An automated continuous homogeneous microextraction for the determination of selenium and arsenic by hydride generation atomic fluorescence spectrometry.

Title An automated continuous homogeneous microextraction for the determination of selenium and arsenic by hydride generation atomic fluorescence spectrometry.
Authors A. Shishov; M. Wieczorek; P. Ko?cielniak; D. Dudek-Adamska; A. Telk; L. Moskvin; A. Bulatov
Journal Talanta
DOI 10.1016/j.talanta.2018.01.033
Abstract

An automated continuous homogeneous microextraction approach based on a flow system has been developed and coupled with a hydride generation atomic fluorescence spectrometry system (HG-AFS). The developed approach was applied for the determination of trace arsenic and selenium in environmental water and liver samples. The nonanoic acid was investigated as a switchable hydrophilicity solvent (SHS) for homogeneous microextraction of As(III) and Se(IV) complexes with pyrrolidinedithiocarbamate (PDC). The procedure involved on-line mixing ammonium PDC (aqueous phase), sodium nonanoate (aqueous phase) and acid sample solution resulting in the formation of SHS (nonanoic acid) dispersed into the acid aqueous phase. By this continuous process, analytes complexes with PDC were formed and extracted into the fine SHS droplets followed by retention into a monolithic column packed with block of porous PTFE. Finally, the retained complexes were eluted with NaOH solution and delivered to the HG-AFS system. The limits of detection, calculated from a blank test based on 3?, were 0.01?gL-1 for both analytes.

Citation A. Shishov; M. Wieczorek; P. Ko?cielniak; D. Dudek-Adamska; A. Telk; L. Moskvin; A. Bulatov.An automated continuous homogeneous microextraction for the determination of selenium and arsenic by hydride generation atomic fluorescence spectrometry.. Talanta. 2018;181:359365. doi:10.1016/j.talanta.2018.01.033

Related Elements

Arsenic

See more Arsenic products. Arsenic (atomic symbol: As, atomic number: 33) is a Block P, Group 15, Period 4 element with an atomic radius of 74.92160. Arsenic Bohr ModelThe number of electrons in each of arsenic's shells is 2, 8, 18, 5 and its electron configuration is [Ar] 3d10 4s2 4p3. The arsenic atom has a radius of 119 pm and a Van der Waals radius of 185 pm. Arsenic was discovered in the early Bronze Age, circa 2500 BC. It was first isolated by Albertus Magnus in 1250 AD. In its elemental form, arsenic is a metallic grey, brittle, crystalline, semimetallic solid. Elemental ArsenicArsenic is found in numerous minerals including arsenolite (As2O3), arsenopyrite (FeAsS), loellingite (FeAs2), orpiment (As2S3), and realgar (As4S4). Arsenic has numerous applications as a semiconductor and other electronic applications as indium arsenide, silicon arsenide and tin arsenide. Arsenic is finding increasing uses as a doping agent in solid-state devices such as transistors.

Selenium

Selenium Bohr ModelSee more Selenium products. Selenium (atomic symbol: Se, atomic number: 34) is a Block P, Group 16, Period 4 element with an atomic radius of 78.96. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electron configuration is [Ar] 3d10 4s2 4p4. The selenium atom has a radius of 120 pm and a Van der Waals radius of 190 pm. Selenium is a non-metal with several allotropes: a black, vitreous form with an irregular crystal structure three red-colored forms with monoclinic crystal structures and a gray form with a hexagonal crystal structure, the most stable and dense form of the element. Elemental SeleniumOne of the most common uses for selenium is in glass production the red tint that it lends to glass neutralizes green or yellow tints from impurities in the glass materials. Selenium was discovered and first isolated by Jöns Jakob Berzelius and Johann Gottlieb Gahn in 1817. The origin of the name Selenium comes from the Greek word "Selênê," meaning moon.

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