Evaluation of a new electrochemical sensor for selective detection of non-enzymatic hydrogen peroxide based on hierarchical nanostructures of zirconium molybdate.

Title Evaluation of a new electrochemical sensor for selective detection of non-enzymatic hydrogen peroxide based on hierarchical nanostructures of zirconium molybdate.
Authors V. Kumar; R. Karthik; S.M. Chen; N. Raja; V. Selvam; V. Muthuraj
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2017.03.113
Abstract

The construction and characterization of selective and sensitive non-enzymatic hydrogen peroxide (H2O2) electrochemical sensor based on sphere-like zirconium molybdate (ZrMo2O8) nanostructure are reported for the first time. The sphere-like ZrMo2O8 were prepared via a simple hydrothermal route followed by annealing process. The structural and morphological properties were investigated by various analytical and spectroscopic techniques such as XRD, Raman, SEM, EDX, TEM, and XPS analysis. Furthermore, the electrochemical properties were investigated by cyclic voltammetry and amperometric techniques. The obtained results displayed that the prepared ZrMo2O8 materials hold excellent-crystallinity, well-defined sphere-like formation and demonstrated superior electrochemical properties. Interestingly, the electrochemical H2O2 sensor was constructed based on ZrMo2O8 nanostructure on the glassy carbon electrode exhibited wide linear response ranges, good sensitivity and lower detection limit (LOD). The estimated sensitivity, wide linear ranges and LOD of the fabricated electrochemical sensor was 2.584?A?M(-1)cm(-2), 0.05-523, 543-3053?M and 0.01?M respectively. The proposed sensor had excellent selectivity even in the presence of biologically co-interfering substances such as uric acid, dopamine, ascorbic acid and glucose. This effortless, fast, inexpensive technique for constructing a modified electrode is a gorgeous approach to the growth of new sensors.

Citation V. Kumar; R. Karthik; S.M. Chen; N. Raja; V. Selvam; V. Muthuraj.Evaluation of a new electrochemical sensor for selective detection of non-enzymatic hydrogen peroxide based on hierarchical nanostructures of zirconium molybdate.. J Colloid Interface Sci. 2017;500:4453. doi:10.1016/j.jcis.2017.03.113

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Zirconium

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Molybdenum

See more Molybdenum products. Molybdenum (atomic symbol: Mo, atomic number: 42) is a Block D, Group 6, Period 5 element with an atomic weight of 95.96. Molybdenum Bohr ModelThe number of electrons in each of molybdenum's shells is [2, 8, 18, 13, 1] and its electron configuration is [Kr] 4d5 5s1. The molybdenum atom has a radius of 139 pm and a Van der Waals radius of 209 pm. In its elemental form, molybdenum has a gray metallic appearance. Molybdenum was discovered by Carl Wilhelm in 1778 and first isolated by Peter Jacob Hjelm in 1781. Molybdenum is the 54th most abundant element in the earth's crust. Elemental MolybdenumIt has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum does not occur naturally as a free metal, it is found in various oxidation states in minerals. The primary commercial source of molybdenum is molybdenite, although it is also recovered as a byproduct of copper and tungsten mining. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead.

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