Degradation of bisphenol A by electro-enhanced heterogeneous activation of peroxydisulfate using Mn-Zn ferrite from spent alkaline Zn-Mn batteries.

Title Degradation of bisphenol A by electro-enhanced heterogeneous activation of peroxydisulfate using Mn-Zn ferrite from spent alkaline Zn-Mn batteries.
Authors B. Deng; Y. Li; W. Tan; Z. Wang; Z. Yu; S. Xing; H. Lin; H. Zhang
Journal Chemosphere
DOI 10.1016/j.chemosphere.2018.03.194
Abstract

Mn-Zn ferrite (MnZnFeO) was prepared by a gel method using spent alkaline Zn-Mn batteries as raw materials and employed as catalyst to degrade bisphenol A (BPA) by electro-enhanced heterogeneous activation of peroxydisulfate (PDS). The effects of initial pH, current density, PDS concentration, and Mn-Zn ferrite dosage on BPA removal were investigated. The formation of reactive radicals was verified by electron paramagnetic resonance (EPR) spectroscopy. The results of radical quenching experiments indicate that surface-bound sulfate and hydroxyl radicals played an important role in BPA removal. The stability of MnZnFeO catalyst was investigated by cycling experiments, which indicates MnZnFeO is stable and can be reused. This work also provides an alternative way for the reutilization of spent alkaline Zn-Mn batteries.

Citation B. Deng; Y. Li; W. Tan; Z. Wang; Z. Yu; S. Xing; H. Lin; H. Zhang.Degradation of bisphenol A by electro-enhanced heterogeneous activation of peroxydisulfate using Mn-Zn ferrite from spent alkaline Zn-Mn batteries.. Chemosphere. 2018;204:178185. doi:10.1016/j.chemosphere.2018.03.194

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