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Ruthenium
Ruthenium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Ruthenium is member of the platinum group of metals. It is one of the most effective hardeners for platinum and palladium , and is alloyed with these metals to make electrical contacts for severe wear resistanant electronics and laboratory equipment. The corrosion resistance of titanium is improved a hundredfold by addition of 0.1% ruthenium. It is also a versatile catalyst. Hydrogen sulfide can be split catalytically by light using an aqueous suspension of cadmium sulfide particles loaded with ruthenium dioxide. It is also believed to have pharmacological applications. Ruthenium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Ruthenium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Ruthenium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Ruthenium is a Block D, Group 8, Period 5 element. The electronic configuration is [Kr] 4d7 5s1. In its elemental form ruthenium's CAS number is 7440-18-8. The ruthenium atom has a radius of 132.5.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Ruthenium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Ruthenium was first discovered by Karl Klaus in 1844.

Abundance. The following table shows

French ruthénium German Ruthenium Italian rutenio Portuguese Rutênio Spanish rutenio Swedish Rutenium

the abundance of ruthenium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Ru-96
95.907598
5.52
Ru-98
97.905287
1.88
Ru-99
98.905939
12.7
Ru-100
99.904220
12.6
Ru-101
100.905582
17.0
Ru-102
101.904350
31.6
Ru-104
103.905430
18.7

Safety Data. The safety data for ruthenium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for ruthenium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
710.19 kJ mol-1
2nd Ionization Energy
1617.11 kJ mol-1
3rd Ionization Energy
2746.96 kJ mol-1

Conductivity. As to ruthenium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 şC is 7.6 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 2.2. The thermal conductivity of ruthenium is 117 W m-1 K-1.

Thermal Properties. The melting point and boiling point for ruthenium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
23.7 kJ mol-1
Heat of Vaporization
567 kJ mol-1
Heat of Atomization
641.031 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Ru 44 101.1 g.mol -1 2.2 12.2 g.cm-3 at 20 °C 2250 °C 4150 °C 200.pm unknown 710.19 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Ruthenium

  • Enantioselective Synthesis of 5-epi-Citreoviral Using Ruthenium-Catalyzed Asymmetric Ring-Closing Metathesis. Funk TW. Org Lett. 2009 Sep 28. [Epub ahead of print] PMID: 19785443 [PubMed - as supplied by publisher]

  • Catalytic Direct Arylations in Polyethylene Glycol (PEG): Recyclable Palladium(0) Catalyst for C-H Bond Cleavages in the Presence of Air. Ackermann L, Vicente R. Org Lett. 2009 Sep 28. [Epub ahead of print] PMID: 19785433 [PubMed - as supplied by publisher]

  • Olefin Cyclopropanation by a Sequential Atom-Transfer Radical Addition and Dechlorination in the Presence of a Ruthenium Catalyst. Thommes K, Kiefer G, Scopelliti R, Severin K. Angew Chem Int Ed Engl. 2009 Sep 25. [Epub ahead of print] No abstract available. PMID: 19784992 [PubMed - as supplied by publisher]

  • Ruthenium(III) chloride catalyzed acylation of alcohols, phenols, and thiols in room temperature ionic liquids. Xi Z, Hao W, Wang P, Cai M. Molecules. 2009 Sep 10;14(9):3528-37. PMID: 19783941 [PubMed - in process]

  • Effect of ruthenium complexation on trypanocidal activity of 5-nitrofuryl containing thiosemicarbazones. Pagano M, Demoro B, Toloza J, Boiani L, González M, Cerecetto H, Olea-Azar C, Norambuena E, Gambino D, Otero L. Eur J Med Chem. 2009 Aug 29. [Epub ahead of print] PMID: 19783078 [PubMed - as supplied by publisher]

  • Controlled compaction with ruthenium-catalyzed photochemical cross-linking of fibrin-based engineered connective tissue. Syedain ZH, Bjork J, Sando L, Tranquillo RT. Biomaterials. 2009 Sep 24. [Epub ahead of print] PMID: 19782397 [PubMed - as supplied by publisher]

  • Ruthenium(II) Arene Anticancer Complexes with Redox-Active Diamine Ligands. Bugarcic T, Habtemariam A, Deeth RJ, Fabbiani FP, Parsons S, Sadler PJ. Inorg Chem. 2009 Oct 5;48(19):9444-53. PMID: 19780621 [PubMed - in process]

  • Organo-Ruthenium Supported Heteropolytungstates: Synthesis, Structure, Electrochemistry, and Oxidation Catalysis. Bi LH, Al-Kadamany G, Chubarova EV, Dickman MH, Chen L, Gopala DS, Richards RM, Keita B, Nadjo L, Jaensch H, Mathys G, Kortz U. Inorg Chem. 2009 Sep 25. [Epub ahead of print] PMID: 19780533 [PubMed - as supplied by publisher]

  • Study of a new chiral selector: Sodium arsenyl-(l)-(+) tartrate for capillary electrophoresis. Tong MY, Payagala T, Perera S, Macdonnell FM, Armstrong DW. J Chromatogr A. 2009 Sep 6. [Epub ahead of print] PMID: 19775696 [PubMed - as supplied by publisher]

  • Unexpected formation of a cyclopentadienylruthenium alkoxycarbonyl complex with a coordinated C=C bond. Aberg JB, Warner MC, Bäckvall JE. J Am Chem Soc. 2009 Sep 30;131(38):13622-4. PMID: 19772359 [PubMed - in process]

  • Intra- and intermolecular interaction ECL study of novel ruthenium tris-bipyridyl complexes with different amine reductants. Sun S, Yang Y, Liu F, Fan J, Peng X, Kehr J, Sun L. Dalton Trans. 2009 Oct 14;(38):7969-74. Epub 2009 Aug 6. PMID: 19771359 [PubMed - in process]

  • Calixarene-monophosphines as supramolecular chelators. Sameni S, Lejeune M, Jeunesse C, Matt D, Welter R. Dalton Trans. 2009 Oct 14;(38):7912-23. Epub 2009 Aug 5. PMID: 19771354 [PubMed - in process]

  • Bimetallic complexes based on carboxylate and xanthate ligands: synthesis and electrochemical investigations. Lin YH, Leung NH, Holt KB, Thompson AL, Wilton-Ely JD. Dalton Trans. 2009 Oct 14;(38):7891-901. Epub 2009 May 15. PMID: 19771352 [PubMed - in process]

  • Interaction of nitric oxide with gold nanoparticles capped with a ruthenium(II) complex. Díaz-García AM, Fernández-Oliva M, Ortiz M, Cao R. Dalton Trans. 2009 Oct 14;(38):7870-2. Epub 2009 Aug 4. PMID: 19771345 [PubMed - in process]

  • Electrochemiluminescence detection based on ruthenium(II) tris(bipyridine) immobilised in sulfonic-functionalised titania nanoparticles by ion exchange strategy. Li Y, Yang F, Yang X. Analyst. 2009 Oct;134(10):2100-5. Epub 2009 Aug 5. PMID: 19768220 [PubMed - in process]

  • Protecting-Group-Free Synthesis of 3-tert-Prenylated Oxindoles: Contiguous All-Carbon Quaternary Centers via Tertiary Neopentyl Substitution. Grant CD, Krische MJ. Org Lett. 2009 Sep 18. [Epub ahead of print] PMID: 19764718 [PubMed - as supplied by publisher]

  • Ruthenium-catalyzed selective N ,N-diallylation- and N ,N ,O-triallylation of free amino acids. Sundararaju B, Achard M, Sharma GV, Bruneau C. Org Biomol Chem. 2009 Oct 7;7(19):3906-9. Epub 2009 Jul 31. PMID: 19763288 [PubMed - in process]

  • Theoretical Insight on the S --> O Photoisomerization of DMSO Complexes of Ru(II). Lutterman DA, Rachford AA, Rack JJ, Turro C. J Phys Chem A. 2009 Sep 17. [Epub ahead of print] PMID: 19761198 [PubMed - as supplied by publisher] Related Articles 19: Iodine(V)/Ruthenium(III)-Cocatalyzed Oxidations: A Highly Efficient Tandem Catalytic System for the Oxidation of Alcohols and Hydrocarbons with Oxone. Yusubov MS, Zagulyaeva AA, Zhdankin VV. Chemistry. 2009 Sep 16. [Epub ahead of print] No abstract available. PMID: 19760738 [PubMed - as supplied by publisher]

  • Metallomacrocycles with a Difference: Macrocyclic Complexes with Exocyclic Ruthenium(II)-Containing Domains. Constable EC, Housecroft CE, Neuburger M, Rösel PJ, Schaffner S, Zampese JA. Chemistry. 2009 Sep 16. [Epub ahead of print] PMID: 19760732 [PubMed - as supplied by publisher]

 

 

 

 

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