Vanadium(V) Oxide

SECTION 1. IDENTIFICATION

Product Name: Vanadium(V) Oxide

Product Number: All applicable American Elements product codes, e.g. V5-OX-02 , V5-OX-03 , V5-OX-04 , V5-OX-05

CAS #: 1314-62-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 1 H372 Causes damage to the lung, the liver, the heart, the blood, the brain and the endocrine system through prolonged or repeated exposure. Route
of exposure: Inhalative.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
STOT SE 3 H335 May cause respiratory irritation.
Hazards not otherwise classified No data available
GHS label elements, including precautionary statements
Hazard pictograms

GHS07 GHS08
Signal word Danger
Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
H341 Suspected of causing genetic defects.
H361 Suspected of damaging fertility or the unborn child.
H335 May cause respiratory irritation.
H372 Causes damage to the lung, the liver, the heart, the blood, the brain and the endocrine system through prolonged or repeated exposure. Route of
exposure: Inhalative.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P281 Use personal protective equipment as required.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D1B - Toxic material causing immediate and serious toxic effects
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
2
0 
1
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
CAS No. / Substance Name:
1314-62-1 Vanadium(V) oxide
Identification number(s):
EC number: 215-239-8
Index number: 023-001-00-8

SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed:
No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released:
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without official permits.
Methods and materials for containment and cleanup:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s) No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
1314-62-1 Vanadium(V) oxide (100.0%)
PEL (USA) Ceiling limit value: 0.5* C 0.1** mg/m³
as V2O5,*respirable dust **fume
REL (USA) Ceiling limit value: 0.05* mg/m³
*15-min, except V metal and carbide
TLV (USA) Long-term value: 0.05* mg/m³
*as inhalable fraction
EL (Canada) Short-term value: C 0.05** mg/m³
Long-term value: 0.2* mg/m³
IARC 2B;*total dust;**respirable dust & fume
EV (Canada) Long-term value: 0.05 mg/m³
respirable dust and fume
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if airpurifying
respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Material of gloves Nitrile rubber, NBR
Penetration time of glove material (in minutes) 480
Glove thickness 0.11 mm
Eye protection: Safety glasses
Body protection: Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

General Information
Appearance:
Form: Powder or solid
Color: Various colors
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: 690 °C (1274 °F)
Boiling point/Boiling range: 1750 °C (3182 °F) (dec)
Sublimation temperature / start: No data available
Flammability (solid, gas) No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density at 20 °C (68 °F): 3.357 g/cm³ (28.014 lbs/gal)
Relative density No data available.
Vapor density N/A
Evaporation rate N/A
Solubility in / Miscibility with
Water at 20 °C (68 °F): 8 g/l
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity No data available
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions Reacts with strong oxidizing agents
Conditions to avoid No data available
Incompatible materials: Oxidizing agents

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Harmful if inhaled.
Harmful if swallowed.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: Suspected of causing genetic defects.
Carcinogenicity:
IARC-2B: Possibly carcinogenic to humans: limited evidence in humans in the absence of sufficient evidence in experimental animals.
ACGIH A3: Animal carcinogen: Agent is carcinogenic in experimental animals at a relatively high dose, by route(s) of administration, at site(s), of histologic type(s),
or by mechanism(s) not considered relevant to worker exposure. Available epidemologic studies do not confirm an increased risk of cancer in exposed humans.
Available evidence suggests that the agent is not likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or carcinogenic and/or neoplastic data for this substance.
Reproductive toxicity: Suspected of damaging fertility or the unborn child.
Specific target organ system toxicity - repeated exposure:
Causes damage to the lung, the liver, the heart, the blood, the brain and the endocrine system through prolonged or repeated exposure. Route of exposure:
Inhalative.
Specific target organ system toxicity - single exposure: May cause respiratory irritation.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
Carcinogenic categories
OSHA-Ca (Occupational Safety & Health Administration) Substance is not listed.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information:
Do not allow material to be released to the environment without official permits.
Do not allow product to reach groundwater, water courses, or sewage systems, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic to aquatic life.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

DOT, IMDG, IATA UN2862
UN proper shipping name
DOT Vanadium pentoxide
IMDG, IATA VANADIUM PENTOXIDE
Transport hazard class(es)
DOT
Class 6.1 Toxic substances.
Label 6.1
Class 6.1 (T5) Toxic substances
Label 6.1
IMDG, IATA
Class 6.1 Toxic substances.
Label 6.1
Packing group
DOT, IMDG, IATA III
Environmental hazards: Environmentally hazardous substance, solid
Special precautions for user Warning: Toxic substances
EMS Number: F-A,S-A
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN2862, Vanadium pentoxide, 6.1, III

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements, including precautionary statements
Hazard pictograms
GHS07 GHS08
Signal word Danger
Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
H341 Suspected of causing genetic defects.
H361 Suspected of damaging fertility or the unborn child.
H335 May cause respiratory irritation.
H372 Causes damage to the lung, the liver, the heart, the blood, the brain and the endocrine system through prolonged or repeated exposure. Route of
exposure: Inhalative.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P281 Use personal protective equipment as required.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
1314-62-1 Vanadium(V) oxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer
1314-62-1 Vanadium(V) oxide
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.