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Nickel Molybdate

CAS #:

14177-55-0

Linear Formula:

NiMoO4

MDL Number:

MFCD00016255

EC No.:

238-034-5

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Nickel(II) Molybdate
NI-MOAT-02 Pricing > SDS > Data Sheet >
(3N) 99.9% Nickel(II) Molybdate
NI-MOAT-03 Pricing > SDS > Data Sheet >
(4N) 99.99% Nickel(II) Molybdate
NI-MOAT-04 Pricing > SDS > Data Sheet >
(5N) 99.999% Nickel(II) Molybdate
NI-MOAT-05 Pricing > SDS > Data Sheet >

Properties

Compound Formula

NiMoO4

Molecular Weight

218.651

Appearance

Yellow powder

Melting Point

N/A

Boiling Point

N/A

Density

N/A

Exact Mass

219.82041

Monoisotopic Mass

219.82041

Health & Safety Information

Signal Word Danger
Hazard Statements H350-H372-H317
Hazard Codes Xn, N
Risk Codes 22-36/37/38-40-43-50/53
Safety Statements 22-36/37-60-61
RTECS Number N/A
Transport Information UN 3077 9/PG 3
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 02/21/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Nickel Molybdate

Product Number: All applicable American Elements product codes, e.g. NI-MOAT-02 , NI-MOAT-03 , NI-MOAT-04 , NI-MOAT-05

CAS #: 14177-55-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
1093 Broxton Ave. Suite 2000
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS08 Health hazard
Carc. 1B
H350 May cause cancer.
STOT RE 1 H372 Causes damage to the lung, the kidneys and the liver through prolonged or repeated exposure. Route of exposure: Inhalative.
GHS07
Skin Sens. 1 H317 May cause an allergic skin reaction.
Hazards not otherwise classified
No information known.
Label elements
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

Exclamation Mark - GHS07 Health Hazard - GHS08

GHS07 GHS08
Signal word
Danger
Hazard statements
H317 May cause an allergic skin reaction.
H350 May cause cancer.
H372 Causes damage to the lung, the kidneys and the liver through prolonged or repeated exposure. Route of exposure: Inhalative.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
14177-55-0 Nickel molybdenum oxide
Identification number(s):
EC number:
238-034-5
Index number:
028-057-00-7


SECTION 4. FIRST AID MEASURES

Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Molybdenum oxides
Nickel oxides
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
14177-55-0 Nickel molybdenum oxide (100.0%)
PEL (USA)
Long-term value: 1 mg/m³
as Ni
REL (USA)
Long-term value: 0.015 mg/m³
as Ni; See Pocket Guide App. A
TLV (USA)
Long-term value: 0.2 mg/m³
as Ni; inhalable fraction
EV (Canada) Long-term value: 0.1 mg/m³
Inhalable fraction, as Ni
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes)
480
Glove thickness
0.11 mm
Eye protection:
Safety glasses
Body protection:
Protective work clothing.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder
Color: Green
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density: Not determined
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No further relevant information available.
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Molybdenum oxides
Nickel oxides


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
No effects known.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
May cause an allergic skin reaction.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
May cause cancer.
IARC-1: Carcinogenic to humans: sufficient evidence of carcinogenicity.
ACGIH A1: Confirmed human carcinogen: Agent is carcinogenic to humans based on epidemiologic studies of, or convincing clinical evidence in, exposed humans.
NTP-K: Known to be carcinogenic: sufficient evidence from human studies.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
Causes damage to the lung, the kidneys and the liver through prolonged or repeated exposure. Route of exposure: Inhalative.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, ADN, IMDG, IATA
Not applicable
UN proper shipping name
DOT, ADN, IMDG, IATA
Not applicable
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class
Not applicable
Packing group
DOT, IMDG, IATA
Not applicable
Environmental hazards:
Not applicable.
Special precautions for user
Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No


SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS07
GHS08
Signal word
Danger
Hazard statements
H317 May cause an allergic skin reaction.
H350 May cause cancer.
H372 Causes damage to the lung, the kidneys and the liver through prolonged or repeated exposure. Route of exposure: Inhalative.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings)
14177-55-0 Nickel molybdenum oxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer
14177-55-0 Nickel molybdenum oxide
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About

Molybdate IonNickel(II) Molybdate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Synonyms

Nickel molybdenum oxide, nickel(2+) molybdate, Molybdenum nickel tetraoxide, Nickel(2+) dioxido(dioxo)molybdenum, molybdic acid nickel salt, CAS 12673-58-4, Mo.Ni+2.4[O-2]

Chemical Identifiers

Linear Formula

NiMoO4

Pubchem CID

84241

MDL Number

MFCD00016255

EC No.

238-034-5

IUPAC Name

dioxido(dioxo)molybdenum; nickel(2+)

SMILES

[Ni+2].[O-][Mo]([O-])(=O)=O

InchI Identifier

InChI=1S/Mo.Ni.4O/q;+2;;;2*-1

InchI Key

NLPVCCRZRNXTLT-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Products & Element Information

See more Molybdenum products. Molybdenum (atomic symbol: Mo, atomic number: 42) is a Block D, Group 6, Period 5 element with an atomic weight of 95.96. Molybdenum Bohr ModelThe number of electrons in each of molybdenum's shells is [2, 8, 18, 13, 1] and its electron configuration is [Kr] 4d5 5s1. The molybdenum atom has a radius of 139 pm and a Van der Waals radius of 209 pm. In its elemental form, molybdenum has a gray metallic appearance. Molybdenum was discovered by Carl Wilhelm in 1778 and first isolated by Peter Jacob Hjelm in 1781. Molybdenum is the 54th most abundant element in the earth's crust. Elemental MolybdenumIt has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum does not occur naturally as a free metal, it is found in various oxidation states in minerals. The primary commercial source of molybdenum is molybdenite, although it is also recovered as a byproduct of copper and tungsten mining. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead.

See more Nickel products. Nickel (atomic symbol: Ni, atomic number: 28) is a Block D, Group 4, Period 4 element with an atomic weight of 58.6934. Nickel Bohr ModelThe number of electrons in each of nickel's shells is [2, 8, 16, 2] and its electron configuration is [Ar]3d8 4s2. Nickel was first discovered by Alex Constedt in 1751. The nickel atom has a radius of 124 pm and a Van der Waals radius of 184 pm. In its elemental form, nickel has a lustrous metallic silver appearance. Nickel is a hard and ductile transition metal that is considered corrosion-resistant because of its slow rate of oxidation. Elemental NickelIt is one of four elements that are ferromagnetic and is used in the production of various type of magnets for commercial use. Nickel is sometimes found free in nature but is more commonly found in ores. The bulk of mined nickel comes from laterite and magmatic sulfide ores. The name originates from the German word kupfernickel, which means "false copper" from the illusory copper color of the ore.

Recent Research

Application of dahlia-like molybdenum disulfide nanosheets for solid phase extraction of Co(II) in vegetable and water samples., Aghagoli, Mohammad Javad, Beyki Mostafa Hossein, and Shemirani Farzaneh , Food Chem, 2017 May 15, Volume 223, p.8-15, (2017)

Determination of hexitols by reversed phase liquid chromatography using on-line complexation with molybdate ion., Kemmei, Tomoko, Kodama Shuji, Yamamoto Atsushi, Inoue Yoshinori, and Hayakawa Kazuichi , Anal Chim Acta, 2017 Mar 15, Volume 958, p.71-76, (2017)

Au nanoparticles/hollow molybdenum disulfide microcubes based biosensor for microRNA-21 detection coupled with duplex-specific nuclease and enzyme signal amplification., Shuai, Hong-Lei, Huang Ke-Jing, Chen Ying-Xu, Fang Lin-Xia, and Jia Meng-Pei , Biosens Bioelectron, 2017 Mar 15, Volume 89, Issue Pt 2, p.989-997, (2017)

Laser synthesis, structure and chemical properties of colloidal nickel-molybdenum nanoparticles for the substitution of noble metals in heterogeneous catalysis., Marzun, Galina, Levish Alexander, Mackert Viktor, Kallio Tanja, Barcikowski Stephan, and Wagener Philipp , J Colloid Interface Sci, 2017 Mar 01, Volume 489, p.57-67, (2017)

Enhancement of cavitation erosion resistance of 316 L stainless steel by adding molybdenum., Li, D G., Chen D R., and Liang P , Ultrason Sonochem, 2017 Mar, Volume 35, Issue Pt A, p.375-381, (2017)

Effects of tungsten on uptake, transport and subcellular distribution of molybdenum in oilseed rape at two different molybdenum levels., Qin, Shiyu, Sun Xuecheng, Hu Chengxiao, Tan Qiling, Zhao Xiaohu, and Xu Shoujun , Plant Sci, 2017 Mar, Volume 256, p.87-93, (2017)

A sensitive aptasensor based on molybdenum carbide nanotubes and label-free aptamer for detection of bisphenol A., He, Meng-Qi, Wang Kun, Wang Jin, Yu Yong-Liang, and He Rong-Huan , Anal Bioanal Chem, 2017 Mar, Volume 409, Issue 7, p.1797-1803, (2017)

Localization and pair breaking parameter in superconducting molybdenum nitride thin films., Tsuneoka, Takuya, Makise Kazumasa, Maeda Sho, Shinozaki Bunju, and Ichikawa Fusao , J Phys Condens Matter, 2017 Jan 11, Volume 29, Issue 1, p.015701, (2017)

Template Removal via Boudouard Equilibrium Allows for Synthesis of Mesostructured Molybdenum Compounds., Schieder, Martin, Bojer Carina, Stein Julia Vom, Koch Sebastian, Martin Thomas, Schmalz Holger, Breu Josef, and Lunkenbein Thomas , Angew Chem Int Ed Engl, 2017 Jan 03, (2017)

Molybdenum-Doped PdPt@Pt Core-Shell Octahedra Supported by Ionic Block Copolymer-Functionalized Graphene as a Highly Active and Durable Oxygen Reduction Electrocatalyst., Cho, Kie Yong, Yeom Yong Sik, Seo Heun Young, Kumar Pradip, Lee Albert S., Baek Kyung-Youl, and Yoon Ho Gyu , ACS Appl Mater Interfaces, 2017 Jan 03, (2017)

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February 21, 2017
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