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Phosphorus(III) Iodide

CAS #:

Linear Formula:

PI3

MDL Number:

MFCD00011442

EC No.:

236-647-2

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Phosphorus Iodide
P-I-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Phosphorus Iodide
P-I-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Phosphorus Iodide
P-I-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Phosphorus Iodide
P-I-05
Pricing > SDS > Data Sheet >
Question? Ask an American Elements EngineerWHOLESALE/SKU 0000-742-13895

Phosphorus(III) Iodide Properties

Compound Formula

I3P

Molecular Weight

411.69

Appearance

Black powder, crystals, or chunks

Melting Point

61 °C

Boiling Point

N/A

Density (Theoretical)

4.18 g/cm3

Solubility in H2O

Insoluble

Exact Mass

411.687181

Monoisotopic Mass

411.687181

Phosphorus(III) Iodide Health & Safety Information

Signal Word Danger
Hazard Statements H314-H335
Hazard Codes C
Risk Codes 14-34-37
Safety Statements 26-36/37/39-45
RTECS Number N/A
Transport Information UN 3260 8/PG 2
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/21/2017
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: Phosphorus(III) Iodide

Product Number: All applicable American Elements product codes, e.g. P-I-02 , P-I-03 , P-I-04 , P-I-05

CAS #: 13455-01-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

· Classification of the substance or mixture
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
· Label elements
· GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

Corrosion - GHS05

GHS05
· Signal word Danger
· Hazard-determining components of labeling:
phosphorus triiodide
· Hazard statements
H314 Causes severe skin burns and eye damage.
· Precautionary statements
P231 Handle under inert gas.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P422 Store contents under inert gas.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 4
Fire = 0
Reactivity = 0
· HMIS-ratings (scale 0 - 4)
Health = 4
Fire = 0
Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

· Chemical characterization: Substances
· CAS No. Description
13455-01-1 phosphorus triiodide
· Identification number(s)
· EC number: 236-647-2


SECTION 4. FIRST AID MEASURES

· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.


SECTION 5. FIREFIGHTING MEASURES

· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.


SECTION 6. ACCIDENTAL RELEASE MEASURES

· Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions: No special measures required.
· Methods and material for containment and cleaning up:
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.


SECTION 7. HANDLING AND STORAGE

· Handling:
· Precautions for safe handling
Thorough dedusting.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
· Information about protection against explosions and fires: Keep respiratory protective device available.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· Specific end use(s) No further relevant information available.


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
13455-01-1 phosphorus triiodide
TLV Long-term value: 0.01* ppm
*as inhalable fraction and vapor
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Crystalline
Color: Black
· Odor: Pungent
· Odor threshold: Not determined.
· pH-value: Not applicable.
· Change in condition
Melting point/Melting range: 61 °C (142 °F)
Boiling point/Boiling range: no data °C
· Flash point: Not applicable.
· Flammability (solid, gaseous): Product is not flammable.
· Ignition temperature:
Decomposition temperature: Not determined.
· Auto igniting: Not determined.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapor pressure: no data hPa
· Density at 20 °C (68 °F): 4.18 g/cm³ (34.882 lbs/gal)
· Relative density Not determined.
· Vapor density Not applicable.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
Water: Insoluble.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
· Solvent content:
Organic solvents: 0.0 %
VOC content: 0.0 g/l / 0.00 lb/gl
Solids content: 100.0 %
· Other information No further relevant information available.


SECTION 10. STABILITY AND REACTIVITY

· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.


SECTION 11. TOXICOLOGICAL INFORMATION

· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: Caustic effect on skin and mucous membranes.
· on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
Substance is not listed.
· NTP (National Toxicology Program)
Substance is not listed.
· OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.


SECTION 12. ECOLOGICAL INFORMATION

· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes: Must not reach bodies of water or drainage ditch undiluted or unneutralized.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.


SECTION 14. TRANSPORT INFORMATION

· UN-Number
· DOT, IMDG, IATA UN1759
· UN proper shipping name
· DOT, IATA Corrosive solids, n.o.s.
· IMDG CORROSIVE SOLID, N.O.S.
· Transport hazard class(es)
· DOT
· Class 8 Corrosive substances
· Label 8
· IMDG, IATA
· Class 8 Corrosive substances
· Label 8
· Packing group
· DOT, IMDG, IATA II
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Corrosive substances
· EMS Number: F-A,S-B
· Stowage Category A
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations On passenger aircraft/rail: 15 kg
On cargo aircraft only: 50 kg
· IMDG
· Limited quantities (LQ) 1 kg
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 500 g
· UN "Model Regulation": UN 1759 CORROSIVE SOLIDS, N.O.S., 8, II


SECTION 15. REGULATORY INFORMATION

· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
Substance is not listed.
· Section 313 (Specific toxic chemical listings):
Substance is not listed.
· TSCA (Toxic Substances Control Act):
Substance is listed.
· Proposition 65
· Chemicals known to cause cancer:
Substance is not listed.
· Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
· Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
· Chemicals known to cause developmental toxicity:
Substance is not listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency)
Substance is not listed.
· TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
· GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

Corrosion - GHS05

GHS05
· Signal word Danger
· Hazard-determining components of labeling:
phosphorus triiodide
· Hazard statements
H314 Causes severe skin burns and eye damage.
· Precautionary statements
P231 Handle under inert gas.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P422 Store contents under inert gas.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2016 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Phosphorus(III) Iodide

Phosphorus(III) Iodide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Phosphorus(III) Iodide Synonyms

Phosphorus triiodide; Triiodophosphine; Triiodophosphane

Phosphorus(III) Iodide Chemical Identifiers

Linear Formula

PI3

Pubchem CID

83485

MDL Number

MFCD00011442

EC No.

236-647-2

Beilstein Registry No.

N/A

IUPAC Name

triiodophosphane

SMILES

P(I)(I)I

InchI Identifier

InChI=1S/I3P/c1-4(2)3

InchI Key

PZHNNJXWQYFUTD-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Iodine products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electron configuration is [Kr] 4d10 5s2 5p5. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. In its elemental form, iodine has a lustrous metallic gray appearance as a solid and a violet appearance as a gas or liquid solution. Elemental IodineIodine forms compounds with many elements, but is less active than the other halogens. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Iodine compounds are important in organic chemistry and very useful in the field of medicine. Iodine was discovered and first isolated by Bernard Courtois in 1811. The name Iodine is derived from the Greek word "iodes" meaning violet.

Phosphorus Bohr ModelSee more Phosphorus products. Phosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669 its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation.

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