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Cobalt
Cobalt information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Cobalt has a metallic permeability two thirds that of iron. It exists as a mixture of two allotropes over a wide temperature range. The transformation is slow and accounts in part for the wide variation in the physical properties of cobalt. It is alloyed with iron, nickel and other metals to make Alnico, an alloy of unusual magnetic strength with many important uses. Samarium-cobalt is one of the highest strength magnet alloys known. Cobalt compounds produce a brilliant and permanent blue color in ceramic glazes, glass, pottery, tiles, and enamels. Co-60 is useful as a gamma ray source. Cobalt is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Cobalt facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Cobalt is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Cobalt is a Block D, Group 9, Period 4 element. The electronic configuration is [Ar] 3d7 4s2. In its elemental form cobalt's CAS number is 7440-48-4. The cobalt atom has a radius of 125.3.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Cobalt compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Cobalt was first discovered by George Brandt in 1737.

French Cobalt German Cobalt Italian cobalto Portuguese Cobalto Spanish cobalto Swedish Kobolt

Abundance. The following table shows the abundance of cobalt and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Co-59
58.933200
100

Safety Data. The safety data for cobalt metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Hardness. Cobalt is a hard, brittle metal measuring 5.5 on the Mohs Scale of mineral hardness.

Ionization Energy. The ionization energy for cobalt (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
760.41 kJ mol-1
2nd Ionization Energy
1648.27 kJ mol-1
3rd Ionization Energy
3232.28 kJ mol-1

Conductivity. As to cobalt's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 6.24 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.88. The thermal conductivity of cobalt is 100 W m-1 K-1.

Thermal Properties. The melting point and boiling point for cobalt are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
15.2 kJ mol-1
Heat of Vaporization
382.4 kJ mol-1
Heat of Atomization
423.082 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Co 27 58.9332 g.mol -1 1.8 8.9 g.cm-3 at 20 °C 1495 °C 2927 °C 200.pm 0.078 nm (+2) ; 0.063 nm (+3) 760.41 kJ.mol-1

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Recent Research & Development for Cobalt

  • Aging effects on cobalt availability in soils. Wendling LA, Kirby JK, McLaughlin MJ. Environ Toxicol Chem. 2009 Aug;28(8):1609-17. Epub 2009 Mar 24. PMID: 19642829 [PubMed - in process]

  • Hypoxia-inducible factor-1alpha suppresses the expression of macrophage scavenger receptor 1. Shirato K, Kizaki T, Sakurai T, Ogasawara JE, Ishibashi Y, Iijima T, Okada C, Noguchi I, Imaizumi K, Taniguchi N, Ohno H. Pflugers Arch. 2009 Jul 30. [Epub ahead of print] PMID: 19641936 [PubMed - as supplied by publisher]

  • Hypoxia upregulates CD36 expression and function via hif-1 and PI3K dependent mechanisms. Mwaikambo BR, Yang C, Chemtob S, Hardy P. J Biol Chem. 2009 Jul 29. [Epub ahead of print] PMID: 19640849 [PubMed - as supplied by publisher]

  • Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides. Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639999 [PubMed - as supplied by publisher]

  • Cobalt-Mediated [3 + 2]-Annulation Reaction of Alkenes with alpha,beta-Unsaturated Ketones and Imines. Schomaker JM, Toste FD, Bergman RG. Org Lett. 2009 Jul 29. [Epub ahead of print] PMID: 19639989 [PubMed - as supplied by publisher]

  • A W-band pulsed EPR/ENDOR study of Co(II)S(4) coordination in the Co[(SPPh(2))(SP(i)Pr(2))N](2) complex. Sottini S, Mathies G, Gast P, Maganas D, Kyritsis P, Groenen EJ. Phys Chem Chem Phys. 2009 Aug 21;11(31):6727-32. Epub 2009 Jul 8. PMID: 19639146 [PubMed - in process]

  • Cryophotolysis of a caged oxygen compound for use in low temperature biological studies. Howard-Jones AR, Adam V, Cowley A, Baldwin JE, Bourgeois D. Photochem Photobiol Sci. 2009 Aug;8(8):1150-6. Epub 2009 Jun 1. PMID: 19639117 [PubMed - in process]

  • Implant abutment deformation during prosthetic cylinder screw tightening: an in vitro study. Neto RT, Moura MS, Souza EA, Rubo JH. Int J Prosthodont. 2009 Jul-Aug;22(4):391-5. PMID: 19639078 [PubMed - in process]

  • Direct electrochemical determination of carbaryl using a multi-walled carbon nanotube/cobalt phthalocyanine modified electrode. Moraes FC, Mascaro LH, Machado SA, Brett CM. Talanta. 2009 Oct 15;79(5):1406-11. Epub 2009 Jun 12. PMID: 19635377 [PubMed - in process]

  • No superiority of cemented metal-on-metal vs metal-on-polyethylene THA at 5-year follow-up. Zijlstra WP, Cheung J, Sietsma MS, van Raay JJ, Deutman R. Orthopedics. 2009 Jul;32(7):479. doi: 10.3928/01477447-20090527-06. PMID: 19634856 [PubMed - in process]

  • Bare-metal stents versus drug-eluting stents in large (>/=3.5mm) single coronary artery: Angiographic and clinical outcomes at 6 months. Na JO, Kim JW, Choi CU, Choi UJ, Shin SY, Lim HE, Kim EJ, Rha SW, Park CG, Seo HS, Oh DJ. J Cardiol. 2009 Aug;54(1):108-14. Epub 2009 Jun 13. PMID: 19632529 [PubMed - in process]

  • Prevalence of nickel and cobalt allergy among female patients with dermatitis before and after Danish government regulation: A 23-year retrospective study. Thyssen JP, Johansen JD, Carlsen BC, Menné T. J Am Acad Dermatol. 2009 Jul 23. [Epub ahead of print] PMID: 19632002 [PubMed - as supplied by publisher]

  • Removal of Co(2+) ions from aqueous solution by cation exchange sorption onto NiO. Naeem A, Saddique MT, Mustafa S, Tasleem S, Shah KH, Waseem M. J Hazard Mater. 2009 Jul 4. [Epub ahead of print] PMID: 19631452 [PubMed - as supplied by publisher]

  • Structure and Electronic Properties of Graphene Nanoislands on Co(0001). Eom D, Prezzi D, Rim KT, Zhou H, Lefenfeld M, Xiao S, Nuckolls C, Hybertsen MS, Heinz TF, Flynn GW. Nano Lett. 2009 Jul 24. [Epub ahead of print] PMID: 19630380 [PubMed - as supplied by publisher]

  • Cytotoxic activity, X-ray crystal structures and spectroscopic characterization of cobalt(II), copper(II) and zinc(II) coordination compounds with 2-substituted benzimidazoles. Sánchez-Guadarrama O, López-Sandoval H, Sánchez-Bartéz F, Gracia-Mora I, Höpfl H, Barba-Behrens N. J Inorg Biochem. 2009 Jun 16. [Epub ahead of print] PMID: 19628280 [PubMed - as supplied by publisher]

  • Subsurface changes of a MoM hip implant below different contact zones. Pourzal R, Theissmann R, Williams S, Gleising B, Fisher J, Fischer A. J Mech Behav Biomed Mater. 2009 Apr;2(2):186-91. Epub 2008 Aug 23. PMID: 19627822 [PubMed - in process]

  • The Short-Term Effect on Restenosis and Thrombosis of a Cobalt-Chromium Stent Eluting Two Drugs in a Porcine Coronary Artery Model. Huang Y, Venkatraman SS, Boey FY, Umashankar PR, Mohanty M, Arumugam S. J Interv Cardiol. 2009 Jul 13. [Epub ahead of print] PMID: 19627432 [PubMed - as supplied by publisher]

  • Mechanistic Aspects of the Copolymerization of CO(2) with Epoxides Using a Thermally Stable Single-Site Cobalt(III) Catalyst. Ren WM, Liu ZW, Wen YQ, Zhang R, Lu XB. J Am Chem Soc. 2009 Jul 22. [Epub ahead of print] PMID: 19624164 [PubMed - as supplied by publisher]

  • Homodimerization and Heterodimerization of Minimal Zinc(II)-Binding-Domain Peptides of T-Cell Proteins CD4, CD8alpha, and Lck. Davis AM, Berg JM. J Am Chem Soc. 2009 Jul 22. [Epub ahead of print] PMID: 19624124 [PubMed - as supplied by publisher]

  • Three-Coordinate and Four-Coordinate Cobalt Hydride Complexes That React with Dinitrogen. Ding K, Brennessel WW, Holland PL. J Am Chem Soc. 2009 Jul 21. [Epub ahead of print] PMID: 19621923 [PubMed - as supplied by publisher]

 

 

 

 

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