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Rhodium
Rhodium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density. It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Rhodium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Rhodium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Rhodium is a Block D, Group 9, Period 5 element. The electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Rhodium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Rhodium was first discovered by William Wollaston in 1803.

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Abundance. The following table shows the abundance of rhodium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Rh-103
102.905504
100

Safety Data. The safety data for rhodium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for rhodium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
719.68 kJ mol-1
2nd Ionization Energy
1744.47 kJ mol-1
3rd Ionization Energy
2996.86 kJ mol-1

Conductivity. As to rhodium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ŗC is 4.51 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.28. The thermal conductivity of rhodium is 150 W m-1 K-1.

Thermal Properties. The melting point and boiling point for rhodium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
21.55 kJ mol-1
Heat of Vaporization
494.34 kJ mol-1
Heat of Atomization
555.59 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Rh 45 102.91 g.mol -1 2.2 12.4 g.cm-3 at 20 °C 1970 °C 3727 °C 200.pm unknown 719.68 kJ.mol-1

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Recent Research & Development for Rhodium

  • Water-soluble metal nanoparticles with PEG-tagged 15-membered azamacrocycles as stabilizers. Mejķas N, Serra-Muns A, Pleixats R, Shafir A, Tristany M. Dalton Trans. 2009 Oct 7;(37):7748-55. Epub 2009 Jul 30. PMID: 19759949 [PubMed - in process]

  • Evidence for heterogeneous Sonogashira coupling of phenylacetylene and iodobenzene catalyzed by well defined rhodium nanoparticles. Kanuru VK, Humphrey SM, Kyffin JM, Jefferson DA, Burton JW, Armbrüster M, Lambert RM. Dalton Trans. 2009 Oct 7;(37):7602-5. Epub 2009 Jul 27. PMID: 19759929 [PubMed - in process]

  • Total synthesis of alkaloid (+/-)-g. B. 13 using a rh(i)-catalyzed ketone hydroarylation and late-stage pyridine reduction. Larson KK, Sarpong R. J Am Chem Soc. 2009 Sep 23;131(37):13244-5. PMID: 19754185 [PubMed - in process]

  • Thermodynamic Studies and Hydride Transfer Reactions from a Rhodium Complex to BX(3) Compounds. Mock MT, Potter RG, Camaioni DM, Li J, Dougherty WG, Kassel WS, Twamley B, Dubois DL. J Am Chem Soc. 2009 Sep 15. [Epub ahead of print] PMID: 19754124 [PubMed - as supplied by publisher]

  • Preparation of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation and Hydrozincation of Ynamides. Gourdet B, Rudkin ME, Watts CA, Lam HW. J Org Chem. 2009 Sep 15. [Epub ahead of print] PMID: 19754108 [PubMed - as supplied by publisher]

  • Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Amino Acid Derived Rhodium Complexes: On the Origin of Enantioselectivity and Enantioswitchability. Ahlford K, Ekström J, Zaitsev AB, Ryberg P, Eriksson L, Adolfsson H. Chemistry. 2009 Sep 11. [Epub ahead of print] PMID: 19750526 [PubMed - as supplied by publisher]

  • A method for low volume and low Se concentration samples and application to paired cerebrospinal fluid and serum samples. Michalke B, Grill P, Berthele A. J Trace Elem Med Biol. 2009;23(4):243-50. Epub 2009 Aug 6. PMID: 19747619 [PubMed - in process]

  • A role for photoreceptors in retinal oedema and angiogenesis: an additional explanation for laser treatment? Foulds WS, Kaur C, Luu CD, Kek WK. Eye. 2009 Sep 11. [Epub ahead of print] PMID: 19745837 [PubMed - as supplied by publisher]

  • Thermodynamic trends in carbon-hydrogen bond activation in nitriles and chloroalkanes at rhodium. Evans ME, Li T, Vetter AJ, Rieth RD, Jones WD. J Org Chem. 2009 Sep 18;74(18):6907-14. PMID: 19743881 [PubMed - in process]

  • A fast ultrasound-assisted extraction procedure for trace elements determination in hair samples by ICP-MS for forensic analysis. Batista BL, Rodrigues JL, de Oliveira Souza VC, Barbosa F Jr. Forensic Sci Int. 2009 Sep 7. [Epub ahead of print] PMID: 19740615 [PubMed - as supplied by publisher]

  • Steric Tuning of the Amidomonophosphane-Rhodium(I) Catalyst in Asymmetric Addition of Arylboroxines to N-Phosphinoyl Aldimines. Hao X, Kuriyama M, Chen Q, Yamamoto Y, Yamada KI, Tomioka K. Org Lett. 2009 Sep 9. [Epub ahead of print] PMID: 19739616 [PubMed - as supplied by publisher]

  • High-throughput metal screening in pharmaceutical samples by ICP-MS with automated flow injection using a modified HPLC configuration. Tu Q, Wang T, Welch CJ. J Pharm Biomed Anal. 2009 Aug 15. [Epub ahead of print] PMID: 19733025 [PubMed - as supplied by publisher]

  • Rhodium-Catalyzed Ring-Opening Reactions of a 3-Aza-2-oxabicyclo[2.2.1]hept-5-ene with Arylboronic Acids. Machin BP, Ballantine M, Mandel J, Blanchard N, Tam W. J Org Chem. 2009 Sep 4. [Epub ahead of print] PMID: 19731959 [PubMed - as supplied by publisher]

  • Application of a Supramolecular-Ligand Library for the Automated Search for Catalysts for the Asymmetric Hydrogenation of Industrially Relevant Substrates. Meeuwissen J, Kuil M, van der Burg AM, Sandee AJ, Reek JN. Chemistry. 2009 Sep 3. [Epub ahead of print] PMID: 19731274 [PubMed - as supplied by publisher]

  • Sodium Tetraarylborates as Effective Nucleophiles in Rhodium/Diene-Catalyzed 1,4-Addition to beta,beta-Disubstituted alpha,beta-Unsaturated Ketones: Catalytic Asymmetric Construction of Quaternary Carbon Stereocenters. Shintani R, Tsutsumi Y, Nagaosa M, Nishimura T, Hayashi T. J Am Chem Soc. 2009 Sep 3. [Epub ahead of print] PMID: 19728707 [PubMed - as supplied by publisher]

  • Chiral amidophosphane-rhodium(i)-catalyzed asymmetric conjugate arylation of acyclic enones with arylboronic acids. Chen Q, Kuriyama M, Hao X, Soeta T, Yamamoto Y, Yamada K, Tomioka K. Chem Pharm Bull (Tokyo). 2009 Sep;57(9):1024-7. PMID: 19721271 [PubMed - in process]

  • Room-temperature rhodium-catalyzed asymmetric 1,4-addition of potassium trifluoro(organo)borates. Gendrineau T, Genet JP, Darses S. Org Lett. 2009 Aug 6;11(15):3486-9. PMID: 19719192 [PubMed - in process]

  • An Expedient Route to a Potent Gastrin/CCK-B Receptor Antagonist (+)-AG-041R. Sato S, Shibuya M, Kanoh N, Iwabuchi Y. J Org Chem. 2009 Aug 31. [Epub ahead of print] PMID: 19719158 [PubMed - as supplied by publisher]

  • Rhodium-catalyzed cross-coupling of organoboron compounds with vinyl acetate. Yu JY, Kuwano R. Angew Chem Int Ed Engl. 2009;48(39):7217-20. No abstract available. PMID: 19714694 [PubMed - in process]

  • Enantioselective rhodium-catalyzed [4+2+2] cycloaddition of dienyl isocyanates for the synthesis of bicyclic azocine rings. Yu RT, Friedman RK, Rovis T. J Am Chem Soc. 2009 Sep 23;131(37):13250-1. PMID: 19711950 [PubMed - in process]

 

 

 

 

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