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Lutetium(III) Acetylacetonate Hydrate

Lu(acac)3

CAS #:

Linear Formula:

Lu(CH3COCHCOCH3)3 • xH2O

MDL Number:

MFCD08272319

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Lutetium Acetylacetonate Hydrate
LU-ACAC-02-P.XHYD
Pricing > SDS > Data Sheet >
(3N) 99.9% Lutetium Acetylacetonate Hydrate
LU-ACAC-03-P.XHYD
Pricing > SDS > Data Sheet >
(4N) 99.99% Lutetium Acetylacetonate Hydrate
LU-ACAC-04-P.XHYD
Pricing > SDS > Data Sheet >
(5N) 99.999% Lutetium Acetylacetonate Hydrate
LU-ACAC-05-P.XHYD
Pricing > SDS > Data Sheet >

Lutetium(III) Acetylacetonate Hydrate Properties (Theoretical)

Compound Formula C15H26LuO7
Molecular Weight 493.33
Appearance White powder
Melting Point 158-163 °C
Boiling Point N/A
Density N/A
Solubility in H2O Insoluble
Exact Mass 493.108625
Monoisotopic Mass 493.108625

Lutetium(III) Acetylacetonate Hydrate Health & Safety Information

Signal Word Warning
Hazard Statements H302-H312-H315-H319-H332-H335-H361
Hazard Codes Xn
Precautionary Statements P261-P280-P305 + P351 + P338
Risk Codes 20/21/22-36/37/38-63
Safety Statements 26-36
RTECS Number N/A
Transport Information NONH for all modes of transport
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 09/21/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Lutetium(III) Acetylacetonate Hydrate

Product Number: All applicable American Elements product codes, e.g. LU-ACAC-02-P.XHYD 02 , LU-ACAC-03-P.XHYD 03 , LU-ACAC-04-P.XHYD 04 , LU-ACAC-05-P.XHYD 05

CAS #: 86322-74-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral(Category 4), H302
Acute toxicity, Inhalation(Category 4), H332
Acute toxicity, Dermal(Category 4), H312
Skin irritation(Category 2), H315
Eye irritation(Category 2A), H319
Reproductive toxicity(Category 2), H361
Specific target organ toxicity -single exposure(Category 3), Respiratory system, H335
GHS Label elements, including precautionary statements
Pictogram

Exclamation Mark - GHS07 Health Hazard - GHS08

Signal word
Warning
Hazard statement(s)
H302 + H312 + H332
Harmful if swallowed, in contact with skin or if inhaled
H315
Causes skin irritation.
H319
Causes serious eye irritation.
H335
May cause respiratory irritation.
H361
Suspected of damaging fertility or the unborn child.
Precautionary statement(s)
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P261
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264
Wash skin thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well-ventilated area.
P280
Wear protective gloves/ eye protection/ face protection.
P301 + P312
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302 + P352
IF ON SKIN: Wash with plenty of soap and water.
P304 + P340
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313
IF exposed or concerned: Get medical advice/ attention.
P322
Specific measures (see supplemental first aid instructions on this label).
P330
Rinse mouth.
P332 + P313
If skin irritation occurs: Get medical advice/ attention.
P337 + P313
If eye irritation persists: Get medical advice/ attention.
P362
Take off contaminated clothing and wash before reuse.
P403 + P233
Store in a well-ventilated place. Keep container tightly closed.
P405
Store locked up.
P501
Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS-none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Synonyms: Lu(acac)3
Formula: C15H21LuO6· xH2O
Molecular Weight: 472.29 g/mol
CAS-No.: 86322-74-9


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not b
reathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
no data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, lutetium oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
Normal measures for preventive fire protection.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: solid
Odor
no data available
Odor Threshold
no data available
pH
no data available
Melting point/freezing point
Melting point/range: 158 -163 °C (316 -325 °F)-lit.
Initial boiling point and boiling range
no data available
Flash point
no data available
Evaporation rate
no data available
Flammability (solid, gas)
no data available
Upper/lower flammability or explosive limits
no data available
Vapor pressure
no data available
Vapor density
no data available
Relative density
no data available
Water solubility
no data available
Partition coefficient: n-octanol/water
no data available
Auto-ignition temperature
no data available
Decomposition temperature
no data available
Viscosity
no data available
Explosive properties
no data available
Oxidizing properties
no data available
Other safety information
no data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products-no data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
Inhalation: Irritating to respiratory system.
no data available
Skin corrosion/irritation
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
Possible risk of congenital malformation in the fetus.
Suspected human reproductive toxicant
no data available
Specific target organ toxicity -single exposure
Inhalation-May cause respiratory irritation.
Specific target organ toxicity -repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
no data available
Persistence and degradability
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Lutetium(III) acetylacetonate hydrate
CAS-No.
86322-74-9
New Jersey Right To Know Components
Lutetium(III) acetylacetonate hydrate
CAS-No.
86322-74-9
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Lutetium(III) Acetylacetonate Hydrate

Acetylacetonate Formula Diagram (C5H8O2)Lutetium Acetylacetonate Hydrate is a Lutetium source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic Acetylacetonate Packaging, Lab Quantitycompounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis. We also manufacture anhydrous lutetium acetylacetonate. Please request a quote above to receive pricing information based on your specifications.

Lutetium(III) Acetylacetonate Hydrate Synonyms

Lutetium(III) 2,4-pentanedionate hydrate; Lu(acac)3, (Z)-4-hydroxypent-3-en-2-one lutetium hydrate; Lutetium tris(2,4-pentanedionato-O,O')-, monohydrate, (OC-6-11)-

Chemical Identifiers

Linear Formula Lu(CH3COCHCOCH3)3 • xH2O
MDL Number MFCD08272319
EC No. N/A
Beilstein Registry No. N/A
Pubchem CID 16213767
IUPAC Name (Z-4-hydroxypent-3-en-2-one; lutetium; hydrate
SMILES CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.O.[Lu]
InchI Identifier InChI=1S/3C5H8O2.Lu.H2O/c3*1-4(6)3-5(2)7;;/h3*3,6H,1-2H3;;1H2/b3*4-3-;;
InchI Key CIQHOJLOKQPOPH-KJVLTGTBSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Lutetium products. Lutetium (atomic symbol: Lu, atomic number: 71) is a Block F, Group 3, Period 6 element with an atomic weight of 174.9668. The number of electrons in each of Lutetium's shells is [2, 8, 18, 32, 9, 2] and its electron configuration is [Xe] 4f15 5d1 6s2.Lutetium Bohr Model In its elemental form, lutetium has a silvery-white appearance. The lutetium atom has a radius of 174 pm and a Van der Waals radius of 221 pm. Lutetium was discovered and first isolated by Georges Urbain, Carl Auer von Welsbach and Charles James in 1906, all independently of each other.Elemental Lutetium Urbain was awarded the naming honor because he published his findings first. Lutetium is the last member of the rare earth series. Unlike most rare earths it lacks a magnetic moment. It has the smallest metallic radius of any rare earth and it is perhaps the least naturally abundant of the lanthanides. The most common source of commercially produced lutetium is the mineral monazite. The name lutetium originates from the Latin word Lutetia, meaning Paris. Lutetium is found with almost all other rare earth metals, but it never occurs naturally by itself.

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