A Reaction Cycle for Octahedral Tungsten Iodide Clusters.

Title A Reaction Cycle for Octahedral Tungsten Iodide Clusters.
Authors M. Ströbele; H.J. Meyer
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.7b00537
Abstract

A reaction cycle is shown for octahedral tungsten iodide compounds. The thermal transformation of W6I16 (W6I12·2I2) via release of iodine proceeds via the new W6I13 (W6I12·xI2 with 0 < x ? 1/2) to yield a new modification of W6I12, denoted as ?-W6I12. When heated, ?-W6I12 is converted into the known (?-)W6I12. The reaction of (?-)W6I12 with I2 leads to the formation of the starting compound W6I16. The new compounds W6I13 (W6I12·xI2 with 0 < x ? 1/2) and ?-W6I12 are structurally characterized by powder and single-crystal X-ray diffraction techniques. The thermal decomposition of W6I16 and the monotropic phase transition of ?-W6I12 into ?-W6I12 are examined by differential scanning calorimetry measurements.

Citation M. Ströbele; H.J. Meyer.A Reaction Cycle for Octahedral Tungsten Iodide Clusters.. Inorg Chem. 2017;56(10):58805884. doi:10.1021/acs.inorgchem.7b00537

Related Elements

Tungsten

See more Tungsten products. Tungsten (atomic symbol: W, atomic number: 74) is a Block D, Group 6, Period 6 element with an atomic weight of 183.84. The number of electrons in each of tungsten's shells is [2, 8, 18, 32, 12, 2] and its electron configuration is [Xe] 4f14 5d4 6s2. Tungsten Bohr ModelThe tungsten atom has a radius of 139 pm and a Van der Waals radius of 210 pm. Tungsten was discovered by Torbern Bergman in 1781 and first isolated by Juan José Elhuyar and Fausto Elhuyar in 1783. In its elemental form, tungsten has a grayish white, lustrous appearance. Elemental TungstenTungsten has the highest melting point of all the metallic elements and a density comparable to that or uranium or gold and about 1.7 times that of lead. Tungsten alloys are often used to make filaments and targets of x-ray tubes. It is found in the minerals scheelite (CaWO4) and wolframite [(Fe,Mn)WO4]. In reference to its density, Tungsten gets its name from the Swedish words tung and sten, meaning heavy stone.

Iodine

See more Iodine products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electron configuration is [Kr] 4d10 5s2 5p5. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. In its elemental form, iodine has a lustrous metallic gray appearance as a solid and a violet appearance as a gas or liquid solution. Elemental IodineIodine forms compounds with many elements, but is less active than the other halogens. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Iodine compounds are important in organic chemistry and very useful in the field of medicine. Iodine was discovered and first isolated by Bernard Courtois in 1811. The name Iodine is derived from the Greek word "iodes" meaning violet.

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