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About Gold

Gold Bohr

The notable properties of gold in its pure, metallic form are as follows: it is the most malleable and ductile of metals and an unusual color for compounds of that class, is mostly non-reactive, conducts electricity well, and is extremely dense. The density of gold helped to drive its relative rarity, as gold present when the earth was formed would have largely sunk to the core of the planet. It is therefore believed that virtually all gold discovered by humans was deposited considerably later by meteorites containing the element. The low reactivity of gold explains why the metal was known to ancient societies despite its rarity: unlike most metals, it occurs mostly in its elemental form.

The rarity of gold, in combination with the ease with which it can be worked, its visual distinctiveness, and its resistance to chemical corrosion, made it an extremely unusual material and the object of much fascination. It was an obvious choice, then, for use as an ornamental status symbol and as a unit of monetary exchange. The oldest gold artifacts known have been dated to the 4th millenium BC, and the first gold coins (actually made of electrum, a natural alloy of gold and silver) were minted around 600 BC in present-day Turkey. Gold remained a major component of monetary systems for much of the world into the twentieth century, as even when gold coinage became less common, most industrial economies used a gold standard to back their currencies. Gold standards started to be abandoned during World War I, and over time all modern industrialized nations switched to fiat currency systems.

Despite the fall of gold from an official monetary function, it is still widely viewed as valuable and used as a form of investment or storage of wealth, with many hoarding it as a hedge against inflation, and gold also remains a common metal used in fine jewelry. These functions still consume the majority of gold produced, despite a large number of other applications for the metal. Amalgams of gold and mercury have long been used in restorative dentistry for fillings and crowns, though concerns of mercury toxicity and the increasing availability of suitable composite materials as replacements have led to a decline in demand. Gold also finds many applications in electronics, where its high conductivity makes it attractive for wiring or as a coating for more easily corroded metals. Printed circuit boards often feature such thin protective gold layers. Thin films of gold are also useful for a variety of other functions. Gold can be manufactured to be thin enough to appear transparent, and thus be used in windows--in settings such as aircraft windshields--that can then be de-iced by passing electricity through the conductive film. Gold films are also excellent reflectors of electromagnetic radiation, including infrared light and radio waves, and are therefore used in infrared mirrors, heat shielding, and protective coatings on satellites and other equipment.

Despite being known for its low reactivity, it has long been known that gold can be dissolved in nitro-hydrochloric acid, or aqua regia, and will form some compounds, including chlorides, oxides, and thiosulfates, and many applications of gold involve these less-familiar forms. Gold chloride solutions prepared by dissolving gold in aqua regia have been used to produce cranberry glass, the brilliant red color of which is now known to come from nanoscale particles of gold dispersed within the glass.

Suspensions of such gold particles in liquid, also known as colloidal gold, are now of great interest due to their unique optical and electrical properties, in addition to their potential for useful interactions with biological systems. The electromagnetic absorption of collodial gold solutions is tunable based on the size of the particles, a useful property with a side-effect of producing solutions that range in color from red to blue. Such solutions can be used in printable conductive inks for electronics, the production of sensors and photovoltaics, and the preparation of microscopy samples.

There is a significant history in modern biology of attaching tiny gold particles to a variety of biological probes, usually for use in electron microscopy, where the high electron-density of the gold particles makes them easy to visualize.Today, the ability to specifically target gold nanoparticles this way is being used in medicine, which prizes the ability to target specific tissues or cell types, including cancer cells. This allows them to be used in the detection of cancer cell locations and in the site-specific delivery of drugs and other therapeutic agents (including small RNA molecules under investigation for use as gene therapy). Additionally, gold nanorod structures absorb light in the near-infrared range, which easily passes through many human tissues. This fact has been exploited in cancer treatment: the heat generated when near-infrared light is absorbed by the rods kills the cells containing them, leaving surrounding cells largely unscathed.

Gold occurs most often as a native metal on its own or as natural gold-silver alloy. Most gold is mined in this form from either lode or placer deposits, and a small amount is produced as a byproduct of the processing of base metals. Additionally, gold is also frequently recycled from scrap, and many financial institutions still hold significant gold stockpiles.

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Summary. Gold is used in coinage and is a standard for most modern monetary systems. It is also used extensively for jewelry, dental work, and plating. It is used for coating certain space satellites, as it is a good infrared reflector and it's inert. The use of gold in electronics has seen significant growth, particularly within telecommunications, information technology and safety critical applications. Similarly, within computers there are usually gold-plated edge connectors. Gold bonding wires are used extensively within semiconductor packages and gold thick film inks are applied in the fabrication of hybrid circuits. High Purity (99.999%) Gold Oxide (Au2O3) Powder Gold's excellent solder wetting properties are used to form a very thin protective layer on copper laminate printed circuit boards. Gold is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity). High Purity (99.999%) Gold (Au) Sputtering TargetElemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Gold nanoparticles and nanopowders are also available. Oxides are available in powder and dense pellet form for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Gold is also available in soluble forms including chlorides, nitrates and acetates. These compounds can be manufactured as solutions at specified stoichiometries.

Gold Properties

Gold(Au) atomic and molecular weight, atomic number and elemental symbol Gold is a Block D, Group 11, Period 6 element. The number of electrons in each of Gold's shells is 2, 8, 18, 32, 18, 1 and its electronic configuration is [Xe] 4f142 5d10 6s1. The gold atom has a radius of 144.2.pm and its Van der Waals radius is 217.pm. Gold Bohr ModelIn its elemental form, CAS 7440-57-5, gold has a metallic yellow appearance. Gold is a soft metal and is usually alloyed to give it more strength.Elemental Gold It is a good conductor of heat and electricity, and is unaffected by air and most reagents. It is one of the least reactive chemical elements. Gold is often found as a free element and with silver as a gold silver alloy. Less commonly, it is found in minerals as gold compounds, usually with tellurium. Gold was first discovered by Early Man c.a. 6000.

Symbol: Au
Atomic Number: 79
Atomic Weight: 196.9666
Element Category: transition metal
Group, Period, Block: 11, 6, d
Color: golden yellow
Other Names: Or, Oro, Ouro, Guld
Melting Point: 1064.18 °C,1947.52 °F, 1337.33 K
Boiling Point: 2856 °C,5173 °F, 3129 K
Density: 19.30 g/cm3
Liquid Density @ Melting Point: 17.31 g/cm3
Density @ 20°C: 19.32 g/cm3
Density of Solid: 19300 kg·m3
Specific Heat: 0.13 (kJ/kg K)
Superconductivity Temperature: N/A
Triple Point: N/A
Critical Point: 7250 K,  510.0 Mpa
Heat of Fusion (kJ·mol-1): 12.7
Heat of Vaporization (kJ·mol-1): 343.1
Heat of Atomization (kJ·mol-1): 365.93
Thermal Conductivity: 318 W·m-1·K-1
Thermal Expansion: (25 °C) 14.2 µm·m-1·K-1
Electrical Resistivity: (20 °C) 22.14 nΩ·m
Tensile Strength: 120 MPa
Molar Heat Capacity: 25.418 J·mol-1·K-1
Young's Modulus: 79 GPa
Shear Modulus: 27 GPa
Bulk Modulus: 180 GPa
Poisson Ratio: 0.44
Mohs Hardness: 2.5
Vickers Hardness: 216 MPa
Brinell Hardness: 25 HB
Speed of Sound: (r.t.) 2030 m·s-1
Pauling Electronegativity: 2.54
Sanderson Electronegativity: N/A
Allred Rochow Electronegativity: 1.42
Mulliken-Jaffe Electronegativity: 1.87 (s orbital)
Allen Electronegativity: N/A
Pauling Electropositivity: 1.46
Reflectivity (%): 95
Refractive Index: N/A
Electrons: 79
Protons: 79
Neutrons: 118
Electron Configuration: [Xe] 4f142 5d10 6s1
Atomic Radius: 144 pm
Atomic Radius,
non-bonded (Å):
2.14
Covalent Radius: 136±6 pm
Covalent Radius (Å): 1.3
Van der Waals Radius: 217 pm
Oxidation States: 5, 4, 3, 2, 1, ?1, ?2 (amphoteric oxide)
Phase: Solid
Crystal Structure: lattice face centered cubic
Magnetic Ordering: diamagnetic
Electron Affinity (kJ·mol-1) 222.785
1st Ionization Energy: 890.13 kJ·mol-1
2nd Ionization Energy: 1977.96 kJ·mol-1
3rd Ionization Energy: N/A
CAS Number: 7440-57-5
EC Number: 231-165-9
MDL Number: MFCD00003436
Beilstein Number: N/A
SMILES Identifier: [Au]
InChI Identifier: InChI=1S/Au
InChI Key: PCHJSUWPFVWCPO-UHFFFAOYSA-N
PubChem CID: 23985
ChemSpider ID: 22421
Abundance
Earth - Total: 257 ppb
Mercury - Total:  516 ppm
Venus - Total: 250 ppb
Earth - Seawater (Oceans), ppb by weight: 0.05
Earth - Seawater (Oceans), ppb by atoms: 0.0016
Earth -  Crust (Crustal Rocks), ppb by weight: 3.1
Earth -  Crust (Crustal Rocks), ppb by atoms: 0.3
Sun - Total, ppb by weight: 1
Sun - Total, ppb by atoms: 0.01
Stream, ppb by weight: 0.002
Stream, ppb by atoms: 0.00001
Meterorite (Carbonaceous), ppb by weight: 170
Meterorite (Carbonaceous), ppb by atoms: 20
Typical Human Body, ppb by weight: 100
Typical Human Body, ppb by atom: 3
Universe, ppb by weight: 0.6
Universe, ppb by atom: 0.004
Discovered By: N/A
Discovery Date: Prior to 6000 BC
First Isolation: N/A

Health, Safety & Transportation Information for Gold

Gold is not toxic in its elemental form; however, safety data for gold and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the Products tab.

Safety Data
Material Safety Data Sheet MSDS
Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Precautions N/A
RTECS Number N/A
Transport Information N/A
WGK Germany nwg
Globally Harmonized System of
Classification and Labelling (GHS)
N/A

Gold Isotopes

Gold (Au) has one stable isotope, 197Au

Nuclide Isotopic Mass Half-Life Mode of Decay Nuclear Spin Magnetic Moment Binding Energy (MeV) Natural Abundance
(% by atom)
169Au 168.99808(32)# 150# µs Unknown 1/2+# N/A 1285.98 -
170Au 169.99612(22)# 310(50) µs [286(+50-40) µs] Unknown (2-) N/A 1294.05 -
171Au 170.991879(28) 17 µs p to 170Pt; α to 167Ir (1/2+) N/A 1302.13 -
172Au 171.99004(17)# 6.3 ms α to 168Ir; p to 171Pt high N/A 1310.21 -
173Au 172.986237(28) 20 ms α to 169Ir; β- to 173Pt (1/2+) N/A 1327.61 -
174Au 173.98476(11)# 120 ms α to 170Ir; β- to 174Pt low N/A 1335.68 -
175Au 174.98127(5) 185 ms α to 171Ir; β- to 175Pt 1/2+# N/A 1343.76 -
176Au 175.98010(11)# 1.08(17) s [0.84(+17-14) s] α to 172Ir; β- to 176Pt (5-) N/A 1351.84 -
177Au 176.976865(14) 1.462(32) s β- to 177Pt; α to 173Ir (1/2+,3/2+) N/A 1369.24 -
178Au 177.97603(6) 2.6(5) s β- to 178Pt; α to 174Ir N/A N/A 1377.32 -
179Au 178.973213(18) 3.3 s β- to 179Pt; α to 175Ir 5/2-# N/A 1385.39 -
180Au 179.972521(23) 8.1(3) s β- to 180Pt; α to 176Ir N/A N/A 1393.47 -
181Au 180.970079(21) 13.7(14) s β- to 181Pt; α to 177Ir (3/2-) N/A 1401.55 -
182Au 181.969618(22) 15.5(5) s β- to 182Pt; α to 178Ir (2+) N/A 1418.95 -
183Au 182.967593(11) 42.8(10) s β- to 183Pt; α to 179Ir (5/2)- N/A 1427.03 -
184Au 183.967452(24) 20.6(9) s β- to 184Pt 5+ N/A 1435.1 -
185Au 184.965789(28) 4.25(6) min β- to 185Pt; α to 180Ir 5/2- N/A 1443.18 -
186Au 185.965953(23) 10.7(5) min β- to 186Pt; α to 181Ir 3- N/A 1451.26 -
187Au 186.964568(27) 8.4(3) min β- to 187Pt; α to 182Ir 1/2+ N/A 1459.34 -
188Au 187.965324(22) 8.84(6) min β- to 188Pt 1(-) N/A 1467.42 -
189Au 188.963948(22) 28.7(3) min β- to 189Pt; α to 184Ir 1/2+ N/A 1475.5 -
190Au 189.964700(17) 42.8(10) min β- to 190Pt; α to 185Ir 1- N/A 1483.58 -
191Au 190.96370(4) 3.18(8) h β- to 191Pt 3/2+ N/A 1491.66 -
192Au 191.964813(17) 4.94(9) h β- to 192Pt 1- N/A 1499.73 -
193Au 192.964150(11) 17.65(15) h β- to 193Pt; α to 188Ir 3/2+ N/A 1507.81 -
194Au 193.965365(11) 38.02(10) h EC to 194Pt 1- 0.075 1515.89 -
195Au 194.9650346(14) 186.098(47) d EC to 195Pt 3/2+ 0.149 1523.97 -
196Au 195.966570(3) 6.1669(6) d EC to 196Pt; β- to 196Hg 2- 0.591 1532.05 -
197Au 196.9665687(6) Observationally Stable - 3/2+ 0.148159 1540.13 100
198Au 197.9682423(6) 2.69517(21) d β- to 198Hg 2- 0.5934 1548.21 -
199Au 198.9687652(6) 3.139(7) d β- to 199Hg 3/2+ 0.2715 1556.28 -
200Au 199.97073(5) 48.4(3) min β- to 200Hg 1(-) N/A 1555.05 -
201Au 200.971657(3) 26(1) min β- to 201Hg 3/2+ N/A 1563.13 -
202Au 201.97381(18) 28.8(19) s β- to 202Hg (1-) N/A 1571.2 -
203Au 202.975155(3) 53(2) s β- to 203Hg 3/2+ N/A 1579.28 -
204Au 203.97772(22)# 39.8(9) s β- to 204Hg (2-) N/A 1587.36 -
205Au 204.97987(32)# 31(2) s β- to 205Hg 3/2+ N/A 1595.44 -
Gold Elemental Symbol

Recent Research & Development for Gold

  • Raju Poddar, Maddipatla Reddikumar, In vitro 3D anterior segment imaging in lamb eye with extended depth range swept source optical coherence tomography, Optics & Laser Technology, Volume 67, April 2015
  • Arash Ahmadivand, Saeed Golmohammadi, Surface plasmon resonances and plasmon hybridization in compositional Al/Al2O3/SiO2 nanorings at the UV spectrum to the near infrared region (NIR), Optics & Laser Technology, Volume 66, March 2015
  • G.F. Sun, K. Wang, R. Zhou, Z.P. Tong, X.Y. Fang, Effect of annealing on microstructure and mechanical properties of laser deposited Co-285+WC coatings, Optics & Laser Technology, Volume 66, March 2015
  • Xin Jiang, Soni Chandrasekar, Changhai Wang, A laser microwelding method for assembly of polymer based microfluidic devices, Optics and Lasers in Engineering, Volume 66, March 2015
  • Giulio Martini, Elisa Martinelli, Giacomo Ruggeri, Giancarlo Galli, Andrea Pucci, Julolidine fluorescent molecular rotors as vapour sensing probes in polystyrene films, Dyes and Pigments, Volume 113, February 2015
  • M.A. Pogosova, D.I. Provotorov, A.A. Eliseev, M. Jansen, P.E. Kazin, Synthesis and characterization of the Bi-for-Ca substituted copper-based apatite pigments, Dyes and Pigments, Volume 113, February 2015
  • Simon Kuster, Thomas Geiger, Coupled π-conjugated chromophores: Squaraine dye dimers as two connected pendulums, Dyes and Pigments, Volume 113, February 2015
  • Zhenghuan Lin, Yingshuang Ma, Xin Zheng, Limei Huang, E Yang, Cheng-Ya Wu, Tahsin J. Chow, Qidan Ling, Amide-based diarylmaleimide derivatives and polymers: Highly selective and ratiometric fluorescence sensing for anions, Dyes and Pigments, Volume 113, February 2015
  • Qun Wang, Ji Qi, Wenqiang Qiao, Zhi Yuan Wang, Soluble ladder conjugated polypyrrones: Synthesis, characterization and application in photodetectors, Dyes and Pigments, Volume 113, February 2015
  • Lufei Xiao, Hui Wang, Qiong Zhang, Yingzhong Zhu, Junshan Luo, Yunke Liang, Shengyi Zhang, Hongping Zhou, Yupeng Tian, Jieying Wu, Novel ruthenium (II) polypyridyl complexes containing carbazole with flexible substituents: Crystal structure, nonlinear optical properties and DNA-binding interaction, Dyes and Pigments, Volume 113, February 2015