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Molybdenum
Molybdenum information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Molybdenum has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum is a catalyst in the oil refining. It has many other applications, including in catalysts, pigments, corrosion inhibitors and lubricants. It has a very high elastic modulus. Molybdenum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is used in steel alloys to add hardness and raise melting points. It is a component in Hastelloys brand steel. Molybdenum is used in nuclear reactors and aerospace components. Molybdenum is valuable as a catalyst in the refining of petroleum. It is used in high temperature filaments for electronics.

Molybdenum facts, research and properties are

 

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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Molybdenum is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Molybdenum is a Block D, Group 6, Period 5 element. The electronic configuration is [Kr] 4d5 5s1. In its elemental form molybdenum's CAS number is 7439-98-7. The molybdenum atom has a radius of 136.3.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Molybdenum compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Molybdenum was first discovered by Carl Wilhelm in 1778.

French Molybdène German Molybdän Italian Molibdeno Portuguese Molibdênio Spanish Molibdeno Swedish Molybden

Abundance. The following table shows the abundance of molybdenum and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Mo-92
91.906810
14.84
Mo-94
93.905088
9.25
Mo-95
94.905841
15.92
Mo-96
95.904679
16.68
Mo-97
96.906021
9.55
Mo-98
97.905408
24.13
Mo-100
99.907477
9.63

Safety Data. The safety data for molybdenum metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for molybdenum (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
684.32 kJ mol-1
2nd Ionization Energy
1559.21 kJ mol-1
3rd Ionization Energy
2617.67 kJ mol-1

Conductivity. As to molybdenum's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 5.34 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.16. The thermal conductivity of molybdenum is 138 W m-1 K-1.

Thermal Properties. The melting point and boiling point for molybdenum are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
27.6 kJ mol-1
Heat of Vaporization
589.9 kJ mol-1
Heat of Atomization
656.55 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Mo 42 95.94 g.mol -1 1.8 10.2 g.cm-3 at 20 °C 2610 °C 4825°C 200.pm 0.068 nm (+4); 0.06 nm (+6) 684.32 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Molybdenum

  • Immobilization of monomeric organometallic molybdenum oxo and carbonyl complexes and their application in epoxidation reactions. Dalton Trans. 2008 May 7;(17):2221-7. Epub 2008 Feb 27.

  • Two closely related pathways of nicotine catabolism in Arthrobacter nicotinovorans and Nocardioides sp. strain JS614. Arch Microbiol. 2008 May;189(5):511-7. Epub 2007 Dec 11.

  • Screening the phytoremediation potential of desert broom (Baccharis sarothroides Gray) growing on mine tailings in Arizona, USA. Environ Pollut. 2008 May;153(2):362-8. Epub 2007 Oct 25.

  • Cloud-point preconcentration and spectrophotometric determination of trace amounts of molybdenum(VI) in steels and water samples. J Hazard Mater. 2008 May 1;153(1-2):695-700. Epub 2007 Sep 6.

  • Experimental and theoretical study of a truly functional biomimetic molybdenum oxotransferase analogue system. J Inorg Biochem. 2008 May;102(5-6):1199-211. Epub 2008 Jan 31.

  • A widespread riboswitch candidate that controls bacterial genes involved in molybdenum cofactor and tungsten cofactor metabolism. Mol Microbiol. 2008 May;68(4):918-32. Epub 2008 Mar 19.

  • A critical role for ureides in dark and senescence-induced purine remobilization is unmasked in the Atxdh1 Arabidopsis mutant. Plant J. 2008 May;54(3):496-509. Epub 2008 Feb 7.

  • Molybdate transport through the plant sulfate transporter SHST1. FEBS Lett. 2008 Apr 30;582(10):1508-13. Epub 2008 Apr 7.

  • Extended X-ray absorption fine structure and nuclear resonance vibrational spectroscopy reveal that NifB-co, a FeMo-co precursor, comprises a 6Fe core with an interstitial light atom. J Am Chem Soc. 2008 Apr 30;130(17):5673-80. Epub 2008 Apr 2.

  • Inhibitors of the Molybdenum Cofactor Containing 4-Hydroxybenzoyl-CoA Reductase. Biochemistry. 2008 Apr 29;47(17):4964-72. Epub 2008 Apr 5.

  • Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science. Chem Commun (Camb). 2008 Apr 28;(16):1837-52. Epub 2008 Jan 24.

  • Biosynthesis of the Iron-Molybdenum Cofactor of Nitrogenase. Annu Rev Microbiol. 2008 Apr 22; [Epub ahead of print]

  • Use of ionic liquids (ILs) for the IL-anion size-dependent formation of Cr, Mo and W nanoparticles from metal carbonyl M(CO)(6) precursors. Chem Commun (Camb). 2008 Apr 21;(15):1789-91. Epub 2008 Mar 14.

  • Unsaturated dinickel-molybdenum clusters with N-heterocyclic carbene ligands. Dalton Trans. 2008 Apr 21;(15):1973-5. Epub 2008 Feb 14.

  • ATP-driven Reduction by Dark-operative Protochlorophyllide Oxidoreductase from Chlorobium tepidum Mechanistically Resembles Nitrogenase Catalysis. J Biol Chem. 2008 Apr 18;283(16):10559-67. Epub 2008 Feb 5.

  • Redox behavior of molybdenum and tungsten in phosphate glasses. J Phys Chem B. 2008 Apr 17;112(15):4481-7. Epub 2008 Mar 22.

  • Self-assembly of polymer and molybdenum oxide into lamellar hybrid materials. J Colloid Interface Sci. 2008 Apr 15;320(2):445-51. Epub 2008 Jan 13.

  • Bioleaching of spent hydro-processing catalyst using acidophilic bacteria and its kinetics aspect. J Hazard Mater. 2008 Apr 15;152(3):1082-91. Epub 2007 Jul 31.

  • Splice-specific functions of gephyrin in molybdenum cofactor biosynthesis. J Biol Chem. 2008 Apr 14; [Epub ahead of print]

  • Binding of Sulfurated Molybdenum Cofactor to the C-terminal Domain of ABA3 from Arabidopsis thaliana Provides Insight into the Mechanism of Molybdenum Cofactor Sulfuration. J Biol Chem. 2008 Apr 11;283(15):9642-50. Epub 2008 Feb 7.

 

 

 

 

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