Ammonium Tetrathiomolybdate

(NH4)2MoS4
CAS 15060-55-6


Product Product Code Order or Specifications
(2N) 99% Ammonium Tetrathiomolybdate AM-THMO-02 Contact American Elements
(3N) 99.9% Ammonium Tetrathiomolybdate AM-THMO-03 Contact American Elements
(4N) 99.99% Ammonium Tetrathiomolybdate AM-THMO-04 Contact American Elements
(5N) 99.999% Ammonium Tetrathiomolybdate AM-THMO-05 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
(NH4)2MoS4 15060-55-6 162220186 10106661 MFCD00136013 N/A diazanium; molybdenum; tetrasulfide N/A [S-2].[S-2].[S-
2].[S-2].[Mo].[
NH4+].[NH4+]
InChI=1S/Mo.2H
3N.4S/h;2*1H3;;
;;/q;;;4*-2/p+2
SSWUEGNZIONBHZ-UHFFFAOYSA-P

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
H8MoN2S4 260.28 Red. green, purple, or black powder >300 °C N/A N/A 261.86244 261.86244 -6 Safety Data Sheet

Ammonium Tetrathiomolybdate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Molybdenum (Mo) atomic and molecular weight, atomic number and elemental symbolMolybdenum (atomic symbol: Mo, atomic number: 42) is a Block D, Group 6, Period 5 element with an atomic weight of 95.96. Molybdenum Bohr ModelThe number of electrons in each of molybdenum's shells is [2, 8, 18, 13, 1] and its electron configuration is [Kr] 4d5 5s1. The molybdenum atom has a radius of 139 pm and a Van der Waals radius of 209 pm. In its elemental form, molybdenum has a gray metallic appearance. Molybdenum was discovered by Carl Wilhelm in 1778 and first isolated by Peter Jacob Hjelm in 1781. Molybdenum is the 54th most abundant element in the earth's crust.Elemental Molybdenum It has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum does not occur naturally as a free metal, it is found in various oxidation states in minerals. The primary commercial source of molybdenum is molybdenite, although it is also recovered as a byproduct of copper and tungsten mining. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead. For more information on molybdenum, including properties, safety data, research, and American Elements' catalog of molybdenum products, visit the Molybdenum Information Center.

Sulfur Bohr ModelSulfur (S) atomic and molecular weight, atomic number and elemental symbolSulfur or Sulphur (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne]3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777 when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound. For more information on sulfur, including properties, safety data, research, and American Elements' catalog of sulfur products, visit the Sulfur Information Center.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Precautions N/A
RTECS Number N/A
Transport Information N/A
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
N/A        

AMMONIUM TETRATHIOMOLYBDATE SYNONYMS
Diammonium disulfido(dithioxo)molybdenum; Ammonium molybdenum sulfide; Diammonium tetrathioxomolybdate(2-); diammonium molybdenum tetrasulfide; Thiomolybdic acid, diammonium salt; Molybdate(2-), tetrathioxo-, diammonium, (T-4)-

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Molybdenum

  • Han-Chul Park, Kyung-Hoon Lee, Young-Woo Lee, Si-Jin Kim, Da-Mi Kim, Min-Cheol Kim, Kyung-Won Park, Mesoporous molybdenum nitride nanobelts as an anode with improved electrochemical properties in lithium ion batteries, Journal of Power Sources, Volume 269, 10 December 2014
  • Feng Wu, Jun Tian, Yuefeng Su, Yibiao Guan, Yi Jin, Zhao Wang, Tao He, Liying Bao, Shi Chen, Lithium-active molybdenum trioxide coated LiNi0.5Co0.2Mn0.3O2 cathode material with enhanced electrochemical properties for lithium-ion batteries, Journal of Power Sources, Volume 269, 10 December 2014
  • Xiao Jin, Weifu Sun, Zihan Chen, Yue Li, Pinjiang Li, Xingdao He, Yongbiao Yuan, Shibing Zou, Yuancheng Qin, Qinghua Li, Efficient electron/hole transport in inorganic/organic hybrid solar cells by lithium ion and molybdenum trioxide codoping, Journal of Power Sources, Volume 268, 5 December 2014
  • M. Miyamoto, H. Takaoka, K. Ono, S. Morito, N. Yoshida, H. Watanabe, A. Sagara, Crystal orientation dependence of surface modification in molybdenum mirror irradiated with helium ions, Journal of Nuclear Materials, Volume 455, Issues 1–3, December 2014
  • Bedabibhas Mohanty, Beau D. Morton, Arif Sinan Alagoz, Tansel Karabacak, Min Zou, Frictional anisotropy of tilted molybdenum nanorods fabricated by glancing angle deposition, Tribology International, Volume 80, December 2014
  • S. Imran U. Shah, Andrew L. Hector, John R. Owen, Redox supercapacitor performance of nanocrystalline molybdenum nitrides obtained by ammonolysis of chloride- and amide-derived precursors, Journal of Power Sources, Volume 266, 15 November 2014
  • Omid Torabi, Mohammad Hossein Golabgir, Hamid Tajizadegan, Hamid Torabi, A study on mechanochemical behavior of MoO3–Mg–C to synthesize molybdenum carbide, International Journal of Refractory Metals and Hard Materials, Volume 47, November 2014
  • M. Jones, A. Cockburn, R. Lupoi, M. Sparkes, W. O’Neill, Solid-state manufacturing of tungsten deposits onto molybdenum substrates with supersonic laser deposition, Materials Letters, Volume 134, 1 November 2014
  • Majid Khan, Mohammad Islam, Aftab Akram, Zeming Qi, Liangbin Li, Residual strain and electrical resistivity dependence of molybdenum films on DC plasma magnetron sputtering conditions, Materials Science in Semiconductor Processing, Volume 27, November 2014
  • Lin Ma, Guochuang Huang, Weixiang Chen, Zhen Wang, Jianbo Ye, Haiyang Li, Dongyun Chen, Jim Yang Lee, Cationic surfactant-assisted hydrothermal synthesis of few-layer molybdenum disulfide/graphene composites: Microstructure and electrochemical lithium storage, Journal of Power Sources, Volume 264, 15 October 2014
  • Iva Honzícková, Jan Honzícek, Jaromír Vinklárek, Zdenka Padelková, Allyl molybdenum(II) and tungsten(II) compounds bearing bidentate and tridentate pyrazolylmethane ligands, Polyhedron, Volume 81, 15 October 2014
  • Yan-Ming Liu, Gui-Fang Shi, Jing-Jing Zhang, Min Zhou, Jun-Tao Cao, Ke-Jing Huang, Shu-Wei Ren, A novel label-free electrochemiluminescence aptasensor based on layered flowerlike molybdenum sulfide–graphene nanocomposites as matrix, Colloids and Surfaces B: Biointerfaces, Volume 122, 1 October 2014
  • Mingzhu Liu, Tao Wang, Xiaoxue Zhang, Xiaoli Fan, Jing Tang, Qiaoqiao Xie, Hairong Xue, Hu Guo, Jianping He, A facile synthesis of highly compacted, molybdenum-embedded, ordered, mesoporous, protective carbon films of graphitic structure, Corrosion Science, Volume 87, October 2014
  • S.W. Hu, L.W. Yang, Y. Tian, X.L. Wei, J.W. Ding, J.X. Zhong, Paul K. Chu, Non-covalent doping of graphitic carbon nitride with ultrathin graphene oxide and molybdenum disulfide nanosheets: An effective binary heterojunction photocatalyst under visible light irradiation, Journal of Colloid and Interface Science, Volume 431, 1 October 2014
  • O.A. Lambri, F.G. Bonifacich, P.B. Bozzano, G.I. Zelada, F. Plazaola, J.A. García, Defects interaction processes in deformed high purity polycrystalline molybdenum at elevated temperatures, Journal of Nuclear Materials, Volume 453, Issues 1–3, October 2014
  • Zonghua Pu, Qian Liu, Abdullah M. Asiri, Abdullah Y. Obaid, Xuping Sun, Graphene film-confined molybdenum sulfide nanoparticles: Facile one-step electrodeposition preparation and application as a highly active hydrogen evolution reaction electrocatalyst, Journal of Power Sources, Volume 263, 1 October 2014
  • Dong-Suk Han, Yu-Jin Kang, Jae-Hyung Park, Hyung-Tag Jeon, Jong-Wan Park, Influence of molybdenum source/drain electrode contact resistance in amorphous zinc–tin-oxide (a-ZTO) thin film transistors, Materials Research Bulletin, Volume 58, October 2014
  • Anna Wojtaszek-Gurdak, Maciej Trejda, Dorota Kryszak, Maria Ziolek, Comparative study of MCM-22 and MCM-56 modified with molybdenum – Impact of the metal on acidic and oxidative properties of zeolites, Microporous and Mesoporous Materials, Volume 197, October 2014
  • Mahsa Jalal Mousavi, Mohammad Zakeri, Mohammadreza Rahimipour, Elham Amini, Mechanical properties of pressure-less sintered ZrB2 with molybdenum, iron and carbon additives, Materials Science and Engineering: A, Volume 613, 8 September 2014
  • Emmanuel D. Simandiras, Dimitrios G. Liakos, Nikolaos Psaroudakis, Konstantinos Mertis, Kubas complexes extended to four centers; a theoretical prediction of novel dihydrogen coordination in bimetallic tungsten and molybdenum compounds, Journal of Organometallic Chemistry, Volume 766, 1 September 2014

Recent Research & Development for Sulfur

  • Hongying Li, Junying Duan, Xiaobing Min, Comparative studies on the initial stage of arc-sprayed and zinc-rich powder coatings in sulfur-rich environment, Journal of Alloys and Compounds, Volume 616, 15 December 2014
  • Jun Zhang, Zimin Dong, Xiuli Wang, Xuyang Zhao, Jiangping Tu, Qingmei Su, Gaohui Du, Sulfur nanocrystals anchored graphene composite with highly improved electrochemical performance for lithium–sulfur batteries, Journal of Power Sources, Volume 270, 15 December 2014
  • Yu-Sheng Su, Arumugam Manthiram, Sulfur/lithium-insertion compound composite cathodes for Li–S batteries, Journal of Power Sources, Volume 270, 15 December 2014
  • Yongguang Zhang, Yan Zhao, Zhumabay Bakenov, Aishuak Konarov, P. Chen, Preparation of novel network nanostructured sulfur composite cathode with enhanced stable cycle performance, Journal of Power Sources, Volume 270, 15 December 2014
  • Ning Ding, Sheau Wei Chien, T.S. Andy Hor, Zhaolin Liu, Yun Zong, Key parameters in design of lithium sulfur batteries, Journal of Power Sources, Volume 269, 10 December 2014
  • Shunji Kinoshita, Kazuya Okuda, Nobuya Machida, Toshihiko Shigematsu, Additive effect of ionic liquids on the electrochemical property of a sulfur composite electrode for all-solid-state lithium–sulfur battery, Journal of Power Sources, Volume 269, 10 December 2014
  • Keeyoung Jung, Solki Lee, Goun Kim, Chang-Soo Kim, Stress analyses for the glass joints of contemporary sodium sulfur batteries, Journal of Power Sources, Volume 269, 10 December 2014
  • Jan Brückner, Sören Thieme, Hannah Tamara Grossmann, Susanne Dörfler, Holger Althues, Stefan Kaskel, Lithium–sulfur batteries: Influence of C-rate, amount of electrolyte and sulfur loading on cycle performance, Journal of Power Sources, Volume 268, 5 December 2014
  • Lin Chen, Leon L. Shaw, Recent advances in lithium–sulfur batteries, Journal of Power Sources, Volume 267, 1 December 2014
  • Sebastian Risse, Stefano Angioletti-Uberti, Joachim Dzubiella, Matthias Ballauff, Capacity fading in lithium/sulfur batteries: A linear four-state model, Journal of Power Sources, Volume 267, 1 December 2014
  • Xin Qing, Jingjing Shi, Chengyu Ma, Mengyang Fan, Zhengyu Bai, Zhongwei Chen, Jinli Qiao, Jiujun Zhang, Simultaneous formation of nitrogen and sulfur-doped transition metal catalysts for oxygen reduction reaction through pyrolyzing carbon-supported copper phthalocyanine tetrasulfonic acid tetrasodium salt, Journal of Power Sources, Volume 266, 15 November 2014
  • Qiang Li, Zhian Zhang, Zaiping Guo, Yanqing Lai, Kai Zhang, Jie Li, Improved cyclability of lithium–sulfur battery cathode using encapsulated sulfur in hollow carbon nanofiber@nitrogen-doped porous carbon core–shell composite, Carbon, Volume 78, November 2014
  • Fatemeh Razmjooei, Kiran Pal Singh, Min Young Song, Jong-Sung Yu, Enhanced electrocatalytic activity due to additional phosphorous doping in nitrogen and sulfur-doped graphene: A comprehensive study, Carbon, Volume 78, November 201
  • Ling Fei, Yufeng Jiang, Yun Xu, Gen Chen, Yuling Li, Xun Xu, Shuguang Deng, Hongmei Luo, A novel solvent-free thermal reaction of ferrocene and sulfur for one-step synthesis of iron sulfide and carbon nanocomposites and their electrochemical performance, Journal of Power Sources, Volume 265, 1 November 2014
  • Marco Agostini, Dong-Ju Lee, Bruno Scrosati, Yang Kook Sun, Jusef Hassoun, Characteristics of Li2S8-tetraglyme catholyte in a semi-liquid lithium–sulfur battery, Journal of Power Sources, Volume 265, 1 November 2014
  • Myoungsu Shin, Kyuhun Kim, Seong-Woo Gwon, Soowon Cha, Durability of sustainable sulfur concrete with fly ash and recycled aggregate against chemical and weathering environments, Construction and Building Materials, Volume 69, 30 October 2014
  • Mariusz Ksiazek, The biocorrosion of city sewer collector impregnated special polymer sulfur binder – Polymerized sulfur applied as the industrial waste material, Construction and Building Materials, Volume 68, 15 October 2014
  • Eyal Tzur, Elisa Ivry, Charles E. Diesendruck, Yuval Vidavsky, Israel Goldberg, N. Gabriel Lemcoff, Stability and activity of cis-dichloro ruthenium olefin metathesis precatalysts bearing chelating sulfur alkylidenes, Journal of Organometallic Chemistry, Volume 769, 15 October 2014
  • Matthew J. Lacey, Fabian Jeschull, Kristina Edström, Daniel Brandell, Functional, water-soluble binders for improved capacity and stability of lithium–sulfur batteries, Journal of Power Sources, Volume 264, 15 October 2014
  • M. Hagen, P. Fanz, J. Tübke, Cell energy density and electrolyte/sulfur ratio in Li–S cells, Journal of Power Sources, Volume 264, 15 October 2014