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About Cobalt

Cobalt Bohr

Much like the “kupfernickel”--devil’s copper--ores that had been so named for failing to produce the copper they were thought to contain, cobalt’s ores were frustrating to miners. Not only did they fail to yield useful metals, these ores additionally produced toxic arsenic oxide when smelted. The ores were therefore named after kobolds--goblins that German miners frequently blamed for mining mishaps. When, around 1935, the Swedish chemist Georg Brandt succeeded in isolating cobalt metal, he named his newly discovered element for its ore.

In addition to discovering cobalt, Brandt demonstrated that cobalt compounds had been unknowingly used to provide coloring in smalt, a blue glass, since the middle ages. In the late eighteenth and early nineteenth century, green and blue pigments based on cobalt were developed and came into widespread use for coloring ceramics, jewelry, and paint. These applications for cobalt remain relevant in modern times, but today cobalt is used most often in metallic form.

The majority of cobalt consumed in the United States is used in the production of superalloys, metal formulations which most often find use in arenas where resistance to extreme conditions are required, such as in the components of jet engines or high-speed drill bits. Superalloys are also sometimes used in medical implants such as hip replacement, though these implants must be monitored for damage, as metal nanoparticles produced by wear are easily absorbed by and distributed through the body. Cobalt found in cobalamin, also known as vitamin B12, is an essential nutrient, but excess free cobalt ions in the body have toxic effects.

Cobalt is also used in other alloy applications. It is found in both Alnico and samarium-cobalt magnets, both of which are used widely in industry. Cobalt is also found in combination with primary electrode metals in lithium ion, nickel-cadmium, and nickel metal hydride batteries. Cobalt’s attractive appearance, extreme hardness, and resistance to oxidation lend it to use as a metal for plating of other materials, either alone or as the base for further coatings such as porcelain enamels. Platinum used in jewelry making contains five percent cobalt, as this produces an alloy that is suitable for highly detailed casting.

There are two other major uses for cobalt in industry. The first is as a catalyst: cobalt compounds are used industrially to produce polymer precursors, remove sulfurous impurities from petroleum, and improve adhesion of steel to rubber for the production of steel-belted tires. Additionally, cobalt catalysts are added as drying agents to paints and varnishes, and used in a variety of other chemical processes, on both industrial and lab-scales.The second other major use is as a binder in cemented carbides, extremely hard materials used in machining metals such as steel.

Finally, cobalt radioisotopes serve a few notable functions. Cobalt-60 is a radioactive isotope used to produce gamma rays for sterilizing food and medical supplies and for use in both medical radiotherapy and the in the production of industrial radiographs. Cobalt-57 is used as a tracer in medical imaging, primarily for observing vitamin B12 uptake.

The main cobalt ores are cobaltite, erythrite, glaucodot, and skutterudite, all of which are exploited commercially, but a substantial amount of the metal is also obtained from processing byproducts of copper and nickel mining. Cobalt catalysts and cobalt-alloy scrap may also be recycled to recover high purity cobalt.

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Cobalt is often alloyed with iron, nickel and other metals to make Alnico, an alloy of unusual magnetic strength with many important uses. Samarium-cobalt, for instance, is one of the highest strength magnet alloys known. Cobalt compounds are used to produce a brilliant and permanent blue color in ceramic glazes, glass, High Purity (99.999%) Cobalt Oxide (Co3O4) Powderpottery, tiles, and enamels. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. High Purity (99.999%) Cobalt (Co) Sputtering TargetCobalt is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity). Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Cobalt nanoparticles and nanopowders are also available. Cobalt oxides are available in powder and dense pellet form for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Cobalt fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Cobalt is also available in soluble forms including chlorides, nitrates and acetates. These compounds can be manufactured as solutions at specified stoichiometries.

Cobalt Properties

Cobalt(Co) atomic and molecular weight, atomic number and elemental symbolCobalt is a Block D, Group 9, Period 4 element. The number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar] 3d7 4s2. Cobalt Bohr ModelThe cobalt atom has a radius of 125.3.pm and its Van der Waals radius is 200.pm. In its elemental form, CAS 7440-48-4, cobalt has a Elemental Cobaltlustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores, but is not found free in nature. Cobalt was first discovered by George Brandt in 1732. The origin of the word Cobalt comes from the German word 'Kobalt or Kobold' which translates as "goblin", "elf" or "evil spirit".

Symbol: Co
Atomic Number: 27
Atomic Weight: 58.9332
Element Category: transition metal
Group, Period, Block: 9, 4, d
Color: lustrous, metallic, grayish tinge /bluish-white
Other Names: Cobaltum, Cobalto, Kobalt, Kobolt
Melting Point: 1495.0 °C, 2723.0 °F, 1768.15 K
Boiling Point: 2870.0 °C, 5198.0 °F, 3143.15 K
Density: 8.9 gm/cm3
Liquid Density @ Melting Point: 7.75 g·cm3
Density @ 20°C: 8.90 g/cm3
Density of Solid: 8900 kg·m3
Specific Heat: 0.109 Cal/g/K @ 25°C
Superconductivity Temperature: N/A
Triple Point: N/A
Critical Point: N/A
Heat of Fusion (kJ·mol-1): 15.2
Heat of Vaporization (kJ·mol-1): 382.4
Heat of Atomization (kJ·mol-1): 423.082
Thermal Conductivity: 1.0 W/cm/K @ 298.2 K
Thermal Expansion: (25 °C) 13.0 µm·m-1·K-1
Electrical Resistivity: 6.24 µΩ·m @ 20°C
Tensile Strength: N/A
Molar Heat Capacity: 24.81 J·mol-1·K-1
Young's Modulus: 209 GPa
Shear Modulus: 75 GPa
Bulk Modulus: 180 GPa
Poisson Ratio: 0.31
Mohs Hardness: 5
Vickers Hardness: 1043 MPa
Brinell Hardness: 700 MPa
Speed of Sound: (20 °C) 4720 m·s-1
Pauling Electronegativity: 1.88
Sanderson Electronegativity: 2.56
Allred Rochow Electronegativity: 1.7
Mulliken-Jaffe Electronegativity: N/A
Allen Electronegativity: N/A
Pauling Electropositivity: 2.12
Reflectivity (%): 67
Refractive Index: N/A
Electrons: 27
Protons: 27
Neutrons: 32
Electron Configuration: [Ar] 3d7 4s2
Atomic Radius: 125 pm
Atomic Radius,
non-bonded (Å):
2
Covalent Radius: 126±3 (low spin), 150±7 (high spin) pm
Covalent Radius (Å): 1.18
Van der Waals Radius: 200 pm
Oxidation States: 5, 4, 3, 2, 1, -1 (amphoteric oxide)
Phase: Solid
Crystal Structure: Hexagonal
Magnetic Ordering: ferromagnetic
Electron Affinity (kJ·mol-1) 63.851
1st Ionization Energy: 760.41 kJ·mol-1
2nd Ionization Energy: 1648.27 kJ·mol-1
3rd Ionization Energy: 3232.28 kJ·mol-1
CAS Number: 7440-48-4
EC Number: 231-158-0
MDL Number: MFCD00010935
Beilstein Number: N/A
SMILES Identifier: [Co]
InChI Identifier: InChI=1S/Co
InChI Key: GUTLYIVDDKVIGB-UHFFFAOYSA-N
PubChem CID: 104730
ChemSpider ID: 94547
Earth - Total: 840 ppm
Mercury - Total: 1690 ppm
Venus - Total: 820 ppm
Earth - Seawater (Oceans), ppb by weight: 0.08
Earth - Seawater (Oceans), ppb by atoms: 0.008
Earth -  Crust (Crustal Rocks), ppb by weight: 30000
Earth -  Crust (Crustal Rocks), ppb by atoms: 10000
Sun - Total, ppb by weight: 4000
Sun - Total, ppb by atoms: 70
Stream, ppb by weight: 0.2
Stream, ppb by atoms: 0.003
Meterorite (Carbonaceous), ppb by weight: 600000
Meterorite (Carbonaceous), ppb by atoms: 200000
Typical Human Body, ppb by weight: 20
Typical Human Body, ppb by atom: 2
Universe, ppb by weight: 3000
Universe, ppb by atom: 60
Discovered By: Georg Brandt
Discovery Date: 1732
First Isolation: N/A

Health, Safety & Transportation Information for Cobalt

Toxicity of cobalt and its compounds are mild by skin contact and moderate by ingestion. Safety data for Cobalt and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the Products tab. The below information applies to elemental (metallic) Cobalt.

Safety Data
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H317-H334-H413
Hazard Codes Xn
Risk Codes 42/43-53
Safety Precautions 22-24-37-61
RTECS Number GF8750000
Transport Information UN 3089 4.1/PG 2
WGK Germany nwg
Globally Harmonized System of
Classification and Labelling (GHS)
Health Hazard

Cobalt Isotopes

Naturally occurring cobalt has 1 stable isotope: 59Co.

Nuclide Isotopic Mass Half-Life Mode of Decay Nuclear Spin Magnetic Moment Binding Energy (MeV) Natural Abundance
(% by atom)
47Co 47.01149(54)# N/A Unknown 7/2-# N/A 339.16 -
48Co 48.00176(43)# N/A p to 47Fe (6+) N/A 356.55 -
49Co 48.98972(28)# <35 ns p to 48Fe 7/2-# N/A 375.81 -
50Co 49.98154(18)# 44(4) ms β+ + p to 49Mn; β+ to 50Fe (6+) N/A 391.34 -
51Co 50.97072(16)# 60# ms [>200 ns] p to 51Fe 7/2-# N/A 409.67 -
52Co 51.96359(7)# 115(23) ms p to 52Fe 0+ N/A 424.27 -
53Co 52.954219(19) 242(8) ms p to 53Fe 7/2- N/A 440.73 -
54Co 53.9484596(8) 193.28(7) ms p to 54Fe 4+ N/A 454.4 -
55Co 54.9419990(8) 17.53(3) h EC to 55Fe 7/2- 4.822 469 -
56Co 55.9398393(23) 77.233(27) d EC to 56Fe 2+ 3.85 478.94 -
57Co 56.9362914(8) 271.74(6) d EC to 57Fe 7/2- 4.72 489.82 -
58Co 57.9357528(13) 70.86(6) d EC to 58Fe 5+ 4.04 498.83 -
59Co 58.9331950(7) STABLE - 7/2- 4.627 508.77 100
60Co 59.9338171(7) 5.2713(8) y β- to 60Ni 2+ 3.799 516.85 -
61Co 60.9324758(10) 1.650(5) h β- to 61Ni 7/2- N/A 525.86 -
62Co 61.934051(21) 1.50(4) min β- to 62Ni 1+ N/A 532.07 -
63Co 62.933612(21) 26.9(4) s β- to 63Ni (7/2)- N/A 541.08 -
64Co 63.935810(21) 0.30(3) s β- to 64Ni (3+) N/A 547.3 -
65Co 64.936478(14) 1.20(6) s β- to 65Ni (7/2-)# N/A 554.44 -
66Co 65.93976(27) 0.18(1) s β- to 66Ni (7-) N/A 559.73 -
67Co 66.94089(34) 0.425(20) s β- to 67Ni 7/2-# N/A 566.88 -
68Co 67.94487(34) 0.199(21) s β- to 68Ni (6-) N/A 571.23 -
69Co 68.94632(36) 227(13) ms β- to 69Ni; β- + n to 68Ni 7/2-# N/A 577.44 -
70Co 69.9510(9) 119(6) ms β- to 70Ni; β- + n to 69Ni (6-,7-) N/A 580.86 -
71Co 70.9529(9) 97(2) ms β- to 71Ni; β- + n to 70Ni 7/2-# N/A 588.01 -
72Co 71.95781(64)# 62(3) ms β- to 72Ni; β- + n to 71Ni 0+ N/A 591.43 -
73Co 72.96024(75)# 41(4) ms Unknown 7/2-# N/A 596.72 -
74Co 73.96538(86)# 50# ms [>300 ns] Unknown 0 N/A 600.14 -
75Co 74.96833(86)# 40# ms [>300 ns] Unknown 7/2 N/A 605.42 -
Cobalt Elemental Symbol

Recent Research & Development for Cobalt

  • Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions. Pagano JK, Stelmach JP, Waterman R. Dalton Trans. 2015 Mar 5.
  • Influence of Bi3+-doping on the magnetic and Mössbauer properties of spinel cobalt ferrite. Gore SK, Mane RS, Naushad M, Jadhav SS, Zate MK, Alothman ZA, Hui BK. Dalton Trans. 2015 Mar 6.
  • Investigation on cobalt-oxide nanoparticles cyto-genotoxicity and inflammatory response in two types of respiratory cells. Cavallo D, Ciervo A, Fresegna AM, Maiello R, Tassone P, Buresti G, Casciardi S, Iavicoli S, Ursini CL. J Appl Toxicol. 2015 Mar 13.
  • Controllable fabrication and magnetic properties of double-shell cobalt oxide hollow particles. Zhang D, Zhu J, Zhang N, Liu T, Chen L, Liu X, Ma R, Zhang H, Qiu G. Sci Rep. 2015 Mar 4
  • A Three-Dimensional Complex with a One-Dimensional Cobalt-Hydroxyl Chain Based on Planar Nonanuclear Clusters Showing Spin-Canted Antiferromagnetism. Li B, Li Z, Wei RJ, Yu F, Chen X, Xie YP, Zhang TL, Tao J. Inorg Chem. 2015 Mar 11.
  • Cobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp(3) carbons. Wu X, Yang K, Zhao Y, Sun H, Li G, Ge H. Nat Commun. 2015 Mar 10
  • Validation and analysis of dose distributions in a new and entirely redesigned cobalt-60 stereotactic radiosurgery units. Nakazawa H, Uchiyama Y, Komori M. Nihon Hoshasen Gijutsu Gakkai Zasshi. 2015 Feb
  • Exposing the intermolecular nature of the second relaxation pathway in a mononuclear cobalt(ii) single-molecule magnet with positive anisotropy. Habib F, Korobkov I, Murugesu M. Dalton Trans. 2015 Mar 5.
  • In situ Formation of Cobalt Oxide Nanocubanes as Efficient Oxygen Evolution Catalysts. Hutchings GS, Zhang Y, Li J, Yonemoto BT, Zhou X, Zhu K, Jiao F. J Am Chem Soc. 2015 Mar 11.
  • N-doped graphitic layer encased cobalt nanoparticles as efficient oxygen reduction catalysts in alkaline media. Han C, Bo X, Zhang Y, Li M, Nsabimana A, Guo L. Nanoscale. 2015 Mar 9.
  • Dosimetric feasibility of magnetic resonance imaging-guided tri-cobalt 60 preoperative intensity modulated radiation therapy for soft tissue sarcomas of the extremity. Kishan AU, Cao M, Mikaeilian AG, Low DA, Kupelian PA, Steinberg ML, Kamrava M. Pract Radiat Oncol. 2015 Mar 3.
  • Air- and Water-Resistant Noble Metal Coated Ferromagnetic Cobalt Nanorods. Lentijo-Mozo S, Tan RP, Garcia-Marcelot C, Altantzis T, Fazzini PF, Hungria T, Cormary B, Gallagher JR, Miller JT, Martinez H, Schrittwieser S, Schotter J, Respaud M, Bals S, Tendeloo GV, Gatel C, Soulantica K. ACS Nano. 2015 Mar 9.
  • Cytogenetic characterization of low-dose hyper-radiosensitivity in Cobalt-60 irradiated human lymphoblastoid cells. Joshi GS, Joiner MC, Tucker JD. Mutat Res. 2014 Dec
  • Electronic structure at transition metal phthalocyanine-transition metal oxide interfaces: Cobalt phthalocyanine on epitaxial MnO films. Glaser M, Peisert H, Adler H, Aygül U, Ivanovic M, Nagel P, Merz M, Schuppler S, Chassé T. J Chem Phys. 2015 Mar 14
  • Toxicology of wear particles of cobalt-chromium alloy metal-on-metal hip implants part II: Importance of physicochemical properties and dose in animal and in vitro studies as a basis for risk assessment. Madl AK, Kovochich M, Liong M, Finley BL, Paustenbach DJ, Oberdörster G. Nanomedicine. 2015 Feb 28.
  • High-performance hybrid oxide catalyst of manganese and cobalt for low-pressure methanol synthesis. Li CS, Melaet G, Ralston WT, An K, Brooks C, Ye Y, Liu YS, Zhu J, Guo J, Alayoglu S, Somorjai GA. Nat Commun. 2015 Mar 10
  • In situ generation of hydroxyl radical by cobalt oxide supported porous carbon enhance removal of refractory organics in tannery dyeing wastewater. Karthikeyan S, Boopathy R, Sekaran G. J Colloid Interface Sci. 2015 Feb 4
  • Fast discharge process of layered cobalt oxides due to high Na(+) diffusion. Shibata T, Fukuzumi Y, Kobayashi W, Moritomo Y. Sci Rep. 2015 Mar 11
  • Reaction Mechanism of Cobalt-Substituted Homoprotocatechuate 2,3-Dioxygenase -A QM/MM Study. Cao L, Dong G, Lai W. J Phys Chem B. 2015 Mar 9.
  • Toxicology of wear particles of cobalt-chromium alloy metal-on-metal hip implants Part I: Physicochemical properties in patient and simulator studies. Madl AK, Liong M, Kovochich M, Finley BL, Paustenbach DJ, Oberdörster G. Nanomedicine. 2015 Mar 3.