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Ruthenium
Ruthenium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Ruthenium is member of the platinum group of metals. It is one of the most effective hardeners for platinum and palladium , and is alloyed with these metals to make electrical contacts for severe wear resistanant electronics and laboratory equipment. The corrosion resistance of titanium is improved a hundredfold by addition of 0.1% ruthenium. It is also a versatile catalyst. Hydrogen sulfide can be split catalytically by light using an aqueous suspension of cadmium sulfide particles loaded with ruthenium dioxide. It is also believed to have pharmacological applications. Ruthenium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Ruthenium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Ruthenium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Ruthenium is a Block D, Group 8, Period 5 element. The electronic configuration is [Kr] 4d7 5s1. In its elemental form ruthenium's CAS number is 7440-18-8. The ruthenium atom has a radius of 132.5.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Ruthenium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Ruthenium was first discovered by Karl Klaus in 1844.

Abundance. The following table shows

French ruthénium German Ruthenium Italian rutenio Portuguese Rutênio Spanish rutenio Swedish Rutenium

the abundance of ruthenium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Ru-96
95.907598
5.52
Ru-98
97.905287
1.88
Ru-99
98.905939
12.7
Ru-100
99.904220
12.6
Ru-101
100.905582
17.0
Ru-102
101.904350
31.6
Ru-104
103.905430
18.7

Safety Data. The safety data for ruthenium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for ruthenium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
710.19 kJ mol-1
2nd Ionization Energy
1617.11 kJ mol-1
3rd Ionization Energy
2746.96 kJ mol-1

Conductivity. As to ruthenium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 șC is 7.6 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.2. The thermal conductivity of ruthenium is 117 W m-1 K-1.

Thermal Properties. The melting point and boiling point for ruthenium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
23.7 kJ mol-1
Heat of Vaporization
567 kJ mol-1
Heat of Atomization
641.031 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Ru 44 101.1 g.mol -1 2.2 12.2 g.cm-3 at 20 °C 2250 °C 4150 °C 200.pm unknown 710.19 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Ruthenium

  • Novel substituted 1,4-anthracenediones with antitumor activity directly induce permeability transition in isolated mitochondria. Int J Oncol. 2007 Nov;31(5):1231-41.

  • Charge Separation in a Ruthenium-Quencher Conjugate Bound to DNA. Inorg Chem. 2007 Oct 2; [Epub ahead of print]

  • Phosphine-Substituted Dithiolene Complexes as Ligands: Communication between Ruthenium(II) Centers Through a Dimolybdenum Bis(dithiolene) Core. Inorg Chem. 2007 Oct 2; [Epub ahead of print]

  • Characteristics of electrolysis, ozonation, and their combination process on treatment of municipal wastewater. Water Environ Res. 2007 Sep;79(9):1033-42.

  • Transition metal vinylidene complexes as supramolecular building blocks: nucleobase-mediated self-assembly of crystals with hexagonal symmetry. Dalton Trans. 2007 Oct 21;(39):4427-38. Epub 2007 Aug 29.

  • Synthesis of Spirocyclic C-Arylglycosides and -Ribosides by Ruthenium-Catalyzed Cycloaddition. Chem Asian J. 2007 Sep 28; [Epub ahead of print]

  • A hybrid FIA/HPLC system incorporating monolithic column chromatography. Anal Chim Acta. 2007 Sep 26;600(1-2):136-41. Epub 2007 Mar 25.

  • Sequential injection analysis (SIA)-chemiluminescence determination of indomethacin using tris[(2,2'-bipyridyl)]ruthenium(III) as reagent and its application to semisolid pharmaceutical dosage forms. Anal Chim Acta. 2007 Sep 26;600(1-2):114-21. Epub 2007 Jan 26.

  • Permanent electric dipole moment of molybdenum carbide. J Chem Phys. 2007 Sep 28;127(12):124302.

  • Hyperbranched Macromolecules via Olefin Metathesis. J Am Chem Soc. 2007 Sep 29; [Epub ahead of print]

  • Direct Imaging of Hexaamine-Ruthenium(III) in Domain Boundaries in Monolayers of Single-Stranded DNA.
    Langmuir. 2007 Jan 30;23(3):1410-3.

  • Differential Ionic Permeation of DNA-Modified Electrodes.
    J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2007 Jan 25;111(3):663-8.

  • Two-Photon Absorption Properties of Iron(II) and Ruthenium(II) Trischelate Complexes of 2,2':4,4' ':4',4' ''-Quaterpyridinium Ligands.
    J Phys Chem A Mol Spectrosc Kinet Environ Gen Theory. 2007 Jan 25;111(3):472-478.

  • Ruthenium-Lewis Acid Catalyzed Asymmetric Diels-Alder Reactions between Dienes and alpha,beta-Unsaturated Ketones.
    Chemistry. 2007 Jan 17; [Epub ahead of print]

  • Tris(2,2'-bipyridyl)ruthenium(ii) chemiluminescence enhanced by silver nanoparticles.
    Chem Commun (Camb). 2007 Jan 28;(4):395-7. Epub 2006 Oct 31.

  • [Retinal angiomatosis : Ocular manifestation of von Hippel-Lindau disease.]
    Ophthalmologe. 2007 Jan 12; [Epub ahead of print] German.

  • Asymmetric Hydrogenation of alpha-Chloro Aromatic Ketones Catalyzed by eta(6)-Arene/TsDPEN-Ruthenium(II) Complexes.
    Org Lett. 2007 Jan 18;9(2):255-257.

  • Quantum chemical study of the mechanism of ethylene elimination in silylative coupling of olefins.
    J Mol Model. 2007 Jan 10; [Epub ahead of print]

  • High Energy and Quantum Efficiency in Photoinduced Charge Separation.
    J Am Chem Soc. 2007 Jan 17;129(2):313-320.

  • Chemoselective Hydrogenation of Imides Catalyzed by Cp*Ru(PN) Complexes and Its Application to the Asymmetric Synthesis of Paroxetine.
    J Am Chem Soc. 2007 Jan 17;129(2):290-1.

 

 

 

 

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