 2570
Class: 6.1
Packing group: I
EMS-No: F-A, S-A
Proper shipping name: CADMIUM COMPOUND (Cadmium oxide non-pyrophoric)
IATA
UN number: 2570
Class: 6.1
Packing group: I
Proper shipping name: Cadmium compound (Cadmium oxide non-pyrophoric)


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
1306-19-0 Cadmium oxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer
1306-19-0 Cadmium oxide
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in certain cases.
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
This substance is included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH).
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Boron Oxide

Oxide IonBoron Oxide is a highly insoluble thermally stable Boron source suitable for glass, optic and ceramic applications. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. They are compounds containing at least one oxygen anion and one metallic cation. They are typically insoluble in aqueous solutions (water) and extremely stable making them useful in ceramic structures as simple as producing clay bowls to advancHigh Purity (99.999%) Boron Oxide (B2O3) Powdered electronics and in light weight structural components in aerospace and electrochemical applications such as fuel cells in which they exhibit ionic conductivity. Metal oxide compounds are basic anhydrides and can therefore react with acids and with strong reducing agents in redox reactions. Boron Oxide is also available in pellets, pieces, powder, sputtering targets, tablets, and nanopowder (from American Elements' nanoscale production facilities). Boron Oxide is generally immediately available in most volumes. Ultra high purity, high purity, submicron and nanopowder forms may be considered. Additional technical, research and safety (MSDS) information is available.

Boron Oxide Synonyms

Boric anhydride, Boric oxide, Keto-ketaboranyloxy-borane, Diboron trioxide, Boron trioxide, Dioxodiboroxane, Boron anhydride, borane, 1, 1'-oxybis[1-oxo, Oxo-oxoboranyloxy-borane

Boron Oxide Chemical Identifiers

Linear Formula

B2O3

Pubchem CID

16212772

MDL Number

MFCD00191837

EC No.

N/A

Beilstein Registry No.

N/A

IUPAC Name

oxo(oxoboranyloxy) borane

SMILES

O=BOB=O

InchI Identifier

InChI=1S/B2O3/c3-1-5-2-4

InchI Key

JKWMSGQKBLHBQQ-BHBJOZJASA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Boron products. Boron Bohr ModelBoron (atomic symbol: B, atomic number: 5) is a Block P, Group 13, Period 2 element with an atomic weight of 10.81. The number of electrons in each of boron's shells is 2, 3 and its electron configuration is [He] 2s2 2p1. The boron atom has a radius of 90 pm and a Van der Waals radius of 192 pm. Boron was discovered by Joseph Louis Gay-Lussac and Louis Jacques Thénard in 1808. It was first isolated by Humphry Davy, also in 1808. Boron is classified as a metalloid is not found naturally on earth. Elemental BoronAlong with carbon and nitrogen, boron is one of the few elements in the periodic table known to form stable compounds featuring triple bonds. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. Boron is found in borates, borax, boric acid, colemanite, kernite, and ulexite.The name Boron originates from a combination of carbon and the Arabic word buraqu meaning borax.

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August 19, 2017
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