Thorium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.
Thorium is a lanthanide (rare earth) material with potential nuclear power applications. Thorium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is presently used as a tungsten coating in electronic parts due to its high emission factor. Thorium in the form of its fluoride and oxide is used in advanced optic applications for its high refractive index. It is also used in several other high temperature glass applications, such as in the mantle of lamps and to produce crystal growth crucibles and ampules.
Thorium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.
Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Thorium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.
Thorium is a Block F, Group 3, Period 7 element. The electronic configuration is [Rn] 6d2 7s2. In its elemental form thorium's CAS number is 7440-29-1. The thorium atom has a radius of 179.8.pm and it's Van der Waals radius is 200.pm.
All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Thorium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.
Thorium was first discovered by Jons Berzelius in 1828.
Thorium |
Thorium |
Torio |
Tório |
Torio |
Torium |
Abundance. The following table shows the abundance of thorium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.
|
Isotope |
Atomic Mass |
% Abundance on Earth |
Th-229 |
229.031755 |
* |
Th-230 |
232.038050 |
100 |
Safety Data. The safety data for thorium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.
Ionization Energy. The ionization energy for thorium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:
|
1st Ionization Energy |
608.51 kJ mol-1 |
2nd Ionization Energy |
1109.59 kJ mol-1 |
3rd Ionization Energy |
1929.72 kJ mol-1 |
Conductivity. As to thorium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 13 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.3. The thermal conductivity of thorium is 54 W m-1 K-1.
Thermal Properties. The melting point and boiling point for thorium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.
|
Heat of Fusion |
19.2 kJ mol-1 |
Heat of Vaporization |
513.67 kJ mol-1 |
Heat of Atomization |
598.65 kJ mol-1 |
|
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