CAS #:

Linear Formula:

HfI4

MDL Number:

MFCD00016128

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Ultra Dry Hafnium(IV) Iodide
HF4-I-02-P.UD
Pricing > SDS > Data Sheet >
(3N) 99.9% Ultra Dry Hafnium(IV) Iodide
HF4-I-03-P.UD
Pricing > SDS > Data Sheet >
(4N) 99.99% Ultra Dry Hafnium(IV) Iodide
HF4-I-04-P.UD
Pricing > SDS > Data Sheet >
(5N) 99.999% Ultra Dry Hafnium(IV) Iodide
HF4-I-05-P.UD
Pricing > SDS > Data Sheet >

Ultra Dry Hafnium(IV) Iodide Properties (Theoretical)

Compound Formula I4Hf
Molecular Weight 686.11
Appearance powder
Melting Point N/A
Boiling Point N/A
Density 5.6 g/cm3
Solubility in H2O N/A
Exact Mass 687.564421
Monoisotopic Mass 687.564331 Da

Ultra Dry Hafnium(IV) Iodide Health & Safety Information

Signal Word Danger
Hazard Statements H314-H335
Hazard Codes C, Xi
Precautionary Statements P260-P264-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501
Risk Codes N/A
Safety Statements N/A
Harmonized Tariff Code 2827.60
Transport Information UN 3260 8/PG II
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 09/27/2021
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Ultra Dry Hafnium(IV) Iodide

Product Number: All applicable American Elements product codes, e.g. HF4-I-02-P.UD , HF4-I-03-P.UD , HF4-I-04-P.UD , HF4-I-05-P.UD

CAS #: 13777-23-6

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements
Signal Word
Danger
Hazard Statements
Causes severe skin burns and eye damage
May cause respiratory irritation

Corrosion - GHS05 Exclamation Mark - GHS07

Precautionary Statements
Prevention
Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Response
Immediately call a POISON CENTER or doctor/physician
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Ingestion
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component - Hafnium iodide (HfI4)
CAS-No - 13777-23-6
Weight % - <=100


SECTION 4. FIRST AID MEASURES

General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required. Keep eye wide open while rinsing.
Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Call a physician immediately.
Inhalation Remove to fresh air. If not breathing, give artificial respiration. Call a physician or poison
control center immediately. Do not use mouth-to-mouth method if victim ingested or inhaled
the substance; give artificial respiration with the aid of a pocket mask equipped with a
one-way valve or other proper respiratory medical device.
Ingestion Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water.
Never give anything by mouth to an unconscious person.
Most important symptoms and
effects
Causes burns by all exposure routes. Product is a corrosive material. Use of gastric
lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should
be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue
and danger of perforation
Notes to Physician Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam.
Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature No information available
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
The product causes burns of eyes, skin and mucous membranes.
Hazardous Combustion Products
None known.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
NFPA
Health - 3
Flammability - 0
Instability - 0
Physical hazrds -


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment as required. Evacuate personnel to safe areas. Avoid
contact with skin, eyes or clothing.
Environmental Precautions Should not be released into the environment. Do not allow material to contaminate ground
water system. See Section 12 for additional Ecological Information.
Methods for Containment and Clean
Up
Sweep up and shovel into suitable containers for disposal. Avoid dust formation.


SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on
clothing. Use only under a chemical fume hood. Do not breathe dust. Do not ingest. If
swallowed then seek immediate medical assistance.
Storage Corrosives area. Keep containers tightly closed in a dry, cool and well-ventilated place.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Solid
Appearance Yellow
Odor No information available
Odor Threshold No information available
pH No information available
Melting Point/Range 400 °C / 752 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity Not applicable


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard None known, based on information available
Stability Stable under normal conditions.
Conditions to Avoid Incompatible products.
Incompatible Materials Strong oxidizing agents
Hazardous Decomposition ProductsNone under normal use conditions
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and
delayed
Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
Possible perforation of stomach or esophagus should be investigated: Ingestion causes
severe swelling, severe damage to the delicate tissue and danger of perforation
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Do not empty into drains.
Persistence and Degradability No information available
Bioaccumulation/ Accumulation No information available.
Mobility No information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT
UN-No UN3260Proper Shipping Name Corrosive solid, acidic, inorganic, n.o.s.
Technical Name (Hafnium iodide)
Hazard Class 8
Packing Group II
TDG
UN-No UN3260
Proper Shipping Name Corrosive solid, acidic, inorganic, n.o.s.
Hazard Class 8
Packing Group II
IATA
UN-No UN3260
Proper Shipping Name Corrosive solid, acidic, inorganic, n.o.s.
Hazard Class 8
Packing Group II
IMDG/IMO
UN-No UN3260
Proper Shipping Name Corrosive solid, acidic, inorganic, n.o.s.
Hazard Class 8
Packing Group II


SECTION 15. REGULATORY INFORMATION

TSCA 12(b) - Notices of Export Not applicable
U.S. Federal Regulations
SARA 313 Not applicable
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA - Occupational Safety and
Health Administration
Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know
Regulations
Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland
Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2021 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Ultra Dry Hafnium(IV) Iodide

Iodide IonAmerican Elements specializes in producing Hafnium Iodide in an ultra dry form for use as a compound in semiconductors and other high purity applications. Ultra Dry Hafnium Iodide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Ultra Dry Hafnium(IV) Iodide Synonyms

Hafnium tetraiodide, hafnium iodide anhydrous red powder, Hafnium iodide

Chemical Identifiers

Linear Formula HfI4
MDL Number MFCD00016128
EC No. N/A
Beilstein/Reaxys No. N/A
Pubchem CID 83726
IUPAC Name tetraiodohafnium
SMILES I[Hf](I)(I)I
InchI Identifier InChI=1S/Hf.4HI/h;4*1H/q+4;;;;/p-4
InchI Key YCJQNNVSZNFWAH-UHFFFAOYSA-J

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Hafnium

See more Hafnium products. Hafnium (atomic symbol: Hf, atomic number: 72) is a Block D, Group 4, Period 6 element with an atomic weight of 178.49. Hafnium Bohr ModelThe number of electrons in each of Hafnium's shells is 2, 8, 18, 32, 10, 2 and its electron configuration is [Xe] 4f14 5d2 6s2. The hafnium atom has a radius of 159 pm and a Van der Waals radius of 212 pm. Hafnium was predicted by Dmitri Mendeleev in 1869 but it was not until 1922 that it was first isolated Dirk Coster and George de Hevesy. In its elemental form, hafnium has a lustrous silvery-gray appearance. Elemental HafniumHafnium does not exist as a free element in nature. It is found in zirconium compounds such as zircon. Hafnium is often a component of superalloys and circuits used in semiconductor device fabrication. Its name is derived from the Latin word Hafnia, meaning Copenhagen, where it was discovered.

Iodine

See more Iodine products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electron configuration is [Kr] 4d10 5s2 5p5. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. In its elemental form, iodine has a lustrous metallic gray appearance as a solid and a violet appearance as a gas or liquid solution. Elemental IodineIodine forms compounds with many elements, but is less active than the other halogens. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Iodine compounds are important in organic chemistry and very useful in the field of medicine. Iodine was discovered and first isolated by Bernard Courtois in 1811. The name Iodine is derived from the Greek word "iodes" meaning violet.

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