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Rhodium
Rhodium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density. It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Rhodium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Rhodium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Rhodium is a Block D, Group 9, Period 5 element. The electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Rhodium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Rhodium was first discovered by William Wollaston in 1803.

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Abundance. The following table shows the abundance of rhodium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Rh-103
102.905504
100

Safety Data. The safety data for rhodium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for rhodium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
719.68 kJ mol-1
2nd Ionization Energy
1744.47 kJ mol-1
3rd Ionization Energy
2996.86 kJ mol-1

Conductivity. As to rhodium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 șC is 4.51 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.28. The thermal conductivity of rhodium is 150 W m-1 K-1.

Thermal Properties. The melting point and boiling point for rhodium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
21.55 kJ mol-1
Heat of Vaporization
494.34 kJ mol-1
Heat of Atomization
555.59 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Rh 45 102.91 g.mol -1 2.2 12.4 g.cm-3 at 20 °C 1970 °C 3727 °C 200.pm unknown 719.68 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Rhodium

  • Approaches to trinuclear half-sandwich carbene complexes containing 1,2-dicarba-closo-dodecaboranes. Dalton Trans. 2008 May 21;(19):2615-9. Epub 2008 Mar 26.

  • Modelling proposed intermediates in the hydrocarbonylation of alkenes catalysed by rhodium complexes of PBu(i)(3) and PPr(i)(3). Dalton Trans. 2008 May 14;(18):2389-94. Epub 2008 Mar 17.

  • Cobalt-rhodium heterobimetallic nanoparticle-catalyzed reactions. Dalton Trans. 2008 May 14;(18):2369-78. Epub 2008 Mar 18.

  • Access to enantioenriched alpha-amino esters via rhodium-catalyzed 1,4-addition/enantioselective protonation. J Am Chem Soc. 2008 May 14;130(19):6159-69. Epub 2008 Apr 9.

  • Unsaturated Aldehydes as Alkene Equivalents in the Diels-Alder Reaction. Chemistry. 2008 May 9. [Epub ahead of print]

  • Efficient Rhodium-Catalyzed Installation of Unsaturated Ester Functions onto Porphyrins: Site-Specific Heck-Type Addition versus Conjugate Addition. Chemistry. 2008 May 9;14(14):4256-4262.

  • Parahydrogen induced polarization of barbituric acid derivatives: (1)H hyperpolarization studies. Magn Reson Chem. 2008 May 9. [Epub ahead of print]

  • Rhodium(I)-Catalyzed Cycloisomerizations of Bicyclobutanes. J Am Chem Soc. 2008 May 8. [Epub ahead of print] No abstract available.

  • Geometries and stabilities of the carbon clusters with the rhodium impurity: a computational investigation. J Phys Chem A. 2008 May 8;112(18):4375-81. Epub 2008 Apr 8.

  • Easily Accessible C(2)-Symmetric Chiral Bicyclo[3.3.0] Dienes as Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition. Chem Asian J. 2008 May 7. [Epub ahead of print]

  • Rhodium-Catalyzed Asymmetric Addition of Terminal Alkynes to Diarylphosphinylallenes. Chem Asian J. 2008 May 7. [Epub ahead of print]

  • Highly selective synthesis of catalytically active monodisperse rhodium nanocubes. J Am Chem Soc. 2008 May 7;130(18):5868-9. Epub 2008 Apr 10. No abstract available.

  • Rhodium-catalyzed oxidative coupling between salicylaldehydes and internal alkynes with C-H bond cleavage to produce 2,3-disubstituted chromones. Chem Asian J. 2008 May 5;3(5):881-6.

  • Rhodium-Catalyzed Cyclization Reaction of 1,6-Enynes with Arylboronic Acids through beta-Hydride Elimination/Hydrorhodation Sequence. Chem Asian J. 2008 May 2. [Epub ahead of print]

  • Toward multistation rotaxanes using metalloporphyrin coordination templating. J Org Chem. 2008 May 2;73(9):3336-50. Epub 2008 Apr 8.

  • Measurement of excitation functions of helion-induced reactions on enriched Ru targets for production of medically important (103)Pd and (101m)Rh and some other radionuclides. Appl Radiat Isot. 2008 May;66(5):653-67. Epub 2007 Dec 5.

  • Rhodium-Catalyzed Borylative Cyclization of 2-Alkynylaryl Isocyanates with Bis(pinacolato)diboron. Org Lett. 2008 May 1;10(9):1743-5. Epub 2008 Apr 11.

  • Rhodium-Catalyzed Anti Selective Cross-Addition of Bis(trimethylsilyl)acetylene to Diarylacetylenes via Carbon-Silicon Bond Cleavage. Org Lett. 2008 May 1;10(9):1751-4. Epub 2008 Apr 9.

  • Supramolecular Bidentate Ligands by Metal-Directed in situ Formation of Antiparallel beta-Sheet Structures and Application in Asymmetric Catalysis. Chemistry. 2008 Apr 30;14(15):4488-4502. [Epub ahead of print]

  • The mechanism of the rhodium(I)-catalyzed [2 + 2 + 1] carbocyclization reaction of dienes and CO: a computational study. J Am Chem Soc. 2008 Apr 30;130(17):5821-30. Epub 2008 Apr 2.

 

 

 

 

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