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Molybdenum
Molybdenum information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Molybdenum has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum is a catalyst in the oil refining. It has many other applications, including in catalysts, pigments, corrosion inhibitors and lubricants. It has a very high elastic modulus. Molybdenum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is used in steel alloys to add hardness and raise melting points. It is a component in Hastelloys brand steel. Molybdenum is used in nuclear reactors and aerospace components. Molybdenum is valuable as a catalyst in the refining of petroleum. It is used in high temperature filaments for electronics.

Molybdenum facts, research and properties are

 

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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Molybdenum is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Molybdenum is a Block D, Group 6, Period 5 element. The electronic configuration is [Kr] 4d5 5s1. In its elemental form molybdenum's CAS number is 7439-98-7. The molybdenum atom has a radius of 136.3.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Molybdenum compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Molybdenum was first discovered by Carl Wilhelm in 1778.

French Molybdène German Molybdän Italian Molibdeno Portuguese Molibdênio Spanish Molibdeno Swedish Molybden

Abundance. The following table shows the abundance of molybdenum and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Mo-92
91.906810
14.84
Mo-94
93.905088
9.25
Mo-95
94.905841
15.92
Mo-96
95.904679
16.68
Mo-97
96.906021
9.55
Mo-98
97.905408
24.13
Mo-100
99.907477
9.63

Safety Data. The safety data for molybdenum metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for molybdenum (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
684.32 kJ mol-1
2nd Ionization Energy
1559.21 kJ mol-1
3rd Ionization Energy
2617.67 kJ mol-1

Conductivity. As to molybdenum's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 5.34 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.16. The thermal conductivity of molybdenum is 138 W m-1 K-1.

Thermal Properties. The melting point and boiling point for molybdenum are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
27.6 kJ mol-1
Heat of Vaporization
589.9 kJ mol-1
Heat of Atomization
656.55 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Mo 42 95.94 g.mol -1 1.8 10.2 g.cm-3 at 20 °C 2610 °C 4825°C 200.pm 0.068 nm (+4); 0.06 nm (+6) 684.32 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Molybdenum

  • Atomic-Scale Analysis on the Role of Molybdenum in Iron-Catalyzed Carbon Nanotube Growth. Yoshida H, Shimizu T, Uchiyama T, Kohno H, Homma Y, Takeda S. Nano Lett. 2009 Sep 4. [Epub ahead of print] PMID: 19731921 [PubMed - as supplied by publisher]

  • Plasma Levels of Trace Elements Have an Implication on Interferon Treatment of Children with Chronic Hepatitis B Infection. Balamtekin N, Kurekci AE, Atay A, Kalman S, Okutan V, Gokcay E, Aydin A, Sener K, Safali M, Ozcan O. Biol Trace Elem Res. 2009 Sep 2. [Epub ahead of print] PMID: 19727570 [PubMed - as supplied by publisher]

  • Determination of X-ray mass attenuation coefficients using HPGe detector. Sharanabasappa, Kerur BR, Anilkumar S, Hanumaiah B. Appl Radiat Isot. 2009 Aug 19. [Epub ahead of print] PMID: 19726203 [PubMed - as supplied by publisher]

  • L: -Ribose from L: -arabinose by epimerization and its purification by 3-zone simulated moving bed chromatography. Jeon YJ, Park MB, Kim IH. Bioprocess Biosyst Eng. 2009 Aug 28. [Epub ahead of print] PMID: 19714365 [PubMed - as supplied by publisher]

  • An allelic mutant series of ATM3 reveals its key role in the biogenesis of cytosolic iron-sulfur proteins in Arabidopsis. Bernard DG, Cheng Y, Zhao Y, Balk J. Plant Physiol. 2009 Aug 26. [Epub ahead of print] PMID: 19710232 [PubMed - as supplied by publisher]

  • Macroion clustering in solutions and suspensions: the roles of microions and solvent. Schmitz KS. J Phys Chem B. 2009 Mar 5;113(9):2624-38. PMID: 19708104 [PubMed - in process]

  • Molybdenum(0)-Promoted Carbonylative Cyclization of o-Haloaryl- and beta-Haloalkenylimine Derivatives by Oxidative Addition of a Carbon(sp(2))--Halogen Bond: Preparation of Two Types of gamma-Lactams. Takaya J, Sangu K, Iwasawa N. Angew Chem Int Ed Engl. 2009 Sep 7;48(38):7090-7093. No abstract available. PMID: 19705391 [PubMed - as supplied by publisher]

  • Catalytic epoxidation of a technical mixture of methyl oleate and methyl linoleate in ionic liquids using MoO(O2)2.2QOH (QOH = 8-quinilinol) as catalyst and NaHCO3 as co-catalyst. Cai SF, Wang LS, Fan CL. Molecules. 2009 Aug 10;14(8):2935-46. PMID: 19701136 [PubMed - in process]

  • Isolation and characterization of a new Cu-Fe protein from Desulfovibrio aminophilus DSM12254. Rivas MG, Mota CS, Pauleta SR, Carepo MS, Folgosa F, Andrade SL, Fauque G, Pereira AS, Tavares P, Calvete JJ, Moura I, Moura JJ. J Inorg Biochem. 2009 May 7. [Epub ahead of print] PMID: 19699535 [PubMed - as supplied by publisher]

  • Sequential Construction of One, Two, or Three Dithiolene Ligands from Alkynes and Sulfur in Dinuclear Cyclopentadienyl Molybdenum Complexes. Adams H, Bancroft MN, Morris MJ, Riddiough AE. Inorg Chem. 2009 Aug 21. [Epub ahead of print] PMID: 19697947 [PubMed - as supplied by publisher]

  • Use of a high electron-affinity molybdenum dithiolene complex to p-dope hole-transport layers. Qi Y, Sajoto T, Barlow S, Kim EG, Brédas JL, Marder SR, Kahn A. J Am Chem Soc. 2009 Sep 9;131(35):12530-1. PMID: 19678703 [PubMed - in process]

  • Molybdenum cofactors, enzymes and pathways. Schwarz G, Mendel RR, Ribbe MW. Nature. 2009 Aug 13;460(7257):839-47. PMID: 19675644 [PubMed - in process]

  • Synthesis, characterization and structure of a low coordinate desoxomolybdenum cluster stabilized by a dithione ligand. Perera E, Basu P. Dalton Trans. 2009 Jul 7;(25):5023-8. Epub 2009 May 27. PMID: 19662295 [PubMed - in process]

  • Nucleation and growth mechanism for flame synthesis of MoO2 hollow microchannels with nanometer wall thickness. Merchan-Merchan W, Saveliev AV, Taylor AM. Micron. 2009 Dec;40(8):821-6. Epub 2009 Jul 25. PMID: 19660960 [PubMed - in process]

  • Structures of Mo(x)W(3-x)O(6) (x = 0-3) anion and neutral clusters determined by anion photoelectron spectroscopy and density functional theory calculations. Rothgeb DW, Hossain E, Kuo AT, Troyer JL, Jarrold CC. J Chem Phys. 2009 Jul 28;131(4):044310. PMID: 19655870 [PubMed - in process]

  • Synthesis, electronic and crystal structures, and physical studies of the superconductor Cs(~1)Mo12S14, final step of the condensation of the Mo6L8(i)L6(a) unit. Gougeon P, Salloum D, Cuny J, Le Pollès L, Le Floch M, Gautier R, Potel M. Inorg Chem. 2009 Sep 7;48(17):8337-41. PMID: 19645498 [PubMed - in process]

  • Nutrient composition of plants consumed by black and white ruffed lemurs, Varecia variegata, in the Betampona Natural Reserve, Madagascar. Schmidt DA, Iambana RB, Britt A, Junge RE, Welch CR, Porton IJ, Kerley MS. Zoo Biol. 2009 Jul 30. [Epub ahead of print] PMID: 19645044 [PubMed - as supplied by publisher]

  • Molybdenum supplies and nuclear medicine services. Perkins AC, Vivian G. Nucl Med Commun. 2009 Sep;30(9):657-9. No abstract available. PMID: 19644241 [PubMed - in process]

  • Reactivity of neutral Mo(S2C6H4)3 in aqueous media: an alternative functional model of sulfite oxidase. Pérez Pla F, Cervilla A, Piles M, Llopis E. Inorg Chem. 2009 Sep 7;48(17):8559-68. PMID: 19642629 [PubMed - in process]

  • Molybdenum triamidoamine systems. Reactions involving dihydrogen relevant to catalytic reduction of dinitrogen. Hetterscheid DG, Hanna BS, Schrock RR. Inorg Chem. 2009 Sep 7;48(17):8569-77. PMID: 19639973 [PubMed - in process]

 

 

 

 

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