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Tungsten
Tungsten information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Tungsten has the highest melting point of all the metallic elements and because of this has its first significant commercial application as the filament in incandescent light bulbs and fluorescent light bulbs. Tungsten is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Later it was used in the first television tubes. The first imaging equipment involved X-ray bombardment of a tungsten target. Tungsten expands at nearly the same rate as borosilicate glass and is used to make metal to glass seals. It is the primary metal in heating elements for electric furnaces and in any components where high pressure/temperature environments are expected, such as aerospace and engine systems. Tungsten is alloyed in steel to improve its ability to operate in high temperatures. Tungsten carbide is used in drill bits and cutting tools because it is one of the hardest commercial materials.. Tungsten forms compounds with calcium and magnesium that have phosphorescent properties and are used in the glass coatings for fluorescent light bulbs. Other tungsten chemical compounds are used in catalysts and lubricants.

Tungsten facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Tungsten is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Tungsten is a Block D, Group 6, Period 6 element. The electronic configuration is [Xe] 4f14 5d4 6s2. In its elemental form tungsten's CAS number is 7440-33-7. The tungsten atom has a radius of 137.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Tungsten compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Tungsten was first discovered by Fausto and Juan Jose de Elhuyar in 1783.

French tungstène German Wolfram Italian tungsteno Portuguese Tungstênio Spanish wolframio Swedish Volfram

Abundance. The following table shows the abundance of tungsten and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
W-180
179.946706
0.13
W-182
181.948206
26.3
W-183
182.950224
14.3
W-184
183.950933
30.67
W-186
185.954362
28.6

Safety Data. The safety data for tungsten metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for tungsten (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
758.77 kJ mol-1
2nd Ionization Energy
- kJ mol-1
3rd Ionization Energy
- kJ mol-1

Conductivity. As to tungsten's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ēC is 5.4 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.7. The thermal conductivity of tungsten is 174 W m-1 K-1.

Thermal Properties. The melting point and boiling point for tungsten are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
35.2 kJ mol-1
Heat of Vaporization
824.2 kJ mol-1
Heat of Atomization
848.1 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
W 74 183.85 g.mol -1 1.7 19.3 g.cm-3 at 20 °C 3410 °C 5660 °C 200.pm 0.068 nm (+4) ; 0.067 nm (+6) 758.77 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Tungsten

  • Simultaneous determination of Cd and Fe in grain products using direct solid sampling and high-resolution continuum source electrothermal atomic absorption spectrometry. Dos Santos LM, Araujo RG, Welz B, Jacob SD, Vale MG, Becker-Ross H. Talanta. 2009 Apr 30;78(2):577-583. Epub 2008 Dec 11. PMID: 19203627 [PubMed - as supplied by publisher]

  • Electrical characterization of N- and P-doped hole and electron only organic devices. Park TJ, Kim SY, Jeon WS, Park JJ, Pode R, Jang J, Kwon JH. J Nanosci Nanotechnol. 2008 Oct;8(10):5606-9. PMID: 19198509 [PubMed - in process]

  • Nanostructures of crystalline molybdenum trioxide grown by condensation in a carrier gas. Diaz-Droguett DE, Fuenzalida VM, Solorzano G. J Nanosci Nanotechnol. 2008 Nov;8(11):5977-84. PMID: 19198335 [PubMed - in process]

  • Growth of carbon nanotubes on fully processed silicon-on-insulator CMOS substrates. Haque MS, Ali SZ, Guha PK, Oei SP, Park J, Maeng S, Teo KB, Udrea F, Milne WI. J Nanosci Nanotechnol. 2008 Nov;8(11):5667-72. PMID: 19198286 [PubMed - in process]

  • Effect of fabrication process parameters on the apex-radius of STM tungsten nanotip. Tahmasebipour G, Hojjat Y, Ahmadi V, Abdullah A. Scanning. 2009 Feb 3. [Epub ahead of print] PMID: 19191264 [PubMed - as supplied by publisher]

  • Simulation studies on the effect of absorbers on dose distribution in rotational radiotherapy. Ivanova T, Bliznakova K, Malatara G, Kardamakis D, Kolitsi Z, Pallikarakis N. Phys Med. 2009 Jan 29. [Epub ahead of print] PMID: 19186088 [PubMed - as supplied by publisher]

  • Divergent Electronic Structures of Isoelectronic Metalloclusters: Tungsten(II) Halides and Rhenium(III) Chalcogenide-Halides. Gray TG. Chemistry. 2009 Jan 29. [Epub ahead of print] PMID: 19180591 [PubMed - as supplied by publisher]

  • Thermal stability of a Co/Cu giant magnetoresistance (GMR) multilayer system. Vovk V, Schmitz G. Ultramicroscopy. 2008 Dec 24. [Epub ahead of print] PMID: 19179012 [PubMed - as supplied by publisher]

  • A computational study on molecular adsorption states of nitrogen on a tungsten tetramer. Yamaguchi W, Murakami J. Phys Chem Chem Phys. 2009 Feb 14;11(6):943-9. Epub 2008 Dec 2. PMID: 19177212 [PubMed - in process]

  • Asymmetric C2-C3 Cyclopentannulation of the Indole Ring. Barluenga J, Tudela E, Ballesteros A, Toma´s M. J Am Chem Soc. 2009 Jan 28. [Epub ahead of print] PMID: 19175310 [PubMed - as supplied by publisher]

  • Quantification of breast density with dual energy mammography: a simulation study. Ducote JL, Molloi S. Med Phys. 2008 Dec;35(12):5411-8. PMID: 19175100 [PubMed - in process]

  • Mean glandular dose estimation using MCNPX for a digital breast tomosynthesis system with tungsten/aluminum and tungsten/aluminum+silver x-ray anode-filter combinations. Ma AK, Darambara DG, Stewart A, Gunn S, Bullard E. Med Phys. 2008 Dec;35(12):5278-89. PMID: 19175087 [PubMed - in process]

  • Image artifacts in digital breast tomosynthesis: investigation of the effects of system geometry and reconstruction parameters using a linear system approach. Hu YH, Zhao B, Zhao W. Med Phys. 2008 Dec;35(12):5242-52. PMID: 19175083 [PubMed - in process]

  • Reactive diffusion under Laplace tension. Ene C, Nowak C, Oberdorfer C, Schmitz G. Ultramicroscopy. 2008 Dec 7. [Epub ahead of print] PMID: 19171431 [PubMed - as supplied by publisher]

  • Preliminary measurement of intraoperative sympathetic nerve activity using microneurography and laser Doppler flowmetry during surgical resection of suprasellar tumors. Kurimoto F, Saito K, Watanabe T, Nagatani T, Nishiwaki K, Wakabayashi T, Iwase S. Neurol Med Chir (Tokyo). 2009 Jan;49(1):13-21. PMID: 19168997 [PubMed - in process]

  • Field ionization of helium in a supersonic beam: Kinetic energy of neutral atoms and probability of their field ionization. Holst B, Piskur J, Kostrobiy PP, Markovych BM, Suchorski Y. Ultramicroscopy. 2008 Dec 7. [Epub ahead of print] PMID: 19167823 [PubMed - as supplied by publisher]

  • Structural Tungsten-Imido Chemistry: The Gas-Phase Structure of W(NBu(t))(2)(NHBu(t))(2) and the Solid-State Structures of Novel Heterobimetallic W/N/M (M = Rh, Pd, Zn) Species. Choujaa H, Cosham SD, Johnson AL, Kafka GR, Mahon MF, Masters SL, Molloy KC, Rankin DW, Robertson HE, Wann DA. Inorg Chem. 2009 Jan 23. [Epub ahead of print] PMID: 19166314 [PubMed - as supplied by publisher]

  • Flexible polymer substrate and tungsten microelectrode array for an implantable neural recording system. Patrick E, Sankar V, Rowe W, Yen SF, Sanchez JC, Nishida T. Conf Proc IEEE Eng Med Biol Soc. 2008;1:3158-61. PMID: 19163377 [PubMed - as supplied by publisher]

  • Comparison of tungsten coil electrothermal vaporization and thermospray sample introduction methods for flame furnace atomic absorption spectrometry. Wu P, Zhang Y, Liu R, Lv Y, Hou X. Talanta. 2009 Mar 15;77(5):1778-82. Epub 2008 Oct 19. PMID: 19159798 [PubMed - in process]

  • Evaluation of Lithium Ion Insertion Reactivity via Electrochromic Diffraction-Based Imaging. Kondrachova LV, May RA, Cone CW, Vanden Bout DA, Stevenson KJ. Langmuir. 2009 Jan 20. [Epub ahead of print] PMID: 19154121 [PubMed - as supplied by publisher]

 

 

 

 

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