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Vanadium
Vanadium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Vanadium is highly resistant to corrosion, so it is commonly used to alloy stainless steel grades. Vanadium compounds are used in advanced ceramics. Vanadium is a petrochemical cracking catalyst. Vanadium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Vanadium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


(click on an element)
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Vanadium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Vanadium is a Block D, Group 5, Period 4 element. The electronic configuration is [Ar] 3d3 4s2. In its elemental form vanadium's CAS number is 7440-62-2. The vanadium atom has a radius of 131.1.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Vanadium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Vanadium was first discovered by Nils Sefstrom in 1830.

French vanadium German Vanadium Italian vanadio Portuguese Vanádio Spanish vanadio Swedish Vanadin

Abundance. The following table shows the abundance of vanadium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
V-50
49.947163
0.25
V-51
50.943964
99.75

Safety Data. The safety data for vanadium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for vanadium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
650.92 kJ mol-1
2nd Ionization Energy
1414.49 kJ mol-1
3rd Ionization Energy
2828.10 kJ mol-1

Conductivity. As to vanadium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 19.68 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.63. The thermal conductivity of vanadium is 30.7 W m-1 K-1.

Thermal Properties. The melting point and boiling point for vanadium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
17.6 kJ mol-1
Heat of Vaporization
459.7 kJ mol-1
Heat of Atomization
510.95 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
V 23 50.9414 g.mol -1 1.6 6.1 g.cm-3 at 20 °C 1910 °C 3407 °C 200.pm 0.074 nm (+3) ; 0.059 (+5) 650.92 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Vanadium

  • Synthesis, Structure, and Magnetic Properties of [(CH(3)CN)(5)V-O-V(CH(3)CN)(5)][BF(4)](4). Inorg Chem. 2007 Oct 2; [Epub ahead of print]

  • Investigating the Vanadium Environments in Hydroxylamido V(V) Dipicolinate Complexes Using (51)V NMR Spectroscopy and Density Functional Theory. Inorg Chem. 2007 Sep 29; [Epub ahead of print]

  • Soil metal concentrations and vegetative assemblage structure in an urban brownfield. Environ Pollut. 2007 Sep 25; [Epub ahead of print]

  • Impairment of mineralization by metavanadate and decavanadate solutions in a fish bone-derived cell line. Cell Biol Toxicol. 2007 Sep 25; [Epub ahead of print]

  • Electronic states of neutral and cationic bis(benzene) titanium and vanadium sandwich complexes studied by pulsed field ionization electron spectroscopy. J Chem Phys. 2007 Sep 21;127(11):114302.

  • A pilot study on the content and the release of Ni and other allergenic metals from cheap earrings available on the Italian market. Sci Total Environ. 2007 Sep 19; [Epub ahead of print]

  • Dinitrogen Coordination and Cleavage Promoted by a Vanadium Complex of a sigma,pi,sigma-Donor Ligand. Inorg Chem. 2007 Sep 21; [Epub ahead of print]

  • A visible light photocatalyst: effects of vanadium substitution on ETS-10. Phys Chem Chem Phys. 2007 Oct 7;9(37):5096-104. Epub 2007 Jul 25.

  • Effect of vanadate on gene expression of the insulin signaling pathway in skeletal muscle of streptozotocin-induced diabetic rats. J Biol Inorg Chem. 2007 Sep 14; [Epub ahead of print]

  • Spectroscopic Characterization of a VO2+ Complex of Oxodiacetic Acid and its Bioactivity on Osteoblast-like Cells in Culture. Biol Trace Elem Res. 2007 Aug;118(2):159-66.

  • Molecular basis of vanadium-mediated inhibition of hepatocellular preneoplasia during experimental hepatocarcinogenesis in rats.
    J Cell Biochem. 2007 Jan 22; [Epub ahead of print]

  • Catalytic destruction of 1,2-dichlorobenzene on V(2)O(5)-WO(3)/Al(2)O(3)-TiO(2) catalyst.
    Chemosphere. 2007 Jan 18; [Epub ahead of print]

  • Ab initio constrained crystal-chemical Rietveld refinement of Ca(10)(V(x)P(1 - x)O(4))(6)F(2) apatites.
    Acta Crystallogr B. 2007 Feb;63(Pt 1):37-48. Epub 2007 Jan 15.

  • Stopped-in-loop flow analysis of trace vanadium in water.
    Anal Sci. 2007 Jan;23(1):1-2.

  • Vanadium-catalyzed asymmetric epoxidation of homoallylic alcohols.
    J Am Chem Soc. 2007 Jan 17;129(2):286-7.

  • Marginal and internal adaptation of commercially pure titanium and titanium-aluminum-vanadium alloy cast restorations.
    J Contemp Dent Pract. 2007 Jan 1;8(1):19-26.

  • Role of trace elements in primary arterial hypertension: is mineral water style or prophylaxis?
    Biol Trace Elem Res. 2006 Winter;114(1-3):1-6.

  • Glycine- and sarcosine-based models of vanadate-dependent haloperoxidases in sulfoxygenation reactions.
    Inorg Chem. 2007 Jan 8;46(1):196-207.

  • Carcinogen-induced early molecular events and its implication in the initiation of chemical hepatocarcinogenesis in rats: chemopreventive role of vanadium on this process.
    Biochim Biophys Acta. 2007 Jan;1772(1):48-59. Epub 2006 Nov 10.

  • Binding of oxovanadium ions to the major and minor grooves of DNA duplex: stability and structural models.
    Biochem Cell Biol. 2006 Oct;84(5):677-83.

 

 

 

 

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