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Potassium Hexafluorotitanate(IV)

CAS #:

Linear Formula:

K2(TiF6)

MDL Number:

MFCD00011380

EC No.:

240-969-9

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Potassium Hexafluorotitanate(IV)
K-F6TAT-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Potassium Hexafluorotitanate(IV)
K-F6TAT-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Potassium Hexafluorotitanate(IV)
K-F6TAT-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Potassium Hexafluorotitanate(IV)
K-F6TAT-05
Pricing > SDS > Data Sheet >

Potassium Hexafluorotitanate(IV) Properties

Compound Formula

F6K2Ti

Molecular Weight

240.05

Appearance

White Powder

Melting Point

780 °C

Boiling Point

N/A

Density

N/A

Exact Mass

239.865779

Monoisotopic Mass

239.865779

Potassium Hexafluorotitanate(IV) Health & Safety Information

Signal Word Danger
Hazard Statements H302-H317-H318
Hazard Codes Xn
Risk Codes 22-41-43
Safety Statements 26-36/37/39
RTECS Number TT1575000
Transport Information N/A
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 09/26/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Potassium Hexafluorotitanate(IV)

Product Number: All applicable American Elements product codes, e.g. K-F6TAT-02 , K-F6TAT-03 , K-F6TAT-04 , K-F6TAT-05

CAS #: 16919-27-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Hazards not otherwise classified
No information known.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms

Corrosion - GHS05 Exclamation Mark - GHS07

GHS05 GHS07
Signal word: Danger
Hazard statements
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D1B - Toxic material causing immediate and serious toxic effects
D2B - Toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
2

1
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
16919-27-0 Potassium hexafluorotitanate
Identification number(s):
EC number: 240-969-9


SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Hydrogen fluoride (HF)
Metal oxide fume
Potassium oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes): Not determined
Eye protection: Tightly sealed goggles
Body protection: Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Crystalline powder or solid
Color: White
Odor: Not determined
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 235-237 °C (455-459 °F)
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous): Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density: Not determined
Relative density: Not determined.
Vapor density: Not applicable.
Evaporation rate: Not applicable.
Solubility in / Miscibility with Water: Not determined
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No further relevant information available.
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Hydrogen fluoride
Metal oxide fume
Potassium oxide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Harmful if swallowed.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: Causes skin irritation.
Eye irritation or corrosion: Causes serious eye damage.
Sensitization: May cause an allergic skin reaction.
Germ cell mutagenicity: No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: May cause respiratory irritation.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
Carcinogenic categories
OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA
UN3288
UN proper shipping name
DOT
Toxic solid, inorganic, n.o.s. (Potassium hexafluorotitanate)
IMDG, IATA
TOXIC SOLID, INORGANIC, N.O.S. (Potassium hexafluorotitanate)
Transport hazard class(es)
DOT
Class
6.1 Toxic substances.
Label
6.1
Class
6.1 (T5) Toxic substances
Label
6.1
IMDG, IATA
Class
6.1 Toxic substances.
Label
6.1
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
Not applicable.
Special precautions for user
Warning: Toxic substances
EMS Number:
F-A,S-A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3288, Toxic solid, inorganic, n.o.s. (Potassium hexafluorotitanate), 6.1, III


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Potassium Hexafluorotitanate(IV)

Fluoride IonTitanate IonPotassium Hexafluorotitanate(IV) is a water insoluble Titanium source for use in oxygen-sensitive applications, such as metal production. In extremely low concentrations (ppm), fluoride compounds are used in health applications. Fluoride compounds also have significant uses in synthetic organic chemistry. They are commonly also used to alloy metal and for optical deposition. Certain fluoride compounds can be produced at nanoscale and in ultra high purity forms. Potassium Fluotitanate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. Potassium Hexafluorotitanate(IV) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.

Potassium Hexafluorotitanate(IV) Synonyms

Dipotassium monotitanium hexafluoride; Dipotassiumtitanium hexafluoride; NSC 187663; NSC 43605; Potassium hexafluorotitanate (K2TiF6); Titanate(2-), hexafluoro-, dipotassium, (OC-6-11)- (9CI); Potassium Fluorotitanate; dipotassium titanium(4+) hexafluoride; Titanium potassium fluoride; Titanium potassium hexafluoride

Potassium Hexafluorotitanate(IV) Chemical Identifiers

Linear Formula

K2(TiF6)

Pubchem CID

159800

MDL Number

MFCD00011380

EC No.

240-969-9

Beilstein Registry No.

N/A

IUPAC Name

dipotassium; titanium(4+); hexafluoride

SMILES

[K+].[K+].F[Ti- 2](F)(F)(F)(F)F

InchI Identifier

InChI=1S/6 FH.2K.Ti/h6 *1H;;;/q;;;;;; 2*+1;+4/p-6

InchI Key

RXCBCUJUGULOGC-UHFFFAOYSA-H

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Titanium products. Titanium (atomic symbol: Ti, atomic number: 22) is a Block D, Group 4, Period 4 element with an atomic weight of 47.867. The number of electrons in each of Titanium's shells is [2, 8, 10, 2] and its electron configuration is [Ar] 3d2 4s2. Titanium Bohr ModelThe titanium atom has a radius of 147 pm and a Van der Waals radius of 187 pm. Titanium was discovered by William Gregor in 1791 and first isolated by Jöns Jakob Berzelius in 1825. In its elemental form, titanium has a silvery grey-white metallic appearance. Titanium's properties are chemically and physically similar to zirconium, both of which have the same number of valence electrons and are in the same group in the periodic table. Elemental TitaniumTitanium has five naturally occurring isotopes: 46Ti through 50Ti, with 48Ti being the most abundant (73.8%). Titanium is found in igneous rocks and the sediments derived from them. It is named after the word Titanos, which is Greek for Titans.

Elemental PotassiumSee more Potassium products. Potassium (atomic symbol: K, atomic number: 19) is a Block S, Group 1, Period 4 element with an atomic weight of 39.0983. The number of electrons in each of Potassium's shells is [2, 8, 8, 1] and its electron configuration is [Ar] 4s1. The potassium atom has a radius of 227.2 pm and a Van der Waals radius of 275 pm. Potassium was discovered and first isolated by Sir Humphrey Davy in 1807. Potassium is the seventh most abundant element on earth. It is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other alkali metals, potassium decomposes in water with the evolution of hydrogen because of its reacts violently with water, it only occurs in nature in ionic salts.Potassium Bohr Model In its elemental form, potassium has a silvery gray metallic appearance, but its compounds (such as potassium hydroxide) are more frequently used in industrial and chemical applications. The origin of the element's name comes from the English word 'potash,' meaning pot ashes, and the Arabic word qali, which means alkali. The symbol K originates from the Latin word kalium.

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