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Gallium Selenide Single Crystal

CAS #:

Linear Formula:

GaSe

MDL Number:

N/A

EC No.:

234-689-6

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PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(4N) 99.99% Gallium Selenide Single Crystal
GA-SE-04-ISX
Pricing > SDS > Data Sheet >
(4N5) 99.995% Gallium Selenide Single Crystal
GA-SE-045-ISX
Pricing > SDS > Data Sheet >
(5N) 99.999% Gallium Selenide Single Crystal
GA-SE-05-ISX
Pricing > SDS > Data Sheet >
(6N) 99.9999% Gallium Selenide Single Crystal
GA-SE-06-ISX
Pricing > SDS > Data Sheet >
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Gallium Selenide Single Crystal Properties

Compound Formula

GaSe+4

Molecular Weight

148.7

Appearance

solid

Melting Point

960 °C, 1233 K, 1760 °F

Boiling Point

N/A

Density (Theoretical)

5.03 g/cm3

Exact Mass

148.842103

Monoisotopic Mass

148.842102 Da

Gallium Selenide Single Crystal Health & Safety Information

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Statements N/A
Transport Information N/A
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/23/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Gallium Selenide Single Crystal

Product Number: All applicable American Elements product codes, e.g. GA-SE-04-ISX , GA-SE-045-ISX , GA-SE-05-ISX , GA-SE-06-ISX

CAS #: 12024-11-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008:
GHS06: Skull and crossbones
GHS08: Health hazard
Acute Tox. 2 H300 Fatal if swallowed.
Acute Tox. 2 H330 Fatal if inhaled.
STOT RE 2 H373 May cause damage to the central nervous system, the liver and the digestive system
through prolonged or repeated exposure. Route of exposure: Oral, Inhalative.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC:
T; Toxic
N; Dangerous for the environment
R23/25: Toxic by inhalation and if swallowed.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R33: Danger of cumulative effects.
Information concerning particular hazards for human and environment: Not applicable
Hazards not otherwise classified: No information known.
Label elements
Labeling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard:

Skull and Crossbones - GHS06 Health Hazard - GHS08

GHS06, GHS08
Signal word - Danger
Hazard statements:
H300+H330 Fatal if swallowed or if inhaled.
H373 May cause damage to the central nervous system, the liver and the digestive system
through prolonged or repeated exposure. Route of exposure: Oral, Inhalative.
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P284 [In case of inadequate ventilation] wear respiratory protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor/...
P320 Specific treatment is urgent (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
WHMIS classification:
D1A Very toxic material causing immediate and serious toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System):
HEALTH 2 Health (acute effects) = 2
FIRE 0 Flammability = 0
REACTIVITY 1 Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment:
PBT: Not applicable.
vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
Description: Gallium Monoselenide
Synonyms: Gallium(II) selenide; hydrido(selenoxo)gallium
Formula: GaSe
Molecular weight: 148.68
CAS number: 12024-11-2


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information:
Immediately remove any clothing soiled by the product. Remove breathing apparatus only after contaminated
clothing has been completely removed. In case of irregular breathing or respiratory arrest provide artificial
respiration.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice.
After skin contact:
Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice.
After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Do not induce vomiting; immediately call for medical help.
Most important symptoms and effects, both acute and delayed:
No further relevant information available.
Indication of any immediate medical attention and special treatment needed:
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents:
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture:
If this product is involved in a fire, the following can be released: Selenium dioxide (SeO2), Hydrogen selenide
Advice for firefighters
Protective equipment:
Wear self-contained respirator. Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits. Do not allow
product to reach sewage system or any water course. Do not allow to penetrate the ground/soil.
Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13. Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling:
Keep container tightly sealed. Store in cool, dry place in tightly closed containers. Ensure good ventilation at the
workplace. Open and handle container with care.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed. Store in cool, dry conditions in well-sealed containers. Store at room temperature.
Specific end use(s):
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of
at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
Selenium and selenium compounds (as Se)
mg/m3
ACGIH TLV 0.2
Austria MAK 0.1
Belgium TWA 0.2
Denmark TWA 0.1
Finland TWA 0.1; 0.3-STEL
Germany MAK 0.1
Hungary 0.1-STEL
Japan OEL 0.1
Korea TLV 0.2
Netherlands MAC-TGG 0.2
Poland TWA 0.1; 0.3-STEL
Sweden NGV 0.1
Switzerland MAK-W 0.1
United Kingdom TWA 0.1
USA PEL 0.2
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs,
beverages and feed. Remove all soiled and contaminated clothing immediately. Wash hands before breaks and at
the end of work. Store protective clothing separately. Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use self-contained respiratory protective device in emergency situations.
Protection of hands:
Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable
gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Form: Solid
Odor: Not determined
Odor threshold: Not determined
pH-value: Not applicable
Melting point range: Not determined
Boiling point range: Not determined
Sublimation temperature/start: Not determined
Flash point: Not applicable
Flammability: Not determined
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined
Danger of explosion: No
Lower explosion limits: Not determined
Upper explosion limits: Not determined
Vapor pressure: Not applicable
Density: Not determined
Relative density: Not determined
Vapor density: Not applicable
Evaporation rate: Not applicable
Solubility in water: Not determined
Dynamic viscosity: Not applicable
Partition coefficient (n-octanol/water): Not determined
Kinematic viscosity: Not applicable


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No information known.
Chemical stability:
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions:
No dangerous reactions known
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Selenium dioxide (SeO2), Hydrogen selenide


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Fatal if inhaled. Fatal if swallowed.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
May cause damage to the central nervous system, the liver and the digestive system through prolonged or
repeated exposure. Route of exposure: Oral, Inhalative.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
Selenium may cause amyotrophic lateral sclerosis, bronchial irritation, gastrointestinal distress, vasopharyngeal
irritation, garlic odor on breath and sweat, metallic taste, pallor, irritability, excessive fatigue, loss of fingernails
and hair, pulmonary edema, anemia and weight loss.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability:
No further relevant information available.
Behavior in environmental systems:
Bioaccumulative potential:
No further relevant information available.
Mobility in soil:
No further relevant information available.
Ecotoxical effects:
Remark: Very toxic for aquatic organisms
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits. Do not allow
product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking
water if even extremely small quantities leak into the ground. Also poisonous for fish and plankton in water
bodies. May cause long lasting harmful effects to aquatic life. Avoid transfer into the environment. Very toxic for
aquatic organisms.
Results of PBT and vPvB assessment:
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects:
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods:
Recommendation Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, ADR, IMDG, IATA UN3283
UN proper shipping name
DOT Selenium Compound, N.O.S. (Gallium Monoselenide), 6.1, PG III
ADR 3283 Selenium Compound, N.O.S. (Gallium Monoselenide), 6.1, PG III
IMDG, IATA SELENIUM COMPOUND, N.O.S. (Gallium Monoselenide)
Transport hazard class(es)
DOT, IMDG
Class 6.1
Label 6.1
ADR
Class 6.1
Label 6.1
IATA
Class 6.1
Label 6.1
Packing group
DOT, ADR, IMDG, IATA III
Environmental hazards:
Special marking (ADR): Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
Danger code (Kemler): 90
EMS Number: F-A,S-F
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN3283, Selenium Compound, N.O.S. (Gallium Monoselenide), 6.1, PG III


SECTION 15. REGULATORY INFORMATION

No data available


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Gallium Selenide Single Crystal

Gallium Selenide for solar energy applications is a p-type or absorber layer material. CIGS-based photovoltaic cells (PV Cells) for solar energy are fabricated from a positively charged or p-type Gallium doped Copper Indium Selenide (CIGS) layer underneath a negatively charged or n-type layer. The p-type layer can be partially produced from Gallium Selenide Single Crystal sold under the AE Solar Energy group. Most CIGS-based PV solar cells are produced from thin film deposition of CIGS layers.

Gallium Selenide Single Crystal Synonyms

Gallium monoselenide, gallium(II) selenide, Gallium selenide (GaSe), selanylidenegallium

Gallium Selenide Single Crystal Chemical Identifiers

Linear Formula

GaSe

Pubchem CID

6330514

MDL Number

N/A

EC No.

234-689-6

Beilstein Registry No.

N/A

IUPAC Name

selanylidenegallium

SMILES

[Ga]=[Se]

InchI Identifier

InChI=1S/Ga.Se

InchI Key

QNWMNMIVDYETIG-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Gallium products. Gallium (atomic symbol: Ga, atomic number: 31) is a Block P, Group 13, Period 4 element with an atomic weight of 69.723.The number of electrons in each of Gallium's shells is 2, 8, 18, 3 and its electron configuration is [Ar] 3d10 4s2 4p1. The gallium atom has a radius of 122.1 pm and a Van der Waals radius of 187 pm. Gallium Bohr ModelGallium was predicted by Dmitri Mendeleev in 1871. It was first discovered and isolated by Lecoq de Boisbaudran in 1875. In its elemental form, gallium has a silvery appearance. Elemental GalliumGallium is one of three elements that occur naturally as a liquid at room temperature, the other two being mercury and cesium. Gallium does not exist as a free element in nature and is sourced commercially from bauxite and sphalerite. Currently, gallium is used in semiconductor devices for microelectronics and optics. The element name originates from the Latin word 'Gallia', the old name of France, and the word 'Gallus,' meaning rooster.

Selenium Bohr ModelSee more Selenium products. Selenium (atomic symbol: Se, atomic number: 34) is a Block P, Group 16, Period 4 element with an atomic radius of 78.96. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electron configuration is [Ar] 3d10 4s2 4p4. The selenium atom has a radius of 120 pm and a Van der Waals radius of 190 pm. Selenium is a non-metal with several allotropes: a black, vitreous form with an irregular crystal structure three red-colored forms with monoclinic crystal structures and a gray form with a hexagonal crystal structure, the most stable and dense form of the element. Elemental SeleniumOne of the mose common uses for selenium is in glass production the red tint that it lends to glass neutralizes green or yellow tints from impurities in the glass materials. Selenium was discovered and first isolated by Jöns Jakob Berzelius and Johann Gottlieb Gahn in 1817. The origin of the name Selenium comes from the Greek word "Selênê," meaning moon.

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November 23, 2017
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