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Cerium Bromide
CeBr3
Product Product Code Order or Specifications
(2N) 99% Cerium Bromide CE-BR-02 Contact American Elements
(3N) 99.9% Cerium Bromide CE-BR-03 Contact American Elements
(4N) 99.99% Cerium Bromide CE-BR-04 Contact American Elements
(5N) 99.999% Cerium Bromide CE-BR-05 Contact American Elements
Bromide IonCerium Bromide is a highly water soluble crystalline Cerium source for uses compatible with Bromides and lower (acidic) pH. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding Cerium disulfide (CS2) and chlorine. Cerium Bromide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Cerium(Ce) atomic and molecular weight, atomic number and elemental symbolCerium is a Block F, Group 3, Period 6 element. The number of electrons in each of Cerium's shells is 2, 8, 18, 19, 9, 2 and its electronic configuration is [Xe]4f2 6s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is moderately toxic. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueousCerium Bohr Model solutions.It is, therefore,Elemental Cerium strongly acidic and moderately toxic. It is also a strong oxidizer.The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolor glass by keeping iron in its ferrous state. The ability of cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass. Cerium was first discovered by W. von Hisinger in 1903. The element was named after the asteroid Ceres. See Cerium research below.

Formula CAS No. Appearance Molecular Weight
CeBr3 14457-87-5 White Crystalline Solid 379.828
PRODUCT CATALOG Bromide Products Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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Recent Research & Development for Cerium

  • Retraction notice to "Characterization and mechanistic analysis of the visible light response of cerium and nitrogen co-doped TiO2 nano-photocatalyst synthesized using a one-step technique" [Journal of Hazardous Materials 176 (2010) 829-835]. J Hazard Mater. 2010 Oct 15;182(1-3):945. PubMed PMID: 20737669.

  • High-throughput continuous hydrothermal flow synthesis of Zn-Ce oxides: unprecedented solubility of Zn in the nanoparticle fluorite lattice. Kellici S, Gong K, Lin T, Brown S, Clark RJ, Vickers M, Cockcroft JK, Middelkoop V, Barnes P, Perkins JM, Tighe CJ, Darr JA. Philos Transact A Math Phys Eng Sci. 2010 Sep 28;368(1927):4331-49. PubMed PMID: 20732890.

  • Can simple salts influence self-assembly in oil? Multivalent cations as efficient gelators of lecithin organosols. Lee HY, Diehn KK, Ko SW, Tung SH, Raghavan SR. Langmuir. 2010 Sep 7;26(17):13831-8. PubMed PMID: 20677736.

  • Cytogenetic and developmental toxicity of cerium and lanthanum to sea urchin embryos. Oral R, Bustamante P, Warnau M, D'Ambra A, Guida M, Pagano G. Chemosphere. 2010 Sep;81(2):194-198. Epub 2010 Aug 4. PubMed PMID: 20688349.

  • Development and validation of fixed-time method for the determination of isoxsuprine hydrochloride in commercial dosages forms. Rahman N, Afaq N. Drug Test Anal. 2010 Sep 1. [Epub ahead of print] PubMed PMID: 20812296.

  • Cerium Relieves the Inhibition of Chlorophyll Biosynthesis of Maize Caused by Magnesium Deficiency. Zhou M, Gong X, Ying W, Chao L, Hong M, Wang L, Fashui H. Biol Trace Elem Res. 2010 Aug 27. [Epub ahead of print] PubMed PMID: 20798996.

  • Determination of cerium ion by polymeric membrane and coated graphite electrode based on novel pendant armed macrocycle. Singh AK, Singh P. Anal Chim Acta. 2010 Aug 24;675(2):170-180. Epub 2010 Jul 21. PubMed PMID: 20800729.

  • Aggregation Control of Hydrophilic Maghemite (gamma-Fe(2)O(3)) Nanoparticles by Surface Doping Using Cerium Atoms. Haviv AH, Grene`che JM, Lellouche JP. J Am Chem Soc. 2010 Aug 24. [Epub ahead of print] PubMed PMID: 20735060.

  • Ceria maintains smaller metal catalyst particles by strong metal-support bonding. Farmer JA, Campbell CT. Science. 2010 Aug 20;329(5994):933-6. PubMed PMID: 20724631.

  • Effect of natural organic matter on cerium dioxide nanoparticles settling in model fresh water. Quik JT, Lynch I, Hoecke KV, Miermans CJ, Schamphelaere KA, Janssen CR, Dawson KA, Stuart MA, Meent DV. Chemosphere. 2010 Aug 19. [Epub ahead of print] PubMed PMID: 20728203.

  • Redox-active radical scavenging nanomaterials. Karakoti A, Singh S, Dowding JM, Seal S, Self WT. Chem Soc Rev. 2010 Aug 17. [Epub ahead of print] PubMed PMID: 20717560.

  • Methanol adsorption and decomposition on Pt/CeO2(111)/Cu(111) thin film model catalyst. Matolín V, Johánek V, Skoda M, Tsud N, Prince KC, Skála T, Matolínová I. Langmuir. 2010 Aug 17;26(16):13333-41. PubMed PMID: 20695575.

  • Covalency in Ce(IV) and U(IV) Halide and N-Heterocyclic Carbene Bonds. Arnold PL, Turner ZR, Kaltsoyannis N, Pelekanaki P, Bellabarba RM, Tooze RP. Chemistry. 2010 Aug 16;16(31):9623-9. PubMed PMID: 20658507.

  • Virus removal by biogenic cerium. De Gusseme B, Du Laing G, Hennebel T, Renard P, Chidambaram D, Fitts JP, Bruneel E, Van Driessche I, Verbeken K, Boon N, Verstraete W. Environ Sci Technol. 2010 Aug 15;44(16):6350-6. PubMed PMID: 20704235.

  • Unveiling the mechanism of uptake and sub-cellular distribution of cerium oxide nanoparticles. Singh S, Kumar A, Karakoti A, Seal S, Self WT. Mol Biosyst. 2010 Aug 9. [Epub ahead of print] PubMed PMID: 20697616.

  • Surface-Charge-Dependent Cell Localization and Cytotoxicity of Cerium Oxide Nanoparticles. Asati A, Santra S, Kaittanis C, Perez JM. ACS Nano. 2010 Aug 6. [Epub ahead of print] PubMed PMID: 20690607.

  • Multicolored redox active upconverter cerium oxide nanoparticle for bio-imaging and therapeutics. Babu S, Cho JH, Dowding JM, Heckert E, Komanski C, Das S, Colon J, Baker CH, Bass M, Self WT, Seal S. Chem Commun (Camb). 2010 Aug 4. [Epub ahead of print] PubMed PMID: 20683524.

  • Effect of Cerium on Photosynthetic Pigments and Photochemical Reaction Activity in Soybean Seedling Under Ultraviolet-B Radiation Stress. Liang C, Zhang G, Zhou Q. Biol Trace Elem Res. 2010 Aug 3. [Epub ahead of print] PubMed PMID: 20680511.

  • [Antiviral effect of cerium dioxide nanoparticles stabilized by low-molecular polyacrylic acid]. Mikrobiol Z. 2010 May-Jun;72(3):42-7. Russian. PubMed PMID: 20695228.

  • Non-FokI-based zinc finger nucleases. Imanishi M, Negi S, Sugiura Y. Methods Mol Biol. 2010;649:337-49. PubMed PMID: 20680845.

 

Recent Research & Development for Bromides

  • Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids. Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C. Org Lett. 2010 Jan 5. [Epub ahead of print] PMID: 19689116 [PubMed - as supplied by publisher]

  • Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides. Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Science. 2009 Aug 13. [Epub ahead of print] PMID: 19679769 [PubMed - as supplied by publisher]

  • (2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides. Zhang Q, Wang D, Wang X, Ding K. J Org Chem. 2009 Aug 12. [Epub ahead of print] PMID: 19673481 [PubMed - as supplied by publisher]

  • Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides. Vechorkin O, Barmaz D, Proust V, Hu X. J Am Chem Soc. 2009 Aug 11. [Epub ahead of print] PMID: 19670863 [PubMed - as supplied by publisher]

  • Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia. Huang JM, Dong Y. Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28. PMID: 19662260 [PubMed - in process]

  • Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols. Salvi L, Kim JG, Walsh PJ. J Am Chem Soc. 2009 Aug 4. [Epub ahead of print] PMID: 19653691 [PubMed - as supplied by publisher]

  • Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines. Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J. J Comb Chem. 2009 Jul 31. [Epub ahead of print] PMID: 19645499 [PubMed - as supplied by publisher]

  • Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids. del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N. Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29. PMID: 19641822 [PubMed - in process]

  • Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides. Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639999 [PubMed - as supplied by publisher]

  • Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies. Snelders DJ, van Koten G, Klein Gebbink RJ. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639941 [PubMed - as supplied by publisher]

  • Can One Predict Changes from S(N)1 to S(N)2 Mechanisms? Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H. J Am Chem Soc. 2009 Jul 27. [Epub ahead of print] PMID: 19634906 [PubMed - as supplied by publisher]

  • A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides. Liao Q, Wang Y, Zhang L, Xi C. J Org Chem. 2009 Jul 15. [Epub ahead of print] PMID: 19603753 [PubMed - as supplied by publisher]

  • Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides. Shi L, Chu Y, Knochel P, Mayr H. Org Lett. 2009 Jul 14. [Epub ahead of print] PMID: 19601592 [PubMed - as supplied by publisher]

  • C5-Modified nucleosides exhibiting anticancer activity. Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH. Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21. PMID: 19596579 [PubMed - in process]

  • Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. Vo GD, Hartwig JF. J Am Chem Soc. 2009 Jul 10. [Epub ahead of print] PMID: 19591470 [PubMed - as supplied by publisher]

  • New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes. Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B. Org Lett. 2009 Jul 2. [Epub ahead of print] PMID: 19572730 [PubMed - as supplied by publisher]

  • The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives. Jo Y, Ju J, Choe J, Song KH, Lee S. J Org Chem. 2009 Jul 2. [Epub ahead of print] PMID: 19572571 [PubMed - as supplied by publisher]

  • Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents. Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH. Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8. PMID: 19557114 [PubMed - in process]

  • A facile route to C2-substituted imidazolium ionic liquids. Ennis E, Handy ST. Molecules. 2009 Jun 19;14(6):2235-45. PMID: 19553895 [PubMed - in process]

  • Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines. McCall WS, Comins DL. Org Lett. 2009 Jul 2;11(13):2940-2. PMID: 19552467 [PubMed - indexed for MEDLINE]

 

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