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About Niobium

Niobium Bohr

Refractory metals, characterized by their high melting point and resistance to oxidation, share many other attributes and applications; niobium and tantalum, in particular, are so similar to each other in properties and natural occurrence that the two were not definitely proven to be distinct elements until 1866. Niobium was the first of the two to be identified, in 1801 by British chemist and mineralogist Charles Hatchett. While employed at the British Museum, Hatchett became intrigued by a mineral sample displayed in the collection that had been sent decades earlier from the American colonies by Connecticut governor John Winthrop. His analysis of the sample yielded a substance he believed contained a heretofore undiscovered element that he named “columbium” for Columbia, the symbolic female embodiment of the United States, and the mineral itself came to be called columbite. Hatchett’s discovery was refuted shortly thereafter by British chemist William Hyde Wollaston, who claimed that columbium was in fact the same element discovered in a different mineral by Swedish chemist Anders Gustaf Ekeberg. Hyde argued that “tantalum” (Ekeberg’s name for the element, inspired by Greek mythological figure Tantalus) should subsume columbium as the sole official name for the substance.

The debate was far from over. In 1845, German chemist Heinrich Rose analyzed the same mineral from Ekeberg’s experiment (which had subsequently been termed tantalite) and announced the sample contained two elements in addition to tantalum--which he fittingly named “pelopium” and “niobium” after Pelops and Niobe, the daughters of Tantalus. Though Rose was ultimately incorrect in classifying pelopium as the third element in the sample (rather than a mixture of the other two, as it turned out to be), the substance he called niobium was indeed a second, distinct element--the very same substance Hatchett had (correctly) identified as an element in 1801. The element itself was isolated in 1864 independently by both Christian Blomstrand and Jean Charles Galissard de Marignac, putting an end to the uncertainty about its identity, but not to the ambiguity surrounding its name; both niobium and columbium coexisted in common usage without any consensus. Despite the IUPAC’s 1950 decision in favor of niobium as its sole official name, it is still referred to as columbium in some circles.

The difficulty in distinguishing between niobium and tantalum was due not only to their chemical similarity but also to the fact that the two never occur independently from each other in nature; besides columbite and tantalite, the two elements are found together in the minerals euxenite, manganocolumbite and manganotantalite, aeschynite, samarskite, simpsonite, tapiolite, and pyrochlore, the main commercial source of niobium when extracted as ferroniobium. It is also compercially prepared as a byproduct of tin extraction. de Marignac’s method of separating niobium from tantalum via fractional crystallization remained the primary method for many years, though other techniques such as liquid-liquid extraction were subsequently developed, all made possible by the differing densities of the two metals, niobium’s density being about half that of tantalum’s.

A soft and shiny gray transition metal, niobium is ductile and malleable and can be cold worked over 90% before requiring annealing. Comparared to other refractory metals, niobium has the lowest density, melting point, modulus of elasticity, and thermal conductivity, and the highest thermal expansion. A thin film of niobium oxide ranging from yellow-green to blue in appearance provides surface passivation that makes the metal resistant to corrosion and attack by acids. Paired with its high strength and melting point, niobium’s resistance to oxidation make it an important component of alloys and superalloys such as Inconel 718, C103, and ferroniobium for high temperature, high stress applications like combustion equipment, jet engines, rocket assemblies, gas pipeline production, and air frame systems of spacecraft. It is also used in nuclear reactors due to its low neutron absorption cross section. Adding niobium to carbon and alloy steels increase their strength, toughness, and machinability. Niobium alloys are often used for arc welding rods for stabilized grades of stainless steel and in the arc-tube seals of high pressure sodium vapor lamps; one of the first commercial uses for the metal was in incandescent lamp filaments before being supplanted by tungsten. Niobium is non-toxic and does not react with human tissue, and as such is commonly used in surgical implants and medical devices; it can be colored by anodization, and is used in some jewelry.

Niobium has the largest magnetic penetration depth of any element and, along with vanadium and technetium, is one of the three elemental type-II superconductors--materials that exhibit superconductivity in both strong electric currents and magnetic fields. Niobium-tin alloy (Nb3Sn) was the first such material to be discovered in 1961 at Bell Labs. Niobium-tin wires, niobium-zirconium wires, and niobium-titanium wires are used in the high power superconducting magnets in MRI scanners, nuclear magnetic resonance instruments, and CERN. Niobium oxide has been used in metallic glass and smart windows, and is increasingly used in electronics and optics due to its high dielectric constant; lithium niobium oxide (lithium niobate, or LiNBO) is a common non-linear optical crystal. Due to its similar properties and wider availability, niobium is a potential lower-cost subsitite for tantalum used in capacitors and transistors in microelectronics.

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Niobium's main use is in alloys where it is used to produce arc-welding rods and corrosion-resistant steel. Other applications include its use in superconducting materials, electronics, optics, numismatics and jewelry. Niobium is the basis for various barium titanate compositions used as dielectric coatings in telecommunications and small advanced electronics, such as cell phones, pagers and laptop computers. High Purity (99.999%) Niobium Oxide (Nb2O5) PowderNiobium has medical research applications as well. Niobium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity). High Purity (99.999%) Niobium (Nb) Sputtering TargetElemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Niobium nanoparticles and nanopowders are also available. Niobium oxides are available in powder and dense pellet form for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Niobium fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Niobium is also available in soluble forms including chlorides, nitrates and acetates. These compounds can be manufactured as solutions at specified stoichiometries.

Niobium Properties

Niobium (Nb) atomic and molecular weight, atomic number and elemental symbolNiobium is a Block D, Group 5, Period 5 element. Niobium Bohr ModelThe number of electrons in each of niobium's shells is 2, 8, 18, 12, 1 and its electronic configuration is [Kr] 4d4 5s1.The niobium atom has a radius of 142.9.pm and its Van der Waals radius is 200.pm. In its elemental form, CAS 7440-03-1, niobium has a gray metallic appearance. Elemental NiobiumNiobium has the largest magnetic penetration depth of any element and it's one of three elemental type II superconductors (along with vanadium and technetium). Niobium is found in the minerals pyrochlore, its main commercial source, and columbite. It is not found in nature as a free element. Niobium was first discovered by Charles Hatchett in 1801. The word Niobium originates from Niobe, daughter of mythical Greek king Tantalus.

Symbol: Nb
Atomic Number: 41
Atomic Weight: 92.90638
Element Category: transition metal
Group, Period, Block: 5, 5, d
Color: silvery-white/ gray metalli
Other Names: Niob, Niobio, Nióbio, Niobio
Melting Point: 2477 °C, 4491 °F, 2750 K
Boiling Point: 4744 °C, 8571 °F, 5017 K
Density: 8.57 g·cm3
Liquid Density @ Melting Point: N/A
Density @ 20°C: 8.57 g/cm3
Density of Solid: 8570 kg·m3
Specific Heat: 0.27 (kJ/kg K)
Superconductivity Temperature: 9.25 [or -263.9 °C (-443 °F)] K
Triple Point: N/A
Critical Point: N/A
Heat of Fusion (kJ·mol-1): 27.2
Heat of Vaporization (kJ·mol-1): 680.19
Heat of Atomization (kJ·mol-1): 722.819
Thermal Conductivity: 53.7 W·m-1·K-1
Thermal Expansion: 7.3 µm/(m·K)
Electrical Resistivity: (0 °C) 152 nΩ·m
Tensile Strength: N/A
Molar Heat Capacity: N/A
Young's Modulus: 105 GPa
Shear Modulus: 38 GPa
Bulk Modulus: 170 GPa
Poisson Ratio: 0.4
Mohs Hardness: 6
Vickers Hardness: 1320 MPa
Brinell Hardness: 736 MPa
Speed of Sound: (20 °C) 3480 m·s-1
Pauling Electronegativity: 1.6
Sanderson Electronegativity: 1.42
Allred Rochow Electronegativity: 1.23
Mulliken-Jaffe Electronegativity: N/A
Allen Electronegativity: N/A
Pauling Electropositivity: 2.4
Reflectivity (%): N/A
Refractive Index: N/A
Electrons: 41
Protons: 41
Neutrons: 52
Electron Configuration: [Kr] 4d4 5s1
Atomic Radius: 146 pm
Atomic Radius,
non-bonded (Å):
2.18
Covalent Radius: 164±6 pm
Covalent Radius (Å): 1.56
Van der Waals Radius: 200 pm
Oxidation States: 5, 4, 3, 2, -1 (mildly acidic oxide)
Phase: Solid
Crystal Structure: cubic body-centered
Magnetic Ordering: paramagnetic
Electron Affinity (kJ·mol-1) 88.381
1st Ionization Energy: 652.13 kJ·mol-1
2nd Ionization Energy: 1381.68 kJ·mol-1
3rd Ionization Energy: 2416.01 kJ·mol-1
CAS Number: 7440-03-1
EC Number: 231-113-5
MDL Number: MFCD00011126
Beilstein Number: N/A
SMILES Identifier: [Nb]
InChI Identifier: InChI=1S/Nb
InChI Key: GUCVJGMIXFAOAE-UHFFFAOYSA-N
PubChem CID: 23936
ChemSpider ID: 22378
Earth - Total: 800 ppb
Mercury - Total: 610 ppb
Venus - Total: 840 ppb 
Earth - Seawater (Oceans), ppb by weight: 0.001
Earth - Seawater (Oceans), ppb by atoms: 0.000067
Earth -  Crust (Crustal Rocks), ppb by weight: 17000
Earth -  Crust (Crustal Rocks), ppb by atoms: 3700
Sun - Total, ppb by weight: 4
Sun - Total, ppb by atoms: 0.05
Stream, ppb by weight: N/A
Stream, ppb by atoms: N/A
Meterorite (Carbonaceous), ppb by weight: 190
Meterorite (Carbonaceous), ppb by atoms: 30
Typical Human Body, ppb by weight: N/A
Typical Human Body, ppb by atom: N/A
Universe, ppb by weight: 2
Universe, ppb by atom: 0
Discovered By: Charles Hatchett
Discovery Date: 1801
First Isolation: N/A

Health, Safety & Transportation Information for Niobium

Some niobium compounds are considered toxic. Safety data for Niobium and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the Products tab. The below information applies to elemental (metallic) Niobium.

Safety Data
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H250
Hazard Codes F
Risk Codes 17
Safety Precautions 6
RTECS Number QT9900000
Transport Information UN 1383 4.2/PG 1
WGK Germany nwg
Globally Harmonized System of
Classification and Labelling (GHS)
Flame-Flammables

Niobium Isotopes

Niobium has one stable isotope: 93Nb

Nuclide Isotopic Mass Half-Life Mode of Decay Nuclear Spin Magnetic Moment Binding Energy (MeV) Natural Abundance
(% by atom)
81Nb 80.94903(161)# <44 ns ß+ + p to 80Y; p to 80Zr; ß+ to 81Zr 3/2-# N/A 655.88 -
82Nb 81.94313(32)# 51(5) ms ß+ to 82Zr 0+ N/A 669.55 -
83Nb 82.93671(34) 4.1(3) s ß+ to 83Zr (5/2+) N/A 684.15 -
84Nb 83.93357(32)# 9.8(9) s ß+ to 84Zr; ß+ + p to 85Zr 3+ N/A 695.03 -
85Nb 84.92791(24) 20.9(7) s ß+ to 85Zr (9/2+) N/A 708.69 -
86Nb 85.92504(9) 88(1) s ß+ to 86Zr (6+) N/A 718.64 -
87Nb 86.92036(7) 3.75(9) min ß+ to 87Zr (1/2-) N/A 731.37 -
88Nb 87.91833(11) 14.55(6) min ß+ to 88Zr (8+) N/A 741.32 -
89Nb 88.913418(29) 2.03(7) h EC to 89Zr (9/2+) N/A 754.05 -
90Nb 89.911265(5) 14.60(5) h EC to 90Zr 8+ 4.961 763.99
91Nb 90.906996(4) 680(130) y EC to 91Zr 9/2+ N/A 776.73 -
92Nb 91.907194(3) 3.47(24)E+7 y EC to 92Zr; ß- to 92Mo (7)+ 6.114 783.88 -
93Nb 92.9063781(26) Observationally Stable - 9/2+ 6.1705 792.89 100
94Nb 93.9072839(26) 2.03(16)E+4 y ß- to 94Mo (6)+ N/A 800.04 -
95Nb 94.9068358(21) 34.991(6) d ß- to 95Mo 9/2+ 6.141 809.05 -
96Nb 95.908101(4) 23.35(5) h ß- to 96Mo 6+ 4.976 815.26 -
97Nb 96.9080986(27) 72.1(7) min ß- to 97Mo 9/2+ 6.15 823.34 -
98Nb 97.910328(6) 2.86(6) s ß- to 98Mo 1+ N/A 829.56 -
99Nb 98.911618(14) 15.0(2) s ß- to 99Mo 9/2+ N/A 836.7 -
100Nb 99.914182(28) 1.5(2) s ß- to 100Mo 1+ N/A 841.99 -
101Nb 100.915252(20) 7.1(3) s ß- to 101Mo (5/2#)+ N/A 853.79 -
102Nb 101.91804(4) 1.3(2) s ß- to 102Mo 1+ N/A 861.87 -
103Nb 102.91914(7) 1.5(2) s ß- to 103Mo (5/2+) N/A 869.95 -
104Nb 103.92246(11) 4.9(3) s ß- to 104Mo; ß- to 103Mo (1+) N/A 868.71 -
105Nb 104.92394(11) 2.95(6) s ß- to 105Mo; ß- to 104Mo (5/2+)# N/A 876.79 -
106Nb 105.92797(21)# 920(40) ms ß- to 106Mo; ß- to 105Mo 2+# N/A 884.87 -
107Nb 106.93031(43)# 300(9) ms ß- to 107Mo; ß- to 106Mo 5/2+# N/A 883.63 -
108Nb 107.93484(32)# 0.193(17) s ß- to 108Mo; ß- to 107Mo (2+) N/A 891.71 -
109Nb 108.93763(54)# 190(30) ms ß- to 109Mo; ß- to 108Mo 5/2+# N/A 899.79 -
110Nb 109.94244(54)# 170(20) ms ß- to 110Mo; ß- to 109Mo 2+# N/A 898.55 -
111Nb 110.94565(54)# 80# ms [>300 ns] Unknown 5/2+# N/A 906.63 -
112Nb 111.95083(75)# 60# ms [>300 ns] Unknown 2+# N/A 905.39 -
113Nb 112.95470(86)# 30# ms [>300 ns] Unknown 5/2+# N/A 913.47 -
Niobium Elemental Symbol

Recent Research & Development for Niobium

  • Resolving the morphology of niobium carbonitride nano-precipitates in steel using atom probe tomography. Breen AJ, Xie KY, Moody MP, Gault B, Yen HW, Wong CC, Cairney JM, Ringer SP. Microsc Microanal. 2014 Aug
  • Subtle niobium. Tarselli MA. Nat Chem. 2014 Feb
  • Development of a separation method for molybdenum from zirconium, niobium, and major elements of rubble samples. Shimada A, Ozawa M, Yabuki K, Kimiyama K, Sato K, Kameo Y. J Chromatogr A. 2014 Dec 5
  • Mild Niobium-Catalyzed [2 + 2 + 2] Cycloaddition of Sila-triynes: Easy Access to Polysubstituted Benzosilacyclobutenes. Simon C, Amatore M, Aubert C, Petit M. Org Lett. 2015 Feb 20
  • Tetraphenolate niobium and tantalum complexes for the ring opening polymerization of ?-caprolactone. Al-Khafaji Y, Sun X, Prior TJ, Elsegood MR, Redshaw C. Dalton Trans. 2015 Feb 27.
  • Sub-picowatt resolution calorimetry with niobium nitride thin-film thermometer. Dechaumphai E, Chen R. Rev Sci Instrum. 2014 Sep
  • Proton conductivity of naphthalene sulfonate formaldehyde resin-doped mesoporous niobium and tantalum oxide composites. Turley JP, Romer F, Trudeau ML, Dias ML, Smith ME, Hanna JV, Antonelli DM. ChemSusChem. 2015 Jan
  • Radiopacity and cytotoxicity of Portland cement associated with niobium oxide micro and nanoparticles. Mestieri LB, Tanomaru-Filho M, Gomes-Cornélio AL, Salles LP, Bernardi MI, Guerreiro-Tanomaru JM. J Appl Oral Sci. 2014 Nov-Dec
  • Structural and spectroscopic characterizations of tetra-nuclear niobium(V) complexes of quinolinol derivatives. Amini MM, Fazaeli Y, Mohammadnezhad G, Khavasi HR. Spectrochim Acta A Mol Biomol Spectrosc. 2015 Feb 26
  • Advanced hybrid supercapacitor based on a mesoporous niobium pentoxide/carbon as high-performance anode. Lim E, Kim H, Jo C, Chun J, Ku K, Kim S, Lee HI, Nam IS, Yoon S, Kang K, Lee J. ACS Nano. 2014 Sep 23
  • Monolithic gyroidal mesoporous mixed titanium-niobium nitrides. Robbins SW, Sai H, DiSalvo FJ, Gruner SM, Wiesner U. ACS Nano. 2014 Aug 26
  • Nb2O2F3: a reduced niobium (III/IV) oxyfluoride with a complex structural, magnetic, and electronic phase transition. Tran TT, Gooch M, Lorenz B, Litvinchuk AP, Sorolla MG 2nd, Brgoch J, Chu PC, Guloy AM. J Am Chem Soc. 2015 Jan 21
  • Mixed amido-/imido-/guanidinato niobium complexes: synthesis and the effect of ligands on insertion reactions. Elorriaga D, Carrillo-Hermosilla F, Antiñolo A, López-Solera I, Fernández-Galán R, Villaseñor E. Dalton Trans. 2014 Dec 14
  • Probing structural variation and multifunctionality in niobium doped bismuth vanadate materials. Saithathul Fathimah S, Prabhakar Rao P, James V, Raj AK, Chitradevi GR, Leela S. Dalton Trans. 2014 Nov 14
  • Niobium(V) and tantalum(V) halide chalcogenoether complexes--towards single source CVD precursors for ME2 thin films. Benjamin SL, Chang YP, Gurnani C, Hector AL, Huggon M, Levason W, Reid G. Dalton Trans. 2014 Nov 28
  • Niobium-nitrides derived from nitrogen splitting. Searles K, Carroll PJ, Chen CH, Pink M, Mindiola DJ. Chem Commun (Camb). 2015 Feb 12
  • Reductive lithium insertion into B-cation deficient niobium perovskite oxides. Perejon A, Hayward MA. Dalton Trans. 2015 Jan 5.
  • Niobium pentoxide as radiopacifying agent of calcium silicate-based material: evaluation of physicochemical and biological properties. Silva GF, Tanomaru-Filho M, Bernardi MI, Guerreiro-Tanomaru JM, Cerri PS. Clin Oral Investig. 2015 Feb 3.
  • Redox-reversible niobium-doped strontium titanate decorated with in situ grown nickel nanocatalyst for high-temperature direct steam electrolysis. Yang L, Xie K, Xu S, Wu T, Zhou Q, Xie T, Wu Y. Dalton Trans. 2014 Oct 7
  • Regioselective [2+2] and [4+2] cycloaddition reactivity in an asymmetric niobium(bisimido) moiety towards unsaturated organic molecules. Obenhuber AH, Gianetti TL, Bergman RG, Arnold J. Chem Commun (Camb). 2015 Jan 25