Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges.

Author(s) Tian, H.; Wang, B.L.; Lu, J.; Liu, H.T.; Su, J.; Li, D.; Dou, J.
Journal Chem Commun (Camb)
Date Published 2018 Oct 23

The double chloride-bridged dimer of a dinuclear dysprosium(iii) single-molecule magnet (SMM) was successfully isolated by assembling centrosymmetric dinuclear Dy2 SMMs. Such structural transformation involves the generation and cleavage of chloride bridges and leads to consecutive transformations of one- and two-step slow relaxation of magnetization.

DOI 10.1039/c8cc06699j
ISSN 1364-548X
Citation Chem Commun (Camb). 2018;54(85):1210512108.

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