Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol.

Author(s) Magnabosco, G.; Condorelli, A.M.M.; Rosenberg, R.; Polishchuk, I.; Pokroy, B.; Gebauer, D.; Cölfen, H.; Falini, G.
Journal Chem Commun (Camb)
Date Published 2019 Oct 24

The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.

DOI 10.1039/c9cc07087g
ISSN 1364-548X
Citation Chem Commun (Camb). 2019;55(86):1294412947.

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