Enhancement of photoelectrochemical oxidation by an amorphous nickel boride catalyst on porous BiVO.

Title Enhancement of photoelectrochemical oxidation by an amorphous nickel boride catalyst on porous BiVO.
Authors K. Dang; X. Chang; T. Wang; J. Gong
Journal Nanoscale
DOI 10.1039/c7nr06636h
Abstract

This paper describes an amorphous nickel boride (NiB) electrocatalyst loaded on porous bismuth vanadate (BiVO) with high activity for oxygen evolution in photoelectrochemical water oxidation. The NiB-decorated BiVO photoanode exhibits an onset potential of 0.25 V versus the reversible hydrogen electrode (vs. RHE) and a photocurrent of 3.47 mA cm at 1.23 V vs. RHE under simulated 100 mW cm irradiation.

Citation K. Dang; X. Chang; T. Wang; J. Gong.Enhancement of photoelectrochemical oxidation by an amorphous nickel boride catalyst on porous BiVO.. Nanoscale. 2017;9(42):1613316137. doi:10.1039/c7nr06636h

Related Elements

Boron

See more Boron products. Boron Bohr ModelBoron (atomic symbol: B, atomic number: 5) is a Block P, Group 13, Period 2 element with an atomic weight of 10.81. The number of electrons in each of boron's shells is 2, 3 and its electron configuration is [He] 2s2 2p1. The boron atom has a radius of 90 pm and a Van der Waals radius of 192 pm. Boron was discovered by Joseph Louis Gay-Lussac and Louis Jacques Thénard in 1808 and was first isolated by Humphry Davy later that year. Boron is classified as a metalloid is not found naturally on earth. Elemental BoronAlong with carbon and nitrogen, boron is one of the few elements in the periodic table known to form stable compounds featuring triple bonds. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. The name Boron originates from a combination of carbon and the Arabic word buraqu meaning borax.

Nickel

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

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