Low valent lead hydride chemistry: hydroplumbylation of phenylacetylene and 1,1-dimethylallene.

Author(s) Weiß, S.; Schubert, H.; Wesemann, L.
Journal Chem Commun (Camb)
Date Published 2019 Aug 22
Abstract

Hydroplumbylation reactions of the low valent organolead hydride [(Ar*PbH)2] with phenylacetylene and 1,1-dimethylallene are presented. A vinyl plumbylene was isolated in the case of the alkyne reaction exhibiting a down field NMR signal for the CH unit attached to the low valent heavy atom. 1,1-Dimethylallene affords formation of an allyl plumbylene.

DOI 10.1039/c9cc05431f
ISSN 1364-548X
Citation Weiß S, Schubert H, Wesemann L. Low valent lead hydride chemistry: hydroplumbylation of phenylacetylene and 1,1-dimethylallene. Chem Commun (Camb). 2019;55(69):10238-10240.

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