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Manganese Bromide
Hydrate 10031-20-6 MnBr2·4H2O
Anhydrous 13446-03-2 MnBr2
Product Product Code Order or Specifications
(2N) 99% Manganese Bromide MN-BR-02 Contact American Elements
(3N) 99.9% Manganese Bromide MN-BR-03 Contact American Elements
(4N) 99.99% Manganese Bromide MN-BR-04 Contact American Elements
(5N) 99.999% Manganese Bromide MN-BR-05 Contact American Elements
Bromide IonManganese Bromide is a highly water soluble crystalline Manganese source for uses compatible with Bromides and lower (acidic) pH. Metallic Bromides are marketed under the trade name AE Bromides™. Hydrate or anhydrous forms may be purchased. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding carbon disulfide (CS2) and chlorine. Manganese Bromide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Manganese(Mn) atomic and molecular weight, atomic number and elemental symbolManganese is a Block D, Group 7, Period 4 element. The number of electrons in each of Manganese's shells is 2, 8, 13, 2 and its electronic configuration is [Ar] 3d5 4s2. In its elemental form manganese's CAS number is 7439-96-5. The manganese atom has a radius of 136.7.pm and it's Van der Waals radius is 200.pm. Manganese in excess is toxic, in particular the inhalation of manganese in powder or dust form. Manganese metal is a key component of aluminum alloys. Manganese oxide is used in dry cellManganese Bohr Model batteries. Manganese is used in steel production to remove sulfur and oxygen. Manganese is the colorant in natural Elemental Manganeseamethyst stones and is used in glass and ceramics to also create the amethyst color. It is used like the element cerium to "decolorize" glass by offsetting the green from impurities of ferric ions. Permanganate is a powerful oxidizing agent and is used in medicine. It is added as a nutritional supplement for both human and animal consumption. Recently, the oxide in the form of various perovskite structures have demonstrated applications in oxygen generation and solid oxide fuel cells. Manganese was first discovered by Johann Gahn in 1774. The name Manganese originates from the Latin word mangnes meaning magnet. See Manganese research below.

Formula CAS No. Appearance Molecular Weight
MnBr2·4H2O 10031-20-6 Pink Crystals 286.81
PRODUCT CATALOG Bromide Products Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

 

 

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Recent Research & Development for Manganese

  • Citric acid production from Aspergillus niger MT-4 using hydrolysate extract of the insect Locusta migratoria. Taskin M, Tasar GE, Incekara U. Toxicol Ind Health. 2012 Feb 9. [Epub ahead of print] PMID: 22323475 [PubMed - as supplied by publisher]

  • Seminal Plasma Metals Concentration with Respect to Semen Quality. Li P, Zhong Y, Jiang X, Wang C, Zuo Z, Sha A. Biol Trace Elem Res. 2012 Feb 10. [Epub ahead of print] PMID: 22322880 [PubMed - as supplied by publisher]

  • Fermentable Carbohydrate Alters Hypothalamic Neuronal Activity and Protects Against the Obesogenic Environment. Anastasovska J, Arora T, Sanchez Canon GJ, Parkinson JR, Touhy K, R Gibson G, Nadkarni NA, So PW, Goldstone AP, Thomas EL, K Hankir M, Van Loo J, Modi N, Bell JD, Frost G. Obesity (Silver Spring). 2012 Jan 17. doi: 10.1038/oby.2012.6. [Epub ahead of print] PMID: 22322344 [PubMed - as supplied by publisher]

  • Tremor, olfactory and motor changes in Italian adolescents exposed to historical ferro-manganese emission. Lucchini RG, Guazzetti S, Zoni S, Donna F, Peter S, Zacco A, Salmistraro M, Bontempi E, Zimmerman NJ, Smith DR. Neurotoxicology. 2012 Jan 31. [Epub ahead of print] PMID: 22322213 [PubMed - as supplied by publisher]

  • Measuring hypoxia induced metal release from highly contaminated estuarine sediments during a 40day laboratory incubation experiment. Banks JL, Ross DJ, Keough MJ, Eyre BD, Macleod CK. Sci Total Environ. 2012 Feb 8. [Epub ahead of print] PMID: 22321900 [PubMed - as supplied by publisher]

  • Catalytic remediation of 2-propanol on Pt-Mn/?-Al(2)O(3) bimetallic catalyst during catalytic combustion-Experimental study and response surface methodology (RSM) modeling. Salari D, Niaei A, Aghazadeh F, Hosseini SA, Seyednajafi F. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2012 Feb;47(3):351-7. PMID: 22320686 [PubMed - in process]

  • A healthy volunteer study to investigate trace element contamination of blood samples by stainless steel venepuncture needles. Hodnett D, Wood DM, Raja K, Dargan PI, Shah AD. Clin Toxicol (Phila). 2012 Feb;50(2):99-107. PMID: 22320210 [PubMed - in process]

  • Homogeneity and stability studies during the preparation of a laboratory reference material of soy leaves for the determination of metals. dos Santos AM, Lima DC, de Jesus RM, Ferreira SL. J AOAC Int. 2011 Nov-Dec;94(6):1906-10. PMID: 22320099 [PubMed - in process]

  • Initial Steps of Photosystem II de Novo Assembly and Preloading with Manganese Take Place in Biogenesis Centers in Synechocystis. Stengel A, Gügel IL, Hilger D, Rengstl B, Jung H, Nickelsen J. Plant Cell. 2012 Feb 7. [Epub ahead of print] PMID: 22319052 [PubMed - as supplied by publisher]

  • Physiologic implications of metal-ion transport by ZIP14 and ZIP8. Jenkitkasemwong S, Wang CY, Mackenzie B, Knutson MD. Biometals. 2012 Feb 9. [Epub ahead of print] PMID: 22318508 [PubMed - as supplied by publisher]

  • The Association of Manganese Superoxide Dismutase Expression in Barrett's Esophageal Progression With MnTBAP and Curcumin Oil Therapy. Schiffman SC, Li Y, Martin RC. J Surg Res. 2011 Dec 13. [Epub ahead of print] PMID: 22316666 [PubMed - as supplied by publisher]

  • Monte-Carlo simulations of the new LNHB manganese bath facility. Ogheard F, Chartier JL, Cassette P. Appl Radiat Isot. 2012 Jan 25. [Epub ahead of print] PMID: 22316586 [PubMed - as supplied by publisher]

  • Proteomic analysis of proteins associated with cellular senescence by calorie restriction in mesenchymal stem cells. Kim HJ, Ji BR, Kim JS, Lee HN, Ha DH, Kim CW. In Vitro Cell Dev Biol Anim. 2012 Feb 8. [Epub ahead of print] PMID: 22314686 [PubMed - as supplied by publisher]

  • Metal concentrations in the soils and native plants surrounding the old flotation tailings pond of the Copper Mining and Smelting Complex Bor (Serbia). Antonijevic MM, Dimitrijevic MD, Milic SM, Nujkic MM. J Environ Monit. 2012 Feb 8. [Epub ahead of print] PMID: 22314513 [PubMed - as supplied by publisher]

  • Research capacity development in South African manganese mines to bridge exposure and neuropathologic outcomes. Nelson G, Criswell SR, Zhang J, Murray J, Racette BA. Neurotoxicology. 2012 Jan 31. [Epub ahead of print] PMID: 22313906 [PubMed - as supplied by publisher]

  • Manganese toxicity with ephedrone abuse manifesting as parkinsonism: a case report. Iqbal M, Monaghan T, Redmond J. J Med Case Reports. 2012 Feb 7;6(1):52. [Epub ahead of print] PMID: 22313512 [PubMed - as supplied by publisher]

  • Occurrence and biodegradation of nonylphenol in the environment. Mao Z, Zheng XF, Zhang YQ, Tao XX, Li Y, Wang W. Int J Mol Sci. 2012;13(1):491-505. Epub 2012 Jan 4. PMID: 22312266 [PubMed - in process]

  • Influencing the Symmetry of High-Nuclearity and High-Spin Manganese Oxo-Clusters: Supramolecular Approaches to Manganese-Based Keplerates and Chiral Solids. Zhang L, Clérac R, Heijboer P, Schmitt W. Angew Chem Int Ed Engl. 2012 Feb 6. doi: 10.1002/anie.201107358. [Epub ahead of print] PMID: 22311623 [PubMed - as supplied by publisher]

  • Biodegradation of organic compounds of molasses melanoidin (MM) from biomethanated distillery spent wash (BMDS) during the decolourisation by a potential bacterial consortium. Yadav S, Chandra R. Biodegradation. 2012 Feb 5. [Epub ahead of print] PMID: 22311589 [PubMed - as supplied by publisher]

  • Metals in Fish along the Southeast Coast of India. Thiyagarajan D, Dhaneesh KV, Ajith Kumar TT, Kumaresan S, Balasubramanian T. Bull Environ Contam Toxicol. 2012 Feb 5. [Epub ahead of print] PMID: 22310845 [PubMed - as supplied by publisher]

 

Recent Research & Development for Bromides

  • Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids. Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C. Org Lett. 2010 Jan 5. [Epub ahead of print] PMID: 19689116 [PubMed - as supplied by publisher]

  • Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides. Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Science. 2009 Aug 13. [Epub ahead of print] PMID: 19679769 [PubMed - as supplied by publisher]

  • (2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides. Zhang Q, Wang D, Wang X, Ding K. J Org Chem. 2009 Aug 12. [Epub ahead of print] PMID: 19673481 [PubMed - as supplied by publisher]

  • Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides. Vechorkin O, Barmaz D, Proust V, Hu X. J Am Chem Soc. 2009 Aug 11. [Epub ahead of print] PMID: 19670863 [PubMed - as supplied by publisher]

  • Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia. Huang JM, Dong Y. Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28. PMID: 19662260 [PubMed - in process]

  • Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols. Salvi L, Kim JG, Walsh PJ. J Am Chem Soc. 2009 Aug 4. [Epub ahead of print] PMID: 19653691 [PubMed - as supplied by publisher]

  • Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines. Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J. J Comb Chem. 2009 Jul 31. [Epub ahead of print] PMID: 19645499 [PubMed - as supplied by publisher]

  • Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids. del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N. Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29. PMID: 19641822 [PubMed - in process]

  • Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides. Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639999 [PubMed - as supplied by publisher]

  • Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies. Snelders DJ, van Koten G, Klein Gebbink RJ. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639941 [PubMed - as supplied by publisher]

  • Can One Predict Changes from S(N)1 to S(N)2 Mechanisms? Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H. J Am Chem Soc. 2009 Jul 27. [Epub ahead of print] PMID: 19634906 [PubMed - as supplied by publisher]

  • A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides. Liao Q, Wang Y, Zhang L, Xi C. J Org Chem. 2009 Jul 15. [Epub ahead of print] PMID: 19603753 [PubMed - as supplied by publisher]

  • Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides. Shi L, Chu Y, Knochel P, Mayr H. Org Lett. 2009 Jul 14. [Epub ahead of print] PMID: 19601592 [PubMed - as supplied by publisher]

  • C5-Modified nucleosides exhibiting anticancer activity. Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH. Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21. PMID: 19596579 [PubMed - in process]

  • Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. Vo GD, Hartwig JF. J Am Chem Soc. 2009 Jul 10. [Epub ahead of print] PMID: 19591470 [PubMed - as supplied by publisher]

  • New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes. Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B. Org Lett. 2009 Jul 2. [Epub ahead of print] PMID: 19572730 [PubMed - as supplied by publisher]

  • The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives. Jo Y, Ju J, Choe J, Song KH, Lee S. J Org Chem. 2009 Jul 2. [Epub ahead of print] PMID: 19572571 [PubMed - as supplied by publisher]

  • Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents. Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH. Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8. PMID: 19557114 [PubMed - in process]

  • A facile route to C2-substituted imidazolium ionic liquids. Ennis E, Handy ST. Molecules. 2009 Jun 19;14(6):2235-45. PMID: 19553895 [PubMed - in process]

  • Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines. McCall WS, Comins DL. Org Lett. 2009 Jul 2;11(13):2940-2. PMID: 19552467 [PubMed - indexed for MEDLINE]

     

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